全文获取类型
收费全文 | 3918篇 |
免费 | 284篇 |
专业分类
电工技术 | 25篇 |
综合类 | 1篇 |
化学工业 | 1191篇 |
金属工艺 | 73篇 |
机械仪表 | 126篇 |
建筑科学 | 146篇 |
矿业工程 | 8篇 |
能源动力 | 138篇 |
轻工业 | 1018篇 |
水利工程 | 28篇 |
石油天然气 | 23篇 |
无线电 | 174篇 |
一般工业技术 | 502篇 |
冶金工业 | 325篇 |
原子能技术 | 18篇 |
自动化技术 | 406篇 |
出版年
2024年 | 9篇 |
2023年 | 24篇 |
2022年 | 175篇 |
2021年 | 232篇 |
2020年 | 118篇 |
2019年 | 126篇 |
2018年 | 132篇 |
2017年 | 160篇 |
2016年 | 148篇 |
2015年 | 128篇 |
2014年 | 159篇 |
2013年 | 300篇 |
2012年 | 290篇 |
2011年 | 284篇 |
2010年 | 228篇 |
2009年 | 208篇 |
2008年 | 215篇 |
2007年 | 178篇 |
2006年 | 139篇 |
2005年 | 105篇 |
2004年 | 96篇 |
2003年 | 80篇 |
2002年 | 65篇 |
2001年 | 64篇 |
2000年 | 38篇 |
1999年 | 32篇 |
1998年 | 88篇 |
1997年 | 52篇 |
1996年 | 47篇 |
1995年 | 47篇 |
1994年 | 31篇 |
1993年 | 29篇 |
1992年 | 16篇 |
1991年 | 17篇 |
1990年 | 11篇 |
1989年 | 11篇 |
1988年 | 17篇 |
1987年 | 8篇 |
1986年 | 12篇 |
1985年 | 9篇 |
1984年 | 8篇 |
1983年 | 7篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1980年 | 11篇 |
1979年 | 6篇 |
1976年 | 10篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1972年 | 3篇 |
排序方式: 共有4202条查询结果,搜索用时 546 毫秒
51.
Dragan Jocic Susana Vílchez Tatjana Topalovic Ricardo Molina Antonio Navarro Petar Jovancic Maria Rosa Juli Pilar Erra 《应用聚合物科学杂志》2005,97(6):2204-2214
This study examines in detail the influence of low‐temperature plasma and biopolymer chitosan treatments on wool dyeability. Wool knitted fabrics were treated and characterized by whiteness and shrink‐resistance measurements. Surface modification was assessed by contact‐angle measurements of human hair fibers, which were used as a model to study the wetting properties of the treated wool knitted fabrics. The dyeing behavior was assessed from the diffusion mechanism point of view. The dyeing kinetics were measured at two different pHs (4.2 and 6.5) and three different temperatures (60, 85, and 100°C) to gain information about the contribution of the surface modification treatment to the dyeing mechanism. The exhaustion and reflectance data were compared, and the apparent diffusion coefficients were calculated. On the basis of the obtained results, a model for the dyeing mechanism of the chitosan treated wool was proposed. When treated with chitosan, the polymer sheath spread on the surface of the fibers acted as a predominant dyeing site in very short dyeing times, thus interacting with the dye and in later stages imparting the dye to the wool fiber. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2204–2214, 2005 相似文献
52.
Paola Fabbri Massimo Messori Monica Montecchi Francesco Pilati Rosa Taurino Claudio Tonelli Maurizio Toselli 《应用聚合物科学杂志》2006,102(2):1483-1488
A commercial perfluoropolyether containing alkoxysilane functionalities was employed to prepare organic–inorganic hybrid coatings by using the sol‐gel process in the presence of tetraethoxysilane. Contact angle analysis revealed a strong hydrophobic and oleophobic character of the coatings almost independently from the molecular weight of the starting fluorinated oligomer. Surface tension values were in the range of 14–16 mN/m, suggesting a preferential segregation of fluorinated segments onto the surface of the coating. Atomic force microscopy showed the presence very smooth surfaces permitting to neglect the contribution of the surface roughness to wettability. Friction coefficient values were markedly lower with respect to the value of uncoated glass substrate. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1483–1488, 2006 相似文献
53.
The conditions for obtaining recrystallization in more ordered modifications are described for an uniaxially oriented sample of isotactic polypropylene, annealed with fixed ends. These recrystallization conditions are related to the conditions of a lamination process. 相似文献
54.
Four PPG Avanel Series S surfactants (sodium alkyl polyether sulfonates) with varying ethylene oxide content (n = 3, 7, 9, and 15) were used to investigate the influence of the steric length in this type of electrosteric stabilizers on emulsion polymerization. The polymerization studies employing potassium persulfate as an initiator with styrene, methyl methacrylate, and vinyl acetate monomers showed no apparent change in particle size, number of particles, and polymerization rate with the changing steric length of the surfactant. Steric influences were observed in the redox-initiated systems of styrene, butyl acrylate, and methyl methacrylate. Increasing the ethylene oxide unit content from three to nine units decreased the rate of polymerization, the particle size and number in the polystyrene latexes. Polymerizations with the acrylates displayed the same trend except that the polymerization rate reached a minimum value at nine ethylene oxide units and increased when the surfactant containing 15 ethylene oxide units was used. 相似文献
55.
A specifically formulated nanocomposite based on isotactic poly(1-butene) (PB) and montmorillonite was studied, by wide angle X-ray diffraction (WAXD), small angle X-ray scattering (SAXS), transmission electron microscopy (TEM) and polarized light optical microscopy, investigating the polymorphism of the polymer, and examining the interaction between PB and the silicate. Montmorillonite was found to disrupt the ordered morphology of the polymer, determining a dramatic increase in the rate of the II→I phase transition. Interaction between polymer and clay was studied by TEM and SAXS also under a quantitative point of view. A significant enhancement of physical-mechanical properties was observed, even though exfoliation did not occur, but just a slight intercalation and a reduction in the size of tactoids. 相似文献
56.
The present study was designed to examine the effects of EFA deficiency (EFAD) on biochemical, functional, and structural
aspects of the kidney in growing and adult rats fed a normal or EFAD diet for 9 wk after weaning. Food and fluid intake (FI),
urine volume, and Na+ and K+ excretions were measured weekly from weeks 4 to 8 by placing the rats in individual metabolic cages for 24 h. At week 9,
Li+ and a 5% water load, respectively, were administered at 14 and 1.5 h prior to glomerular and proximal tubular function studies,
as assessed by 3-h creatinine (CCr) and Li+ (CLi+) clearances. Hematocrit and urine volume; serum and urine [Cr], [Li+], [Na+], and [K+]; and renal FA distribution were also measured. Data [corrected to 100 g/body weight (bw) and presented as means ±SEM] were
significant, at P<-0.05. Despite a similar ingestion of solids from weeks 4 to 7 (weeks 7 to 10 of life), the rats on the EFAD diet showed
a decreased body weight from week 5. From weeks 4 to 8, Fl and urine volume were similar for both groups, but the Fl increased
at week 6 in the EFAD group; 24-h Na+ and K+ excretions were similar at all weeks, except for an increase in the EFAD group for both ions at week 7. In the EFAD group,
CCr and CLi+ decreased by 27 and 56.3%, respectively (385.7±33.4 vs. 280±21.1, and 21.0±2.1 vs. 9.2±1.1 μL/min/100 g; n=9 vs. 10), the latter result suggesting increased proximal reabsorption. The 3-h Na+ and K+ excretions were similar, but the Li+ decreased (0.78±0.06×10−2 vs. 0.32±0.03×10−2 μeq/min/100 g) in the EFAD group, giving additional support to the suggestion. Renal structure was normal and similar for
both groups, but the EFAD group showed a more prominent proximal tubule brush border, together with heavier periodic acid-Schiff
staining in all specimens from weeks 5 to 9. In the EFAD group, FA of the n−9 and n−7 series were higher, but most of the
n−6 series were lower as a percentage of total lipids in the medulla and cortex. Medullary levels of 20∶4n−6 were maintained,
22∶4n−6 declined twice, arachidonic acid was maintained, and 20∶5n−3 was lower. The EFAD diet affected glomerular function,
proximal tubular structure and function, and FA distribution in the rat kidney. 相似文献
57.
This article introduces a new method for model falsification using set‐valued observers, which can be applied to a class of discrete linear time‐invariant dynamic systems with time‐varying model uncertainties. In comparison with previous results, the main advantages of this approach are as follows: The computation of the convex hull of the set‐valued estimates of the state can be avoided under certain circumstances; to guarantee convergence of the set‐valued estimates of the state, the required number of previous steps is at most as large as the number of states of the nominal plant; and it provides a straightforward nonconservative method to falsify uncertain models of dynamic systems, including open‐loop unstable plants. The results obtained are illustrated in simulation, emphasizing the advantages and shortcomings of the suggested method. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
58.
Walter Soares Leal Antônio Ricardo Panizzi Cintia Carla Niva 《Journal of chemical ecology》1994,20(5):1209-1216
The alarm pheromone system ofLeptoglossus zonatus (Dallas) adults was shown to be composed of hexyl acetate, hexanol, hexanal, and hexanoic acid. Single components tested in the field elicited dispersive behavior of over 70% of adults. 2-(E)-Hexenal, found in the secretion of nymphs, but not in the exudates of adults, was also active against adults. In addition, first-instar nymphs responded to the four components of the alarm pheromone of adults as well as to 2-(E)-hexenal, a component of their own alarm pheromone system. Adults and nymphs possess different alarm pheromone systems, which are not specific to their own life stage. That hemipteran alarm pheromone systems are not species-specific was supported by the fact that both adult and nymphL. zonatus responded to butanoic acid, an alarm pheromone of Alydidae, which was not found in this Coreidae species. 相似文献
59.
Water Resources Management - This paper presents a case study conducted in the Upper Argos River, in southeast Spain, to verify the applicability of the SWAT model for prediction of the water... 相似文献
60.
Carla Marina Santos Feldhaus Roseli Künzel Máximo Siu Li Ana Paula de Azevedo Marques 《Journal of the American Ceramic Society》2021,104(10):5192-5204
The compounds based on calcium molybdate (CaMoO4) are the subject of extensive research due to their excellent optical properties and a broad range of potential technological applications. In this work, we report a systematic study of CaMoO4:Tm3+ phosphors synthesized by coprecipitation and processed in a microwave-hydrothermal system at low temperature (100°C) and stirring. The effect of the Tm3+ doping content (0%–12%) is studied in full detail to understand their role in the CaMoO4:Tm3+ morphological, structural, and luminescent properties. The X-ray diffraction, Raman, and Fourier Transform Infrared spectroscopic techniques revealed that all the prepared powders have a tetragonal crystal structure with a distinct density of cation vacancies and structural disorders. The band gap remains almost constant for doping levels lower than 8%, but it narrows strongly for powders doped with 12% Tm3+ ions. The designed phosphors have shown two emission bands in which intensity depends on the Tm3+ ions doping level. For doping levels lower than 2%, the photoluminescence profile displays a broad emission band peaking at 543 nm (green). For concentrations higher than 4%, the band centered at 543 nm decreases in intensity and the near-infrared emission band at around 800 nm, assigned to 3F3, 3H4 → 3H6 transitions from Tm3+ ion, become more intense. The outcomes of this work reveal that appropriated Tm3+ ions doping levels can be applied to suppress the PL emission in the visible range and improve that in the near-infrared region in CaMoO4-based materials. 相似文献