Application of Romero García method to the degradation process of DGEBA/ETDA filled with ultra fine metallic copper

Summary The thermal properties of an epoxy resin (diglycidyl ether Bisphenol A, DGEBA) cured with a primary amine (ethylenediamine, ETDA) and filled with 10, 20 and 30 wt. % of ultra fine copper particles were analyzed. The thermal results were evaluated by means of the Romero-Garcia method, which allowed to obtain the resin degradation kinetic parameters, as well as the possible decomposition mechanism. From the obtained results is possible to infer that higger copper content strongly affects the degradation process of the epoxy resin, which causes a drop off on the composites thermal stability. This behavior could be attributed to water presence, being this effect less pronounced for the resin with 10 wt. % copper and unfilled resin. Regarding to decomposition mechanism, three way transport showed the best correlation for all samples.     

A family of highly symmetric codes

We define a class of codes admitting a large automorphism group. This family contains the binary extended Hamming code, the hexacode, the Golay codes, the Pless symmetry codes, as well as the [16,4,12]/sub 8/-codes constructed by Marcugini et al. A computer search resulted in the construction of codes with new parameters [28,7,18]/sub 8/,[32,8,20]/sub 8/, and [39,13,17]/sub 4/ belonging to this family.     

Electroluminescence spectroscopy for reliability investigations of 1.55 μm bulk semiconductor optical amplifier

This paper demonstrates the complementary relation between functional parameters and electroluminescence spectroscopy for reliability investigations of 1550 nm Semiconductor Optical Amplifiers of 700 μm length active region. Ageing tests have been set to 270 mA-100 °C-1500 h and realized on two different wafers showing more impact on wafer 1 than on wafer 2. Our investigations are particularly focused on interpretation of electroluminescence spectra, from reference and aged SOAs of wafer 1, leading to an improvement of degradation mechanisms understanding. The shift rate to lower energies of the recombination energy peak at 1550 nm, as reported by electroluminescence spectra between reference and aged SOAs in relation with the decrease of optical power measured at 200 mA for the degraded SOA and completed by I(V) characterizations, suggest occurrence of non radiative deep centers near the buried ridge structure in relation with the cleaning process uniformity of interfaces before epitaxial overgrowth. These defects mainly trap majority injected carriers instead of minority carriers reducing the luminescence in the active zone. By monitoring the most sensitive failure indicator (pseudo-threshold current), lifetime distributions are also calculated to determine failure rate, between 150 and 200 FITs over 15 years for operating conditions (25 °C-200 mA) using experimental degradation laws and statistic computations, demonstrating the overall robustness of this technology.     

Parathion degradation and toxicity reduction in solar photocatalysis and photolysis.

The solar photocatalytic degradation of methyl parathion was investigated using a circulating TiO2/solar light reactor. Under solar photocatalysis condition, parathion was more effectively degraded than solar photolysis and TiO2-only conditions. With solar photocatalysis, 20 mg/L of parathion was completely degraded within 60 min with a TOC decrease of 63% after 150 min. The main ionic byproducts during photocatalysis recovered from parathion degradation were mainly as NO3-, NO2- and NH4+, 80% of the sulphur as SO4(2-), and 5% of phosphorus as PO4(3-). The organic intermediates 4-nitrophenol and methyl paraoxon were also identified, and these were further degraded in solar photocatalytic condition. Two different bioassays (Vibrio fischeri and Daphnia magna) were used to test the acute toxicity of solutions treated by solar photocatalysis and photolysis. The Microtox test using V. fischeri showed that the toxicity expressed as EC50 (%) value increased from 5.5% to >82% in solar photocatalysis, indicating that the treated solution is non-toxic, but only increased from 4.9 to 20.5% after 150 min in solar photolysis. The acute toxicity test using D. magna showed that EC50 (%) increased from 0.05 to 1.08% under solar photocatalysis, but only increased to 0.12% after 150 min with solar photolysis, indicating the solution is still toxic. The pattern of toxicity reduction parallels the decrease in TOC and the parathion concentrations.     

The 'Conceptual Change In Science' project

Abstract This paper outlines the work of the Conceptual Change in Science project, funded as part of the ESRC InTER programme. The aims of this research project are to clarify and describe the process of change in learners' conceptual understandings of natural phenomena. The domain of reasoning selected for study is that of mechanics. Computer software which may be useful in exploring and developing pupils' reasoning and promoting conceptual change in this domain is being developed and evaluated. The group that is carrying out the research is based at the Universities of Leeds, Glasgow and the Open University.     

Satellite-to-Satellite Range-Rate Measurement

The measurement of range rate between two low-orbiting spacecraft with a precision of better than 1 ?m/s provides a means for sensing global gravity variability. An analysis is given to show the conditions under which this precision can be realized, with emphasis on the requirements of NASA's Geopotential Research Mission. Experimental results obtained with a millimeter-wave demonstration system are presented along with a proposed design for a spaceborne instrument.     

Reconstruction of the friction units of turbine guide vanes

Conclusions After the almost 2-yr operation of the gate apparatus since the start of reconstruction of friction units of the vanes, we can make a preliminary evaluation of the effectiveness of the works:There is practically no leakage of water through the gate vanes to the turbine cover, which led to a complete unloading of the drainage pumps on the turbine cover and the efficiency of operating the gate apparatus increased considerably.Repair of the gate apparatus is not required during maintenance.There is no vibration of the gate vanes, since the gaps in the friction units of the journals of the gate vanes are minimum and stable.The operating personnel objectively evaluate highly the work of the gate apparatus of the turbine after reconstruction and will continue this work on the remaining turbines.Translated from Gidrotekhnicheskoe Stroitel'stvo, No. 9, pp. 12–14, September, 1985.     

Changing the hydrogen content of alloy steel in relation to the technology used to cool cast slabs

Results are reported from the production of two trial heats of alloy steel in which the cast slabs were cooled in a thermostatted chamber and in a dense stack. It is shown that cooling slabs in such a chamber makes it possible to reduce the hydrogen content of the steel 30% compared to slabs that are cooled while stacked.     

Time-series detection of perspiration as a liveness test in fingerprint devices

Fingerprint scanners may be susceptible to spoofing using artificial materials, or in the worst case, dismembered fingers. An anti-spoofing method based on liveness detection has been developed for use in fingerprint scanners. This method quantifies a specific temporal perspiration pattern present in fingerprints acquired from live claimants. The enhanced perspiration detection algorithm presented here improves our previous work by including other fingerprint scanner technologies; using a larger, more diverse data set; and a shorter time window. Several classification methods were tested in order to separate live and spoof fingerprint images. The dataset included fingerprint images from 33 live subjects, 33 spoofs created with dental material and Play-Doh, and fourteen cadaver fingers. Each method had a different performance with respect to each scanner and time window. However, all the classifiers achieved approximately 90% classification rate for all scanners, using the reduced time window and the more comprehensive training and test sets.     

Computer-controlled ion-selective electrode switch

The construction of a microcomputer-controlled electrode switch for use in potentiometric determinations is described. This can be coupled to most of the analytical equipment usually found in laboratories, to enable a setting up of automatic systems capable of performing sequential determinations with several ion-selective electrodes. The assessment of its analytical usage and behaviour are discussed.