Leaching Stability of Simulated Waste Forms for Immobilizing An3＋ by Gd2Zr2O7 with Nd3＋

In order to investigate the anti-leaching capability of pyrochlore Gd2Zr2O7 immobilized An3+, trivalent neodymium was used as the simulacrums for radioactive wastes with trivalence, Gd2-xNdxZr2O7(0.0x 2.0) series samples were successfully synthesized by high temperature solid reaction and using Gd2O3, Zr O2 powders as starting materials. The experiments of long-term chemical stability were conducted in synthetic seawater at 40 and 70 ℃. The XRD diffractive data and extraction ratio of as-received samples were collected with the help of X-ray diffraction(XRD) instrument and inductively coupled plasma mass spectrometry(ICPMass). The results indicate that the phases of as-received compounds keep the single phase of pyrochlore. The extraction ratio of Gd3+, Zr4+ and Nd3+ in waste forms is increasing with the increase of immersion time in synthetic seawater. The extraction ratio of waste forms at 70 ℃ is higher than at 40 ℃. The highest extraction ratio of Gd3+, Zr4+ and Nd3+ after 42 days is near 0.025 8, 0.003 8 and 0.045 2 μg·m L-1, respectively.     

双核稀土配合物Gd_xSm_(1-x)(TTA)_3phen的制备及发光性能

合成了系列钆钐双核稀土有机配合物GdxSm1-x(TTA)3phen(x=0~0.9).红外光谱(IR)、X射线衍射(XRD)、热重(TG)结果推测了配合物可能的分子结构;紫外可见光谱(UV/vis)结果表明,该系列稀土有机配合物能有效的吸收紫外光,吸收峰主要来自于有机配体TTA和phen(270nm和351nm处);荧光光谱(FS)结果表明,Gd3+对于Sm3+具有荧光增效,当Gd3+的摩尔分数为0.6时,Gd0.6Sm0.4(TTA)3phen类配合物的特征荧光(562nm,596nm和643nm处)强度均达到最大.     

改良型腰果酚醛树脂废气治理的研究

改良型腰果酚醛树脂应用到铸件等浸渍、粘合、烘干等过程中会产生恶臭,排放前需要降解处理。研究采用低温等离子体技术结合吸收方法处理改良型腰果酚醛树脂废气,考察了处理工程中峰值电压、停留时间、吸收液pH值对废气去除率的影响。实验室小试改良型腰果酚醛树脂废气进口浓度85 ppm,停留时间1.2 s时,去除率可达92%;工业扩大示范工程去除率最高可达80%,排气口出气平均恶臭浓度1 239.5(无量纲),满足《恶臭污染物排放标准》(GB14554-93)中相关规定。     

明渠扩散段急流运动特性及调控方法研究综述

依据文献分析了有限宽度水槽突然扩散、固定扩散角渐变扩散、无边界平板扩散和急流扩散4种典型明渠扩散段水流的共同流动特征.给出了有限宽度水槽突然扩散段水流宽度的沿程发展规律,以及在平底明渠急流扩散段设计时,为防止水流脱离的扩散角计算方法和突然扩展区急流扩散的边界方程;通过不同底坡比降的试验和原型资料分析,论述了陡坡扩散区水深沿程变化特点、沿程各断面横向分布规律,介绍了陡坡上水平扩散角的计算方法与扩散角最大值的存在.通过大扩散角水槽试验,发现在扩散段不同流态的过渡水流现象及稳定性不一样.上游来流为急流时,下游水跃进入扩散段就是水流失稳、主流偏转的开始;采用潜没式三角翼可以防止扩散段回流发生,提高过流均衡性.     

Preparation of zeolite NaA for CO2 capture from nickel laterite residue

Zeolite NaA was successfully prepared from nickel laterite residue for the first time via a fusion-hydrothermal procedure. The structure and morphology of the as-synthesized zeolite NaA were characterized with a range of experimental techniques, such as X-ray diffraction, scanning electronic microscopy, and infrared spectroscopy. It was revealed that the structures of the produced zeolites were dependent on the molar ratios of the reactants and hydrothermal reaction conditions, so the synthesis conditions were optimized to obtain pure zeolite NaA. Adsorption of nitrogen and carbon dioxide on the prepared zeolite NaA was also measured and analyzed. The results showed that zeolite NaA could be prepared with reasonable purity, it had physicochemical properties comparable with zeolite NaA made from other methods, and it had excellent gas adsorption properties, thus demonstrating that zeolite NaA could be prepared from nickel laterite residue.     

基于医学院校移动图书馆智能服务模式的研究

本文总结了当前医学院校移动图书馆服务开展的现状,分析了当前服务过程中存在的问题与需求,提出了目前我国医学院校移动图书馆服务的优化与发展方向。     

虚拟牛顿环光参量测试仪

虚拟仪器在测试测量领域、自动控制和工业控制领域有着广泛的应用.本文以虚拟牛顿环光参量的测量为例,介绍了虚拟仪器在物理实验中的具体应用.     

高压直流控制原理研究

分析了常规高压直流输电特点和基本原理,论述了特高压直流、柔性直流、背靠背直流、多端直流的特点、发展前景及基本控制原理,提出了针对不同类型的直流输电的控制策略和方法.     

含分布式能源的配电网规划

概述了分布式电源对配电网的影响,分析了分布式电源在配电网中的优化配置以及含分布式能源的配电网的无功优化模型,总结了在规划过程中的算法,最后针对配电网的规划提出了相关建议.     

基于RTDS的高压直流输电控制功能研究

为了对高压直流输电系统实时仿真并对控制功能进行研究,基于实时仿真平台RTDS搭建了高压直流输电控制保护详细仿真模型,通过进行启停控制、阶跃响应、功率控制、无功控制、交流系统故障等试验,研究了直流输电基本控制功能,验证了模型的准确性和有效性,控制系统能准确和快速响应,表明了该模型可用于直流运行特性和交直流交互影响研究。