Trace element analysis of Cretan wines and wine products

The object of this research is to investigate the ways and the degree of contamination of Cretan grapes from the area of Chania and their alcoholic products, with the elements aluminium, arsenic, cadmium, copper, chromium, iron, lead, manganese, nickel and zinc. Fifteen samples of grapes were collected and used for the production of experimental wines from rinsed and unrinsed grapes. A microwave furnace was used for the digestion and dissolution of the experimental wines, the precipitates that originated in these wines, as well as the wines of the corresponding producers. The analyses of all mentioned samples as well as 34 local alcoholic distillates were performed using total reflection X-ray fluorescence and graphite furnace atomic absorption spectrometry. The concentrations for all the elements that were determined were almost in all cases, well below the maximum permissible levels by the Greek and the European Union legislation.     

Soil salinity of urban turf areas irrigated with saline water: I. Spatial variability

With increasing use of saline water for irrigating urban landscapes, soil salinization is becoming a concern. This study examined spatial variation in soil salinity over the length of selected fairways at five golf courses, and of large turf areas at two public parks located in west Texas and southern New Mexico. Salinity of water used for irrigation ranged from 680 to 2700 mg L⁻¹, and the sites consisted mostly of Aridisols (upland soils) or Entisols (alluvial soils). Soil salinity distribution at sites consisting of deep Aridisols was spatially independent with the coefficient of variability (CV) ranging from 24 to 42%. The sites consisting of shallow Aridisols over a calcic horizon had erratic and random soil salinity distributions with an average CV of 37%. Since soil salinity distributions in Aridisols and Alfisols appeared to be spatially independent within the distance of fairways, soil sampling adequacy can be determined by the conventional probability statistics. However, salinity distributions at Entisols sites were spatially dependant to a length of 100 m or more. In addition, the clayey Entisols used for public parks had high levels of salt accumulation (>10 dS m⁻¹ in the saturation extract) with the CV exceeding 60%. When salinity readings were stratified by soil type distribution, the CV was reduced to 28% on the average. The number of samples required to obtain the mean salinity over a typical length of fairways (250–300 m) within a deviate range of 20% averaged 6 in deep sandy Aridisols and Alfisols, and 13 each in other cases, provided that sampling of Entisols is made based on soil type distributions. These sampling requirements are greater than those for field soil moisture or saturation water contents. The spacing to collect the required number of samples over the prevailing length of fairways was between 23 and 38 m. Soil sampling for salinity appraisal is most problematic in Entisols, but can be made simple if a detailed soil map is available. In Aridisols containing a calcic horizon, it is probable to have saline spots over poorly permeable caliche.     

A contribution to the study of some greek marbles

The use of marble in Architecture began on the 7th century B.C. and continued to be used without stop untill today. Greece and especially the East Macedonia region is an extremely privileged area on marble deposits both in quantities and qualities and colours. In the present work the main physical and engineering properties of some varieties of greek marbles are given and a comparison with the international standards is made. The experimental material (marbles) was from East Macedonia, Argolida-Arcadia and Magnessia, three of the biggest marble deposit areas in Greece. From the results obtained, it is concluded that the marbles examined satisfy all the international standard codes and thus they can be used as building stones and decoration materials.     

Stress-Strain State of Weak Saturated Clay Beds of Embankments

Results are presented for laboratory and field tests of weak saturated soils serving as beds for embankments in Ho Chi Min City and various regions of the Mekong River Delta (Vietnam). A method is outlined for quantitative evaluation of the stress-strain state (SSS) of the weak saturated clayey beds (plane problem). A method is described for quantitative evaluation of the deformation and stability of weak beds in the initial, intermediate, and stabilized stages of the formation and transformation of the SSS. __________ Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 5, pp. 2–6, September–October, 2005.     

Separation of physical loading from photosynthesis/respiration processes in rivers by mass balance

Diurnal variations in physical and chemical concentrations, including nutrients, are observed in river ecosystems. Understanding these cycles and separating the effects of physical loading (from point and non-point sources) and biogeochemical processes are necessary for water management and the TMDL process. A chloride mass balance approach is used to separate the relative influences of physical loading and biogeochemical processes in the Bow River through Calgary, Canada, which has a significant influence on the river water chemistry. Sampling campaigns were conducted in December 2005, when minimal photosynthesis and respiration occur, and in July 2006, when river discharge is high and some photosynthesis and respiration activity is present. Samples in each campaign were collected at point source input and output along the river reach through the city every hour for a 24-hour period, allowing for time of travel. The two wastewater treatment facilities within the city contributed the majority of physical mass loading to the river, with temporal variations in effluent discharge, chloride, and nutrient concentrations. Wastewater effluent chloride to nutrient (as well as other parameter relationships) concentrations also varied diurnally. An hourly chloride mass balance was achieved, within 0.5% (average, S.D.=4.4) for December and 7.7% (average, S.D.=4.2) for July, between estimated cumulative sum values from all inputs and measured values at the river output downgradient of the city, allowing for the investigation of other parameter conservativeness. Some slight diurnal variations associated with photosynthesis and respiration were observed even with limited productivity in the river. Nitrate mass fluxes appeared to be most strongly influenced by photosynthesis and respiration processes, with phosphate being less influenced. Ammonia mass fluxes appeared to be most strongly influenced by wastewater effluent loading. Physical loading can mask or enhance biogeochemical diurnal fluctuations, creating errors in river process interpretations. Chloride was a useful tracer in the mass balance to distinguish between and assist in separating physical loading and biogeochemical processes in the river.     

Lead contamination in tap water of households with children in Lower Saxony, Germany

Lead has numerous acute and chronic adverse effects on human beings. This is especially true for infants and children. The main path of lead ingestion in children can be different according to housing and living situation. The intake of lead through drinking water is commonly due to metal corrosion. The users plumbing can be an important factor. In recent years, many lead pipes in Germany have been replaced by pipes made of an alternative material. The aim of this study is to assess the present state of drinking water contamination and the resulting exposure of infants to lead. For this purpose mothers of new-born babies were offered a free examination of their drinking water. After a written declaration of consent had been obtained and after the infant in question had reached an age of 3 months, a stagnation sample of cold tap-water after overnight stagnation together with a random daytime sample was obtained from the family. The collected samples were analysed by atomic absorption spectrometry for their lead concentration. In total, 1485 samples from households were collected. Of the 1434 stagnation samples, 3.1% had lead concentrations greater than 0.01 mg/l (recommended limit of the WHO) and 0.6% had concentrations above the limit of the German drinking water regulation (0.04 mg/l). The values for the 1474 random daytime samples were 2.1% above 0.01 mg/l and 0.2% greater than 0.04 mg/l, respectively. By region, the areas Bovenden, Friedland, Duderstadt, Northeim and Rosdorf were particularly affected. The highest measured concentrations of lead in the stagnation samples were 0.11 mg/l and 0.15 mg/l in the random daytime samples, respectively.     

Energy and environmental comparison of three variants of a family house during its whole life span

The aim of this study is to analyse and compare three variants of a family house in order to evaluate the total environmental impacts produced during the whole building life cycle. The first variant corresponds to the standard in force in Switzerland, the second alternative to the requirements of a quality control label for houses with low energy consumption and the third case is a very low energy consumption building. The three variants have the same architectural aspect but different insulation thicknesses and types, different energy production systems and the use of different renewable energies. The calculation of the environmental impacts is carried out by means of a life cycle analysis, which includes not only the impact related to the energy consumption during the occupancy stage, but also the materials manufacture, transport, replacement and elimination at the end of the building lifetime. The results are expressed with the Swiss and the UCTE (Union for the Co-ordination of Transmission of Electricity) electricity mix to analyse how they influence the building impact.     

Chlorine disappearance in sea-water

A series of chlorination studies were carried out on natural and artificial sea-water. It was determined that both the forward and back titration procedures accurately described the two phases of chlorine losses in sea-water: a rapid initial loss followed by a continuous loss at a sharply reduced rate. The order of adding the iodide and buffer reagents was found to be crucial in affecting the rapid initial loss. The initial loss was found to reach a saturation level that varied widely between natural sea-water samples and appeared to be related to a true organic demand. In contrast, the second phase was difficult to explain. Losses continued over 10 day periods and were pronounced in both natural and artificial sea-water containing bromide. In the absence of bromide, long term losses in artificial sea-water were greatly reduced, indicating that the lost applied chlorine was associated with the bromine chemical system in sea-water. The fate of the lost chlorine was not determined and the untitratable halogen compounds must remain suspect as potential biocides.