Substituent-Induced Supramolecular Aggregates of Edge Functionalized Nanographenes

Precisely controlled molecular assemblies often display intriguing morphologies and/or functions arising from their structures. The application of the concept of the self-assembly for controlling the aggregation of nanographenes (NGs) is challenging. The title NGs are those carrying both long alkyl chains and tris(phenylisoxazolyl)benzene (TPIB) on the edge. The former group secures the affinity of NGs for organic solvents, and the latter group drives the 1D arrangement of NGs through the interactions between the TPIB units. The concentration-dependent and temperature variable ¹H NMR, UV–vis, and PL spectra demonstrate the aggregation of NGs in 1,2-dichloroethane, and the aggregation is controllable by the regulation of the solvent polarity. AFM images give the stacked structures of the NGs, and these aggregates turn out to be network polymeric structures at a high concentration. These observations demonstrate that the synergy of the face-to-face interactions between the surfaces and the interactions between the TPIB units are effective for controlling the self-assembly of the NGs.     

3D Visualization of Morphological Evolution of Large Defects during Spark Plasma Sintering of Alumina Granules

The mechanical reliability of products must be assured for scaling up and production of complex-shaped components by spark plasma sintering (SPS) of spray-dried granules. The evolution of morphologies of pores and defects, which control the mechanical strength, is investigated by using synchrotron X-ray multiscale tomography during SPS of alumina granules at 1300 °C. While large defects arising from the hierarchical granule packing structure cannot be removed by pressureless sintering, crack-like defects and branched rodlike defects are almost eliminated by SPS at stresses higher than 30 and 50 MPa, respectively. But, small ellipsoidal porous regions, which may arise from aggregates or dimples of granules, cannot be removed even at a pressure of 50 MPa. A very large defect is also found by using micro-CT. It is supposed that this defect is formed from a large void in loosely packed granules. The shrinkage of large voids and the elimination of crack-like defects are explained by the theoretical prediction based on the continuum theory of sintering.     

Oxidation behavior of ytterbium silicide

Si-rich ytterbium silicide was fabricated by through an arc-melting technique for applying use as a bond coat material in an environmental barrier coating system. Evaluation of its potential was accomplished through oxidation tests in dry air and an inert atmosphere. The experimental results showed that the changes in weight and morphologies of ytterbium silicide observed after the tests depended on the oxygen partial pressure. Extensive oxidation and weight gain occurred after oxidation in air. In order to apply this material for hot structures, improvement of the oxidation resistance is needed.     

A Simple Pneumatic Loading System Controlling Stress and Strain Rates for One-Dimensional Compression of Clay

A simple but automated pneumatic loading system that can control the stress and strain rates for one-dimensional (1D) compression of clay was developed. The rate-dependency of stress-strain behaviour due to the viscous property of clay was investigated by 1D compression tests on standard-size specimens by various loading methods: 1) Standard Consolidation Tests (SCTs), stepwise increasing the axial stress two times every one day; 2) ordinary Constant-Rate-of-Strain (CRS) tests at different strain rates; 3) special CRS tests including unloading and reloading cycles with different stress amplitudes at strain rates of which the absolute value was either kept constant throughout respective tests or changed at the start of reloading; and 4) special CRS tests including a number of sustained loading (SL) during otherwise primary loading or unloading or reloading at constant strain rate. Sufficiently low strain rates were employed to ensure essentially fully drained condition. The followings were found. Despite that the newly developed pneumatic loading system is rather simple, 1D compression tests following such various loading histories as above can be performed on four types of clay rather accurately. The stress-strain behaviour of clay is significantly rate-dependent, exhibiting significant creep strains at SL stages. The creep strain rate is significantly different whether SL starts during otherwise primary loading or unloading or reloading, controlled by the magnitude and sign of the initial strain rate at the start of SL. The whole observed trends of rate-dependent stress-strain behaviour can be qualitatively explained by the non-linear three-component elasto-viscoplastic model extended to cyclic loading conditions.     

Methodology to optimize radiation protection in radioactive waste disposal after closure of a disposal facility based on probabilistic approach

We propose a methodology to optimize radiation protection in radioactive waste disposal after the closure of a disposal facility based on a probabilistic approach. In this methodology, a set of alternative options of the disposal system design with the associated uncertainties estimated through a probabilistic approach are developed. Then, the methodology evaluates the advantages and disadvantages of each option for the optimization of radiation protection, in which it is possible to determine the compliance with a dose constraint of 0.3 mSv/y and to collect information for making a decision on the optimization. In particular, the obtained information on the exposure, which is the mode and width of the dose distribution, can be converted into information on engineering measures and site conditions for the options. This process allows us to discuss which option should be selected as the optimal option by considering the balance between the exposure and the engineering, economic, and social feasibility of the option. This methodology is helpful for providing clear reasons why an optimal disposal system design is selected by combining quantitative information on the exposure and the feasibility of each option.     

Influence of tungsten–carbon mixed layer and irradiation defects on deuterium retention behavior in tungsten

The D₂⁺ fluence dependence on deuterium (D) retention was studied to clarify the D retention mechanism in tungsten. The additional D desorption stage was observed around 660 K in the TDS spectrum for a sample implanted with D₂⁺ up to the fluence of 10²³ D⁺ m^?2, which desorption stage was not observed the D₂⁺ implanted sample with the fluence less than 10²² D⁺ m^?2. The TEM observation showed that the highly dense voids were formed in tungsten by D₂⁺ implantation with the fluence of 10²³ D⁺ m^?2, considering that the D would be trapped by voids. To understand the D trapping by voids in C⁺ implanted tungsten, C⁺–D₂⁺ sequential implantation experiments at various C⁺ implantation temperatures were performed. It was found that the amount of D desorbed around 560 K was increased by increasing the C⁺ implantation temperature. The formation of the voids was observed with increasing the C⁺ implantation temperature by TEM, indicating that the increase of D desorption around 560 K was caused by the formation of voids. However, the desorption temperature of D trapped by voids in C⁺ implanted sample was lower than that in D₂⁺ implanted one. TEM observation and XPS measurement indicated that this difference was caused by the increase of void size and/or the presence of implanted carbon.     

JSFR key technology evaluation on fuel handling system

A simplified fuel handling system design for the demonstration Japan sodium-cooled fast reactor (JSFR) has been proposed. Fast Reactor Cycle Technology Development project phase I results of key technology evaluations on a pantograph fuel handling machine (FHM), a fuel transfer pot with two core component positions, dry spent fuel cleaning and minor actinide-bearing fresh fuel shipping cask are summarized. A full-scale FHM mockup has been fabricated and tested in the air accumulating performance and seismic tolerance data. A mockup fuel transfer pot with fins and chromium carbide coating has been fabricated and tested with sodium accumulating heat transfer performance data. Several sodium cleaning tests using a dummy subassembly has been conducted accumulating cleaning performance data. For fresh fuel shipping cask, a design tool for evaluation of heat transfer capability has been developed and a helium gas cask shows cooling capability of minor actinide-bearing fresh fuel. Those experimental and analytical efforts have shown that key technologies to develop simplified fuel handling system are matured enough to proceed large-scale sodium experiments and conceptual design study for the demonstration JSFR.     

Effect of fasting subjects'' posture on 13C-urea breath test for detection of Helicobacter pylori infection

HIV-associated salivary gland disease (HIV-SGD) includes lymphoepithelial lesions and cysts involving the salivary gland tissue and/or intraglandular lymph nodes, and Sj?gren-like conditions. Three cases of salivary gland disease occurring in HIV-infected patients are reported. Histopathological examination showed squamous epithelium-lined cysts. In the walls of the cysts lymphoid tissue, epitheloid granulomas and giant cells were found. The clinical and histopathological criteria as well as magnetic resonance imaging and therapy are discussed.     

Short‐current pulse‐based adaptive maximum‐power‐point tracking for a photovoltaic power generation system

This paper focuses on a maximum‐power‐point tracking method of photovoltaics via use of the short‐current pulse. It has been reported that the optimum operating current is proportional to the short current and that maximum‐power‐point tracking can be performed by detecting the short current. The proposed method utilizes the intermittent short‐current pulse to estimate the optimum operating current and its operating characteristics have experimentally been verified. Also, an adaptive mechanism to identify the parameter between the optimum current and the short current is discussed. A prototype of the controller has been set up and the experimental results have demonstrated excellent performance, proving the feasibility of the system. © 2002 Scripta Technica, Electr Eng Jpn, 139(1): 65–72, 2002; DOI 10.1002/eej.1147