The use of doped polyaniline as an electrode in the galvanic anodic protection of ferrous metals in industrial acid solutions

In order to investigate the galvanic anodic protection (GAP) of ferrous metals (such as 410, 304 and 316 stainless steels) in acid solutions by doped polyaniline (PANi), separate doped PANi powder-pressed electrodes with different surface areas (the area ratio of the PANi electrode to stainless steel is between 1:1 and 1:2) have been prepared. These were coupled with ferrous metal in the following solutions: 5 M sulphuric acid, 5 M phosphoric acid and industrial phosphoric acid (containing 5 M phosphoric acid and 0.05% chloride ion) to construct a galvanic cell, in which PANi is cathode while ferrous metal is anode. The results indicate that a PANi electrode with sufficient area can provide corrosion protection to stainless steel in these acidic solutions. A pilot scale coupling experiment was carried out. The results indicate that PANi is a promising material as an electrode for the anodic protection of ferrous metals in acidic solutions in industrial situations.     

On constructivity of involutive divisions

In the paper, the problem of existence of the minimal involutive monomial basis is considered for different involutive divisions. The existence criterion is obtained in the form of a constructivity property. In the paper, new examples of constructive and nonconstructive (> σ)-divisions are presented.     

Aggregation of Induction Motor Loads for Transient Stability Studies

This study investigates the dynamic representation of a group of induction motors by one or more equivalent motors. The unknown parameters of the equivalent are estimated through a weighted-least-squares procedure. Verification of simulated results with experimental ones suggests that a fifth order dynamic model of the aggregate with a ninth order parameter model is appropriate. The least squares technique was found to provide good convergence characteristics subject to satisfaction of the following conditions good initial estimate of the parameters, proper selection of acceleration factors and homogenity of the motor group.     

Optical performance of a composite parabolic trough

The effects of receiver misplacement and the trough pointing towards the sun on the concentration characteristics of a composite parabolic trough are discussed. Results from some numerical calculations are presented graphically and discussed.     

Effects of free convection and mass transfer on the flow past an impulsively moving infinite vertical circular cylinder

The effects of free convection and mass transfer are taken into account for the Stokes' problem of the flow near an impulsively moving infinite vertical circular cylinder. Expressions of the velocity, temperature, concentration and skin friction of the fluid in closed form are obtained by the Laplace transform technique. The results based on various values of the parameters Gr (Grashof number), Gm (modified Grashof number), Sc (Schmidt number) and Pr (Prandtl number) are given in graphical form. It will be seen that there is a rise in the velocity due to the presence of a foreign mass. But higher Sc yields the lower velocity and skin friction. As the radius of the circular cylinder approaches to infinite, the results presented in this paper agree with those of V.M. Soundalgekar's and C.K. Chen's etc. for the flow past an impulsively moving infinite vertical plate.     

Wind flow patterns about buildings

A knowledge of building wake characteristics is useful in a variety of applications including dispersion of pollutants downwind of conventional or nuclear power plants, airport runway interference effect, take-off/landing limitations at heliports, pedestrian wind comfort, and wind loads on structures. Recent investigations have advanced both understanding of physical flow processes occurring in the near and far wake regions and theoretical predictive capability for flow and diffusion in the far wake region. These studies have shown, for example, that separation cavities immediately downwind are not enclosed by free streamlines as in two-dimensional separation/reattachment, that organized vortices can play an important role in wake development, and that theoretical solutions for some wake regions are possible.     

Increasing the corrosion resistance of low-alloy and carbon steels for automobile construction by optimizing the metallurgical technology

It is shown that the corrosion resistance of automobile sheet can be improved by ensuring that steels of this type have a low content of corrosion-active nonmetallic inclusions (CANI). The main mechanisms responsible for the formation of CANI in automobile sheet have been established, and recommendations have been developed to reduce their concentration in this product • optimize the deoxidation processes that are used by ensuring that the proportions of the additions made to the steel are consistent with the composition of the ladle slag and that certain key temperature-time parameters of these processes are maintained • control the composition of the ladle slag to prevent the formation of solid phases in the slag and their transfer to the metal; certain conditions must also be observed in the argon blow and the introduction of the addtions. Use of the above recommendations to make automobile sheet and tube steels cleaner with respect to their content of CANI and thus help optimize out-of-furnace treatments at metallurgical and pipe plants will make it possible to improve the corrosion resistance of metal products used in automotive manufacturing. __________ Translated from Metallurg, No. 2, pp. 45–48, February, 2006.     

Development of an empirical mathematical model for describing and optimizing the hygiene potential of a thermophilic anaerobic bioreactor treating faeces.

Poor sanitation and insufficient disposal of sewage and faeces are primarily responsible for water associated health problems in developing countries. Domestic sewage and faeces are prevalently discharged into surface waters which are used by the inhabitants as a source for drinking water. This paper presents a decentralized anaerobic process technique for handling of such domestic organic waste. Such an efficient and compact system for treating faeces and food waste may be of great benefit for developing countries. Besides a stable biogas production for energy generation, the reduction of bacterial pathogens is of particular importance. In our research we investigated the removal capacity of the reactor concerning pathogens, which has been operated under thermophilic conditions. Faecal coliforms and intestinal enterococci have been detected as indicator organisms for bacterial pathogens. By the multiple regression analysis technique an empirical mathematical model has been developed. The model shows a high correlation between removal efficiency and both, hydraulic retention time (HRT) and temperature. By this model an optimized HRT for defined bacterial pathogens effluent standards can be easily calculated. Thus, hygiene potential can be evaluated along with economic aspects. In this paper not only results for describing the hygiene potential of a thermophilic anaerobic bioreactor are presented, but also an exemplary method to draw the right conclusions out of biological tests with the aid of mathematical tools.