Ligand Design in Atomically Precise Copper Nanoclusters and Their Application in Electrocatalytic Reactions

Metal nanoclusters (MNCs) are compositionally well-defined and also structurally precise materials with unique molecule-like properties and discrete electronic energy levels. Atomically precise ligand-protected Cu nanoclusters (LP-CuNCs) are one category of typical MNCs that usually demonstrate unique geometric and electronic structures to serve as electrocatalysts. However, the synthesis, application, as well as structure-performance relationship of LP-CuNCs are not adequately studied. Significantly, the ligands are essential to the geometric structure, crystal structure, size, and electronic structure of LP-CuNCs, which determine their physiochemical properties and applications. In this review, significant progress in the ligand design of LP-CuNCs, and their application in electrocatalytic reactions is introduced. The general basics of ligand-protected MNCs (LP-MNCs) are first introduced and the functions of ligands are emphasized. Subsequently, a series of different ligands for LP-CuNCs including thiolates, phosphines, alkynyl, polymers, and biomolecules are highlighted. Thereafter, their applications in different electrocatalytic reactions are discussed. It is believed that this review will not only inspire the design and synthesis of novel LP-CuNCs, but also contribute to the extension of their applications in electrocatalytic reactions and the establishment of accurate structure-performance relationships.     

Privacy Preserving distributed smart grid system based on Hyperledger Fabric and Wireguard

Smart grid has drawn a lot of attention and investment in recent years, which not only helps the modern generation and distribution of traditional power but also highly widens the application of renewable energy sources. However, the main challenges in the application of smart grid are 1. the privacy preservation of users' information and 2. the trustful transmission channel among peers. In order to solve these problems, VPN and blockchain can be considered since they have some features perfectly suitable for these situations. In this paper, we propose a smart grid system based on WireGuard and Hyperledger Fabric to solve the problems mentioned above. And we also implement the whole system and give a view by web application. What's more, all the functionalities are displayed and tested, including building a smart device simulator, deploying data visualization and making some performance evaluations about transactions and WireGuard communication. Experiment results show that the introduction of WireGuard into network infrastructure does not cause too much loss of bandwidth and delay, but it ensures a certain degree of communication security. And Fabric provides the consistency and traceability of transactions in smart grid system.     

Finite-time optimal tracking control for a class of nonlinear systems with prescribed performance

In this paper, a finite-time optimal tracking control scheme based on integral reinforcement learning is developed for partially unknown nonlinear systems. In order to realize the prescribed performance, the original system is transformed into an equivalent unconstrained system so as to a composite system is constructed. Subsequently, a modified nonlinear quadratic performance function containing the auxiliary tracking error is designed. Furthermore, the technique of experience replay is used to update the critic neural network, which eliminates the persistent of excitation condition in traditional optimal methods. By combining the prescribed performance control with the finite-time optimization control technique, the tracking error is driven to a desired performance in finite time. Consequently, it has been shown that all signals in the partially unknown nonlinear system are semiglobally practical finite-time stable by stability analysis. Finally, the provided comparative simulation results verify the effectiveness of the developed control scheme.     

The Effect of the Rotary Steerable Spindle Structure Parameters on the Characteristics of Cantilever Bearing

Journal of Failure Analysis and Prevention - In point-the-bit rotary steerable drilling system, the internal and outer diameter of the spindles and the fillet radius of the shaft shoulder have a...     

Synthesis of ultrathin semicircle-shaped copper nanowires in ethanol solution for low haze flexible transparent conductors

Nano Research - Copper nanowires (CuNWs) are becoming an indispensable item for next-generation transparent optical devices due to their excellent conductivity and transparency. In this work,...     

智能车竞赛中道路的视频识别方案

视频信号的的采集和处理是一个复杂的过程,这需要程序设计者了解视频信号的构成,充分利用复合视频信号中的各种同步信息作为视频信号采集的控制信号,从而完成信号的采集。     

基于罚函数的解析目标分流法计算特性分析

为了在复杂产品早期开发阶段更好的使用解析目标分流法(ATC),分析了基于不同罚函数的ATC方法的计算特性.给出了ATC方法的一般公式,比较了3种ATC方法的优缺点,以常用的几何规划算例为例,研究了初值、初始罚参数、收敛准则等因素对计算精度和计算花费的影响.计算结果表明,ATC是一种稳定性好、计算效率高的多学科设计优化(MDO)方法,并且基于增广拉格拉日函数的ATC方法的总体性能比其它两种方法要好一些.