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991.
Jun Young Kim Ji Won Lee Young Soo Kim Yuno Lee Dr. Young Bae Ryu Songmi Kim Hyung Won Ryu Marcus J. Curtis‐Long Prof. Dr. Keun Woo Lee Dr. Woo Song Lee Prof. Dr. Ki Hun Park 《Chembiochem : a European journal of chemical biology》2010,11(15):2125-2131
Competitive glycosidase inhibitors are generally sugar mimics that are costly and tedious to obtain because they require challenging and elongated chemical synthesis, which must be stereo‐ and regiocontrolled. Here, we show that readily accessible achiral (E)‐1‐phenyl‐3‐(4‐strylphenyl)ureas are potent competitive α‐glucosidase inhibitors. A systematic synthesis study shows that the 1‐phenyl moiety on the urea is critical for ensuring competitive inhibition, and substituents on both terminal phenyl groups contribute to inhibition potency. The most potent inhibitor, compound 12 (IC50=8.4 μM , Ki=3.2 μM ), manifested a simple slow‐binding inhibition profile for α‐glucosidase with the kinetic parameters k3=0.005256 μM ?1 min?1, k4=0.003024 min?1, and ${K{{{\rm app}\hfill \atop {\rm i}\hfill}}}$ =0.5753 μM . 相似文献
992.
Taegong Ryu Miguel Olivas-Martinez Hong Yong Sohn Z.Z. Fang Terry A. Ring 《Chemical engineering science》2010,65(5):1773-1780
The chemical vapor synthesis (CVS) reactor for the preparation of WC nanopowder from tungsten hexachloride was simulated by a two-dimensional multiphase computational fluid dynamics (CFD) model. The model solves the gas-phase governing equations of overall continuity, momentum, energy, and species mass transport inside a tubular reactor system. The population balance model is coupled with the gas-phase equations to describe the formation and growth of WC nanoparticles. The model has been validated with experimental data in terms of average particle size and concentration of unreacted precursor at the outlet. The contours of temperature, velocity, species concentration and particle size distribution (PSD) inside the tubular reactor were computed. 相似文献
993.
Two years after the Hebei Spirit oil spill: residual crude-derived hydrocarbons and potential AhR-mediated activities in coastal sediments 总被引:2,自引:0,他引:2
Hong S Khim JS Ryu J Park J Song SJ Kwon BO Choi K Ji K Seo J Lee S Park J Lee W Choi Y Lee KT Kim CK Shim WJ Naile JE Giesy JP 《Environmental science & technology》2012,46(3):1406-1414
The Hebei Spirit oil spill occurred in December 2007 approximately 10 km off the coast of Taean, South Korea, on the Yellow Sea. However, the exposure and potential effects remain largely unknown. A total of 50 surface and subsurface sediment samples were collected from 22 sampling locations at the spill site in order to determine the concentration, distribution, composition of residual crudes, and to evaluate the potential ecological risk after two years of oil exposure. Samples were extracted and analyzed for 16 polycyclic aromatic hydrocarbons (PAHs), 20 alkyl-PAHs, 15 aliphatic hydrocarbons, and total petroleum hydrocarbons using GC-MSD. AhR-mediated activity associated with organic sediment extracts was screened using the H4IIE-luc cell bioassay. The response of the benthic invertebrate community was assessed by mapping the macrobenthic fauna. Elevated concentrations of residual crudes from the oil spill were primarily found in muddy bottoms, particularly in subsurface layers. In general, the bioassay results were consistent with the chemistry data in a dose-dependent manner, although the mass-balance was incomplete. More weathered samples containing greater fractions of alkylated PAHs exhibited greater AhR activity, due to the occurrence of recalcitrant AhR agonists present in residual oils. The macrobenthic population distribution exhibits signs of species-specific tolerances and/or recolonization of certain species such as Batillaria during weathering periods. Although the Hebei Spirit oil spill was a severe oil exposure, it appears the site is recovering two years later. 相似文献
994.
Ho-Young Cha Juhwan Choi Han Sik Ryu Jin Hwan Choi 《Journal of Mechanical Science and Technology》2011,25(7):1687-1694
Contact force of Multi-body dynamics (MBD) system can be classified two parts. First is a normal force and the other is a
tangential force called friction force. And the friction force can be represented by two states such as stick and slip. The
stick-slip phenomenon is simply described as a simple contact model which is a rigid body contacted on a sloped surface. If
the calculated friction coefficient between the body and sloped surface is less than the static friction coefficient, the
body should be stuck. If the calculated friction coefficient is greater than the static friction coefficient, the body will
be sliding along the surface. The phenomenon is called as stick and slip state of friction, respectively. Usually many researchers
and commercial MBD software used a coulomb friction force model which is defined with an only function of relative velocity.
This kind of friction force model will be called a conventional friction force model in this paper. A big problem of the conventional
model can not describe a stick state of friction phenomenon. In the case of conventional friction force model, the body will
be sliding even though friction state is stick. Because, the relative velocity must have a non-zero value in order to generate
the friction force. To solve this kind of problem, we propose a stick-slip friction force model including a spring like force.
In the case of stick-slip friction force model, the body can be stuck on the sloped surface because the friction force will
be a non-zero value, even though the relative velocity approaches zero. We defined a relative displacement variable called
stiction deformation. In this paper, the stick-slip friction model is proposed and applied in the contact algorithm of MBD
system. And then two friction models are compared with numerical examples. With the proposed stick-slip friction model, more
realistic results are achieved. 相似文献
995.
The stabilization characteristics of liftoff and blowoff in nonpremixed laminar jet flames in a coflow have been investigated experimentally for propane fuel by applying AC and DC electric fields to the fuel nozzle with a single-electrode configuration. The liftoff and blowoff velocities have been measured by varying the applied voltage and frequency of AC and the voltage and the polarity of DC. The result showed that the AC electric fields extended the stabilization regime of nozzle-attached flame in terms of jet velocity. As the applied AC voltage increased, the nozzle-attached flame was maintained even over the blowout velocity without having electric fields. In such a case, a blowoff occurred directly without experiencing a lifted flame. While for the DC cases, the influence on liftoff was minimal. There existed three different regimes depending on the applied AC voltage. In the low voltage regime, the nozzle-detachment velocity of either liftoff or blowoff increased linearly with the applied voltage, while nonlinearly with the AC frequency. In the intermediate voltage regime, the detachment velocity decreased with the applied voltage and reasonably independent of the AC frequency. At the high voltage regime, the detachment was significantly influenced by the generation of discharges. 相似文献
996.
997.
Kyung Ha Ryu Il Soon Hwang Young Jin Oh Jin Ho Park 《Nuclear Engineering and Design》2008,238(12):3263-3268
Flow accelerated corrosion (FAC) phenomenon has persisted its impact on plant reliability and personnel safety. Unless we change the operation condition drastically, most parameters affecting FAC will not be effectively controlled. In order to help expand piping inspection coverage, we have developed a screening approach to monitor the wall thinning by direct current potential drop (DCPD) technique. To improve the applicability to the complex piping network such as the secondary cooling water system in PWR's, we devised the equipotential control method that can eliminate undesired leakage currents outside a measurement section. In this paper, we present Wide Range Monitoring (WiRM) and Narrow Range Monitoring (NaRM) with Equipotential Switching Direct Current Potential Drop (ES-DCPD) method to rapidly monitor the thinning of piping. Based on the WiRM results, susceptible locations can be identified for further inspection by ultrasound technique (UT). On-line monitoring of a thinned location can be made by NaRM. Finite element analysis results and a closed-form resistance model are developed for the comparison with measured wall thinning by the developed DCPD technique. Verification experiments were conducted using UT as the reference. The result shows that model predictions and the experimental results agree well to confirm that both WiRM and NaRM based on ES-DCPD can be applicable to FAC management efforts. 相似文献
998.
LVA Reddy Young‐Jung Wee Hwa‐Won Ryu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(11):1526-1533
BACKGROUND: Purification and characterization of a novel protease produced by Bacillus sp. RKY3, has been investigated, with special emphasis on the stability of the enzyme in the presence of different oxidizing and reducing agents as well as organic solvents. The enzyme was purified in two steps through concentration of the crude enzyme by ammonium sulfate precipitation, followed by anion exchange chromatography. RESULTS: The purified protease had a molecular mass of approximately 38 kDa, which was highly active over a broad range of pH between 7.0 and 9.0 and was also stable over a wide pH range from 5.0 to 11.0. Although the optimum temperature for enzyme activity was found to be 60 °C, it was rapidly deactivated at temperatures above 60 °C. It also showed good stability at 50 °C, with a 70 min half‐life. Ca2+ ions did not greatly enhance the activity or the stability of the enzyme. PMSF (1 mmol L?1) completely inhibited the protease activity, and thus the purified protease was considered to be serine protease. The purified protease was stable with oxidants (H2O2, 2%), reducing agents (sodium dodecyl sulfate, 2%), and organic solvents (25%) such as benzene, hexane, and toluene. CONCLUSION: The purified enzyme, protease, seems to possess potential applications in protease‐based detergent and bleaching industries. The enzymatic activity against a wide variety of substrates suggests that the purified enzyme should be investigated for a range of commercial applications, especially for soy protein and gelatin hydrolysis in the food processing industry. Copyright © 2008 Society of Chemical Industry 相似文献
999.
1000.