用于氢化的铜铬氧化物催化剂的研究

通过铜铬氧化物催化剂用于豆油的选择氢化,研究了制备方法及氢化条件对催化剂活性的影响.在所用的五种催化剂中,以Adkins法制备的催化剂活性最好,碳酸氢铵法次之.文中还对催化剂焙烧气氛、焙烧温度、焙烧时间、铜铬原子比对催化剂活性的影响以及氢化温度、催化剂用量、搅拌速度、氢流速等对反应的影响进行了较详细的讨论.     

Investigation on Ballistic Performance of Armor Ceramics against Long-Rod Penetration

A series of depth-of-penetration (DOF) tests are carried out to investigate the ballistic performance of armor ceramics. Based on the experimental results, an improved differential efficiency factor (DEF) is presented, which demonstrates that the general ballistic efficiency index is independent of the ceramic thickness. It is also shown that the density, internal friction, and compression strength of ceramics are crucial factors that affect the ballistic performance of ceramics significantly through the interaction between the long-rod projectiles and thick-tile armor. This article is based on a presentation made in the symposium entitled “Dynamic Behavior of Materials,” which occurred during the TMS Annual Meeting and Exhibition, February 25–March 1, 2007 in Orlando, Florida, under the auspices of The Minerals, Metals and Materials Society, TMS Structural Materials Division, and TMS/ASM Mechanical Behavior of Materials Committee.     

Guest Editors' Introduction: Human-Centered Computing--Toward a Human Revolution

Human-centered computing studies the design, development, and deployment of mixed-initiative human-computer systems. HCC is emerging from the convergence of multiple disciplines that are concerned both with understanding human beings and with the design of computational artifacts.     

A region-based selective optical flow back-projection for genuine motion vector estimation

Motion vector plays one significant feature in moving object segmentation. However, the motion vector in this application is required to represent the actual motion displacement, rather than regions of visually significant similarity. In this paper, region-based selective optical flow back-projection (RSOFB) which back-projects optical flows in a region to restore the region's motion vector from gradient-based optical flows, is proposed to obtain genuine motion displacement. The back-projection is performed based on minimizing the projection mean square errors of the motion vector on gradient directions. As optical flows of various magnitudes and directions provide various degrees of reliability in the genuine motion restoration, the optical flows to be used in the RSOFB are optimally selected based on their sensitivity to noises and their tendency in causing motion estimation errors. In this paper a deterministic solution is also derived for performing the minimization and obtaining the genuine motion magnitude and motion direction.     

65钢冶炼浇铸工艺实践

介绍了采用转炉-LF炉-连铸生产65高碳钢的生产工艺，对铸坯质量及相关工序效果进行了分析。生产实践表明，采用的65钢工艺生产是可行的，铸坯质量能满足用户要求。     

转炉冶炼20管坯钢生产实践

介绍了20#管坯钢的生产试验工艺，采取了拉碳法脱碳、钢包底吹氩及喂丝、保护浇铸、合理控制拉速等有效措施，解决了生产中存在的质量问题，为下一步的生产提供了理论和实践依据。     

剖析半悬挂减速机故障的产生与对策

介绍了半悬挂减速机的工作原理，分析其故障原因，实施相应的解决对策。     

精铸件结构优化设计实践

以6种典型的精密铸件为例，利用“6个千方百计”原则对产品结构进行优化设计，同时辅助有限元分析对优化结果进行再验证。通过减少大平面、避免深长孔、采用加强筋等优化措施，有效地避免了夹砂、鼓包、跑火、缩孔、裂纹等铸造缺陷，实现了少无切削和减轻铸件质量。     

Molecular recognition of diketide substrates by a beta-ketoacyl-acyl carrier protein synthase domain within a bimodular polyketide synthase

BACKGROUND: Modular polyketide synthases (PKSs) are large multifunctional proteins that catalyze the biosynthesis of structurally complex bioactive products. The modular organization of PKSs has allowed the application of a combinatorial approach to the synthesis of novel polyketides via the manipulation of these biocatalysts at the genetic level. The inherent specificity of PKSs for their natural substrates, however, may place limits on the spectrum of molecular diversity that can be achieved in polyketide products. With the aim of further understanding PKS specificity, as a route to exploiting PKSs in combinatorial synthesis, we chose to examine the substrate specificity of a single intact domain within a bimodular PKS to investigate its capacity to utilize unnatural substrates. RESULTS: We used a blocked mutant of a bimodular PKS in which formation of the triketide product could occur only via uptake and processing of a synthetic diketide intermediate. By introducing systematic changes in the native diketide structure, by means of the synthesis of unnatural diketide analogs, we have shown that the ketosynthase domain of module 2 (KS2 domain) in 6-deoxyerythronolide B synthase (DEBS) tolerates a broad range of variations in substrate structure, but it strongly discriminates against some others. CONCLUSIONS: Defining the boundaries of substrate recognition within PKS domains is crucial to the rationally engineered biosynthesis of novel polyketide products, many of which could be prepared only with great difficulty, if at all, by direct chemical synthesis or semi-synthesis. Our results suggest that the KS2 domain of DEBS1 has a relatively relaxed specificity that can be exploited for the design and synthesis of medicinally important polyketide products.     

双层辉光离子渗镀钽

介绍了一种新型离子渗镀钽的工艺方法。较好解决了渗镀钽时供给活性钽粒子的总是比方法工艺简单，操作方便，效率高。为充分利用和节约使用昂贵的钽探索了一条实用可行的途径。