Measurement involving human perception and interpretation

The measurement of features related to human perception and interpretation is discussed. After a brief review of the historical framework, the state of the art is presented on the basis of the authors’ experience in the field and their participation in related European projects, with development of experiments, and co-ordination activities. Future research needs and challenges are then addressed.     

Samplinghelper a web-based tool to assess the reliability of sampling strategies in sewers and receiving waters

Sampling is a key step in the analysis of chemical compounds. It is particularly important in the environmental field, for example for wastewater effluents, wet-weather discharges or streams in which the flows and concentrations vary greatly over time. In contrast to the improvements that have occurred in analytical measurement, developments in the field of sampling are less active. However, sampling errors may exceed by an order of magnitude those related to analytical processes. We proposed an Internet-based application based on a sampling theory to identify and quantify the errors in the process of taking samples. This general theory of sampling, already applied to different areas, helps to answer questions related to the number of samples, their volume, their representativeness, etc. The use of the internet to host this application facilitates use of theoretical tools and raise awareness of the uncertainties related to sampling. An example is presented, which highlights the importance of the sampling step in the quality of analytical results.     

Flow measurements in sewers based on image analysis: automatic flow velocity algorithm

Discharges of combined sewer overflows (CSOs) and stormwater are recognized as an important source of environmental contamination. However, the harsh sewer environment and particular hydraulic conditions during rain events reduce the reliability of traditional flow measurement probes. An in situ system for sewer water flow monitoring based on video images was evaluated. Algorithms to determine water velocities were developed based on image-processing techniques. The image-based water velocity algorithm identifies surface features and measures their positions with respect to real world coordinates. A web-based user interface and a three-tier system architecture enable remote configuration of the cameras and the image-processing algorithms in order to calculate automatically flow velocity on-line. Results of investigations conducted in a CSO are presented. The system was found to measure reliably water velocities, thereby providing the means to understand particular hydraulic behaviors.     

Photo-degradation and stabilization effects in operating organic photovoltaic devices by joint photo-current and morphological monitoring

We report on a joint morphological/photoelectrical study of polymer-based photovoltaic (PV) cells in working conditions. The bulk heterojunction devices investigated are based on an active layer of poly(3-hexyl thiophene) blended with methano-fullerene, combining good PV performances with promising stability. The set-up adopted allowed the electrical properties of the device to be directly correlated to the modification of the electrode morphological parameters (thickness and roughness), which were obtained by in situ energy dispersive X-ray reflectometry (EDXR). The results of this joint time-dependent characterization demonstrated how the observed photo-induced oxidation process, limited to the buried electrode interface, is responsible for a fast decrease in the photo-current. The time-resolved measurements allowed to rule out the dynamics of the morphological changes and showed that the interface morphology may be stabilized by annealing treatments, with a significant improvement of the cell efficiency.     

Computerized planning of cryosurgery using bubble packing: An experimental validation on a phantom material

The current study focuses on experimentally validating a planning scheme based on the so-called bubble packing method. This study is a part of an ongoing effort to develop computerized planning tools for cryosurgery, where bubble packing has been previously developed as a means to find an initial, uniform distribution of cryoprobes within a given domain; the so-called force-field analogy was then used to move cryoprobes to their optimum layout. However, due to the high quality of the cryoprobe distribution suggested by bubble packing and its low computational cost, it has been argued that a planning scheme based solely on bubble packing may be more clinically relevant. To test this argument, an experimental validation is performed on a simulated cross-section of the prostate, using gelatin solution as a phantom material, proprietary liquid nitrogen-based cryoprobes, and a cryoheater to simulate urethral warming. Experimental results are compared with numerically simulated temperature histories resulting from planning. Results indicate an average disagreement of 0.8 mm in identifying the freezing front location, which is an acceptable level of uncertainty in the context of prostate cryosurgery imaging.     

Definition of Risk Indicators for Reservoirs Management Optimization

An alternative procedure for drought risk assessment and for the mitigation of drought risk is proposed in the paper. An analysis of the relationship between failure of water supply systems and reservoir volumes for the urban area of Firenze in central Tuscany, in central Italy, is performed. Long term simulations are carried out using the software package WEAP. A simplified model of the water resources system is built to assess the threshold values and the management rules. The probability to have definite degree of shortage in the water supply system is evaluated in function of the volume stored in the reservoir at the beginning of the month with Monte Carlo simulations. The reservoir levels and volumes are simulated using time series of the period 1970–2005. Four scenarios (i.e. normal, pre-alert, alert and emergency) associated with different levels of severity of drought are defined. Threshold values are identified considering the probability to assure a given fraction of the demand in a certain time horizon, and are calibrated with an optimization method, which try to minimize the water shortages, especially the heavier. The critical situations are assessed month by month in order to evaluate optimal management rules during the year and avoid conditions of total water shortage.     

Electroactive carbon nanotube actuators: Soft-lithographic fabrication and electro-chemical modelling

Carbon nanotube (NT) actuators were fabricated using the micromolding method. In order to prevent the nanotubes from aggregating, they were enclosed in a partially cross-linked polyvinylalcohol–polyallylamine matrix. A unimorph matrix bender in the form of a small multi-layered strip, 5 mm × 15 mm was fabricated. The resulting composite system: NT/PVA, solid polymer electrolyte and metal contact, was characterised using impedance analysis and cyclic voltammetry. Initial measurements on electro-mechanical transduction show a conversion efficiency of 0.2 μm/mV. An electrochemical model of the impedance of the system was then developed, with which the experimental results agree fairly well.