Comparison between infrared and Raman spectroscopic analysis of maturing rabbit cortical bone

The molecular composition of the organic and inorganic matrices of bone undergoes alterations during maturation. The aim of this study was to compare Fourier transform infrared (FT-IR) and near-infrared (NIR) Raman microspectroscopy techniques for characterization of the composition of growing and developing bone from young to skeletally mature rabbits. Moreover, the specificity and differences of the techniques for determining bone composition were clarified. The humeri of female New Zealand White rabbits, with age range from young to skeletally mature animals (four age groups, n = 7 per group), were studied. Spectral peak areas, intensities, and ratios related to organic and inorganic matrices of bone were analyzed and compared between the age groups and between FT-IR and Raman microspectroscopic techniques. Specifically, the degree of mineralization, type-B carbonate substitution, crystallinity of hydroxyapatite (HA), mineral content, and collagen maturity were examined. Significant changes during maturation were observed in various compositional parameters with one or both techniques. Overall, the compositional parameters calculated from the Raman spectra correlated with analogous parameters calculated from the IR spectra. Collagen cross-linking (XLR), as determined through peak fitting and directly from the IR spectra, were highly correlated. The mineral/matrix ratio in the Raman spectra was evaluated with multiple different peaks representing the organic matrix. The results showed high correlation with each other. After comparison with the bone mineral density (BMD) values from micro-computed tomography (micro-CT) imaging measurements and crystal size from XRD measurements, it is suggested that Raman microspectroscopy is more sensitive than FT-IR microspectroscopy for the inorganic matrix of the bone. In the literature, similar spectroscopic parameters obtained with FT-IR and NIR Raman microspectroscopic techniques are often compared. According to the present results, however, caution is required when performing this kind of comparison.     

Podcasting: A new technological tool to facilitate good practice in higher education

The literature has frequently highlighted the usefulness of podcasting in higher education; however, there is an important gap between the theory on good practice in higher education and empirical studies about podcasting. With this in mind, we carried out an empirical study on an undergraduate degree course in Information Systems Management. The study consisted of the creation and broadcast of 13 podcasts, distributed over four months in which ninety distance students took part. The analysis follows the suggestions proposed in previous literature about the evaluation of technologies in a university learning environment. The findings, discussed within the framework of principles for good practice in higher education, suggest some interesting issues in distance courses, such as: (1) podcasting is a powerful tool as a complement to the traditional resources on a course, but not a substitute for them; (2) the characteristics of podcasting increase the impression of permanent contact between students and teachers, increasing students’ motivation; (3) the use of podcasting allows for a diverse range of student skills and learning methods. Other secondary findings are discussed and some suggestions for future research are proposed at the end of this paper.     

Lossless handover for wireless ATM

Handover is one of the key research topics for the emerging wireless ATM networks. This paper describes a handover mechanism for intra-switch handovers for wireless ATM. The handover procedure is simple enough to be implementable as a limited enhancement to ATM switch platforms for fixed network, yet provides low delay and lossless handover when used together with a suitable radio interface. The paper also reports on initial simulation result.     

Remarks on rate constitutive equations for finite deformation problems: computational implications

It is explicitly shown that if the (spatial) elasticity tensor of an elastic material is taken as isotropic for all possible configurations, then its coefficients cannot be constants; they must depend nontrivially on the Jacobian determinant of the deformation gradient. Moreover, the assumption typically made for computational purposes that its coefficients remain constant for all possible configurations is incompatible with elasticity. It is further shown that an assumption widely used in the computational literature in the context of finite deformation plasticity, namely, relating an objective stress rate to the rate of deformation tensor through a fourth-rank constant isotropic tensor, is also incompatible with elasticity, thus furnishing an example of an hypoelastic material which is not elastic.     

Spatial distibution and temporal accumulation of polychlorinated dibenzo-p-dioxins,dibenzofurans, and biphenyls in the Gulf of Finland

Dated sediment cores and surface sediments were analyzed from the Gulf of Finland, a part of the Baltic Sea, to study the sources, levels, distribution, and total amounts of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and polychlorinated biphenyls (PCBs). The gulf was found to be severely polluted, with PCDD/F sum concentrations as high as 101000 ng/kg and 479 ng/kg WHO-TEQ in dry weight. The source of pollution was the former manufacturing and use of a chlorophenol based wood preservative along the Kymijoki River. It was estimated thatthe impacted sedimentary area stretched a distance of 75 km away out from the coast and that the PCDD/F sum load attributed to the wood preservative source was 1770 kg of PCDD/Fs or 12.4 (+/-2.8) kg WHO-TEQ. The surface sediments contained 24-66% of the maximum concentrations present in the 1960-1970s, showing that the river still acts as a significant PCDD/F source and may contribute to the high levels in fish. Moreover, the reduced PCDD/F and PCB concentrations were partly due to the dilution by increased dry matter deposition. PCBs were uniformly distributed over the gulf, and the PCB load in the polluted area was 2020 kg or 0.14 kg WHO-TEG.     

Malolactic fermentation in four varieties of sea buckthorn (Hippophaë rhamnoides L.)

Malolactic fermentation (MLF) used in winemaking was applied to four varieties of sea buckthorn (Hippophaë rhamnoides L.). Sensory properties and chemical components of fermented and unfermented juices were studied in order to see whether the MLF can have an effect on sensory quality of sea buckthorn and if there are differences between varieties. The juices were inoculated with unadapted Oenococcus oeni at a cell density of 10⁹ CFU/mL and the fermentation was performed over 18 h at 28 °C. The fermentation decreased sourness and astringency in the samples, and fruity flavor as well as fermented flavor were increased. However, the ML reaction was different between the varieties. The size of the reaction was not proportional to the initial pH or malic acid content of the juice. Larger the ML reaction, more changes were observed in the sensory properties.     

VO2 nanostructures based chemiresistors for low power energy consumption hydrogen sensing

Mott-type VO₂ oxide nanobelts are demonstrated to be effective hydrogen gas sensors at room temperature. These nanobelts, synthesized by hydrothermal process and exhibiting the VO₂ (A) crystallographic phase, display room temperature H₂ sensitivity as low as 0.17 ppm. The nanobelts (ultralong belt-like) nanostructures could be an ideal system for fully understanding dimensionally confined transport phenomena in functional oxides and for building functional devices based on individual nanobelts.     

Finite element analysis of the stability of multilayer elastomeric bearings

The stability of multilayer elastomeric bearings is considered within the framework of two-dimensional finite elasticity. For this purpose, simple constitutive equations which generalize those of a transversally isotropic linear elastic solid are considered. A finite element formulation is discussed which is capable of accounting for very general boundary conditions. For moderate deflections and classical boundary conditions this formulation leads to numerical results in close correspondence with those obtained by Haringx's one-dimensional treatment. It is shown that the presence of boundary conditions in the form of unilateral constraints explains a softening effect which has been experimentally observed during the testing of this type of composite column. Experimental results are also presented which indicate that this softening effect is not produced by a form of material instability. These experimental results provide further justification for the simple constitutive model adopted.     

Bubble behaviors in direct methanol fuel cell anode with parallel design

In this paper, the Volume of Fluid (VOF) method for tracking the gas-liquid interface is employed to investigate the carbon dioxide (CO₂) behaviors inside the anode of a direct methanol fuel cell (DMFC). The CO₂ bubble emergence processes from the catalyst layer (CL) to the gas diffusion layer (GDL) and then to the flow channels are studied with two different strategies. In the first strategy, the CL and GDL are modeled as a uniform porous layer; in the second strategy, they are modeled as a well-ordered-path GDL and a uniform CL. The simulation results show that the second modeling strategy can better capture and match the fundamental phenomena of CO₂ bubble formation and evolvement observed from the experiments inside a DMFC anode.