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61.
The flame retardant polypropylene containing the micro-envelope core-shell structure flame retardant, which encapsulated ammonium polyphosphate into melamine-formaldehyde resin and sodium silicate through in situ polymerization was prepared with polyamide 6, added as a carbon-forming agent. The composition of ammonium polyphosphate, encapsulated ammonium polyphosphate with melamine-formaldehyde resin and the micro-envelope core-shell structure flame retardant were characterized. The fire safety and thermal stability were investigated and showed an improvement including limiting oxygen index, thermogravimetric analysis, vertical burning tests, and microscale combustion calorimeter. The burned compounds were also studied to confirm the burning mechanism. The results showed the flame retardant performance had been greatly improved, while polyamide 6 had better char-forming effect. Besides, the water solubility of flame retardants and their influence on the mechanical properties of polypropylene were also investigated. The results on the effects of additives demonstrated a high efficiency flame retardant to polypropylene. A core-shell flame retardant that sodium silicate and melamine-formaldehyde resin-coated ammonium polyphosphate had been constructed. The effect of the built flame retardant system on the combustion performance of polypropylene was studied from the mechanism and performance. The LOI of the most flame retardant polypropylene reached 28.6%, and UL-94 reached the V-0 level. 相似文献
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Cleide Borsoi Betina Hansen Ruan Ezequiel Gemmer Marcos Aurélio Dahlem Júnior Edson Luiz Francisquetti Ademir José Zattera Ruth Marlene Campomanes Santana André Luis Catto 《应用聚合物科学杂志》2021,138(45):51350
This study presents the preparation of post-consumer polypropylene (r-PP) composites filled with 30 wt% yerba mate (YM) stick particles. To improve the fiber–matrix adhesion, three surface treatments were performed: alkaline treatment with sodium hydroxide (NaOH) and use of 3-aminopropyltriethoxysilane (APTS) and maleic anhydride graft polypropylene copolymer (PP-g-MA) as coupling agents. Mechanical properties including tensile, flexural, and impact resistance were determined, and chemical (Fourier transform infrared spectroscopy [FTIR]), physical (water absorption), and morphological analyses were performed. The main findings show that the treatments were efficient in improving the mechanical properties of the composites, with emphasis on the r-PP/YM30/APTS and r-PP/YM30/PP-g-MA composites, which proved to be superior in tensile, flexion and impact strength and absorption of water compared to the untreated composite. The morphological analysis showed a better interaction between the fiber and the polymeric matrix for the composites with YM/APTS and YM/PP-g-MA, which corroborates the results of tensile and flexural strength, as well as with the spectra of FTIR in which the chemical modification of the fibers is observed. However, the results show that these treatments are promising in obtaining composites with recycled matrix with better properties. 相似文献
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MODELLINGOFP/MFORMINGPROCESSESBYFEM¥Wei,Yuanping;Ruan,Xueyu(DepartmentofPlasticityTechnology,ShanghaiJiaoTongUniversity,Shang... 相似文献
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正向充液变薄拉深工艺的研究 总被引:2,自引:0,他引:2
提出了一种称为正向充液变薄拉深的工艺方法。从理论上推导出变薄成形传力区拉应力计算式,并采用软铝车削毛坯进行了正向充液变薄拉深试验。当液压达到了120MPa时,车削铝毛坯的极限变薄拉深系数由0.5减小到0.3,说明正向充液变薄拉深工艺能有效地提高一次变薄拉深成形极限。 相似文献
68.
Microstructures of mechanically activated Ti-46at.% Al powders and spark plasma sintered ultrafine TiAl alloy 总被引:1,自引:0,他引:1
Powder of Ti-46at.%Al was synthesized through mechanical activation (MA) for different milling times, and the 16 h MAed powder was sintered by using a spark plasma sintering (SPS) process at different sintering temperatures. The XRD profiles showed that the MAed Ti-46at%Al powder for 12,16, and 20 h contained initial α-Ti and Al phases, and that the SPSed TiAl alloys contained the gamma TiAl and α2-Ti3Al phases. The TEM showed two different types of regions in the 16 h MAed Ti-46at.%Al powder. One type consisted of only Al with a grain size about 80 nm, and the other type a mixture of Al and Ti with a grain size of 30 nm. According to the optical micrographs of MA-SPSed samples, the alloys sintered at higher temperatures showed a coarser microstructure. In the case of the 1473 K sintering, typical duplex structures ((α2 + γ) lamella and γ phases) with interlamellar spacings of 50-400 nm and the grain size either less man 100 nm, or 1000 nm were observed. 相似文献
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板料成形数值模拟的关键技术及难点 总被引:14,自引:4,他引:14
本文结合国内外板料成形数值模拟的最新研究动态,从关键算法、屈服函数、本构方程、有限元列式、接触问题、破裂准则、回弹计算、起皱分析八个方面叙述了板料成形有限元计算的关键技术及主要难点。 相似文献