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81.
    
In this article, the yolk–shell structure of resin‐based carbon spheres (YRFC) and the solid structure of resin‐based carbon spheres (SRFC) were prepared by condensation polymerization, and then novel spherical composites of poly(3,4‐propylenedioxythiophene)/YRFC (PProDOT/YRFC) and PProDOT/SRFC were obtained by in situ chemical oxidative polymerization. The prepared composites were characterized by Fourier transform infrared spectroscopy (FTIR), ultraviolet–visible absorption spectra (UV–vis), Raman, X‐ray diffraction (XRD), Brunauer–Emmett–Teller (BET), X‐ray photoelectron spectrometer (XPS), scanning electron microscope (SEM), and transmission electron microscopy (TEM). Electrochemical behavior of the composites were investigated with reference to their suitability as electrode materials in electrochemical capacitors (ECs), which were accomplished by a combination of cyclic voltammetry and galvanostatic charge/discharge cycles. The resultant PProDOT/YRFC composite showed ideal charge storage capacity with a specific capacitance of 327.5 F g−1 at the current density of 1 A g−1, which is much higher than that of the materials of PProDOT/SRFC (298.1 F g−1) and PProDOT (180.9 F g−1). Furthermore, long cycle life was achieved with the optimized PProDOT/YRFC and the capacitance retention is 87.3% after 10,000 charge/discharge processes, which was attributed to its uniformly dispersible fluffy structure. POLYM. COMPOS., 40:1989–1999, 2019. © 2018 Society of Plastics Engineers  相似文献   
82.
    
Thermal oils are widely used as heat transfer fluids in medium temperature applications. Addition of small amounts of nanoparticles in such fluids can significantly improve their thermophysical properties. This paper presents experimental investigation of an oil‐based nanofluids prepared by dispersing different concentrations (0.25 wt%–1.0 wt%) of copper oxide nanoparticles in Therminol‐55 oil using two‐step method. Shear mixing and ultrasonication were used for uniform distribution and de‐agglomeration of nanoparticles to enhance the stability of the suspensions. The effect of nanoparticles concentrations on thermophysical properties of the nanofluids was analysed by measuring thermal conductivity, dynamic viscosity, effective density and specific heat capacity at different temperatures (25 °C–130 °C). Thermal conductivity exhibited increasing trend with rising temperature and increase in nanoparticles loading. A significant decrease in dynamic viscosity and effective density against increasing temperature makes it suitable for medium temperature applications. Nano‐oils with improved thermal properties are expected to increase the efficiency of concentrating solar thermal collectors.  相似文献   
83.
    
Efficient and flexible schemes for a swift, field‐free control of the phase in quantum devices have far‐reaching impact on energy‐saving operation of quantum computing, data storage, and sensoring nanodevices. A novel approach for an ultrafast generation of a field‐free vector potential that is tunable in duration, sign, and magnitude, allowing to impart non‐invasive, spatiotemporally controlled changes to the quantum nature of nanosystems is reported. The method relies on triggering a steady‐state toroidal moment in a donut‐shaped nanostructure that serves as a vector‐potential generator and quantum phase modulator. Irradiated by moderately intense, few cycle THz pulses with appropriately shaped polarization states, the nano donut is brought to a steady‐state where a nearby object does not experience electric or magnetic fields but feels the photo‐generated vector potential. Designing the time structure of the driving THz pulses allows for launching picosecond trains of vector potentials which is the key for a contact‐free optimal control of quantum coherent states. This research can trigger a new class of ultrafast quantum devices operated and switched in an energy‐efficient, contact and field‐free manner, enabling new techniques for use in quantum information, magnetic nanostructures, and superconducting tunnel junctions as well as in toroidally ordered systems and multiferroics.  相似文献   
84.
This work utilizes the mechanistic modeling approach for predicting cutting forces and simulating the milling process of fiber-reinforced polymers (FRP) with a straight cutting edge. Specific energy functions were developed by multiple regression analysis (MR) and committee neural network approximation (CN) of milling force data and a cutting model was developed based on these energies and the cutting geometry. It is shown that both MR and CN models are capable of predicting the cutting forces in milling of unidirectional and multidirectional composites. Model predictions were compared with experimental data and were found to be in good agreement over the entire range of fiber orientations from 0 to 180°. Furthermore, CN model predictions were found to greatly outperform MR model predictions.  相似文献   
85.
Machines are key elements in manufacturing systems and their breakdowns can dramatically affect system performance measures. This paper proposes a new multi-objective pure integer linear programming approach for the cell formation problem with alternative process routings and machine reliability consideration. The model minimizes total cost and maximizes system reliability simultaneously. Traditional reliability evaluation approaches attempt to model the reliability of the manufacturing system as a function of its elements. These approaches have some negative aspects; therefore, instead of modeling the system reliability as an explicit objective function, we use an approach to model the effects of the machine unreliability in terms of cost and time-based effects. Using the ?-constraint method as an optimization tool for multi-objective programming, a numerical example is solved to demonstrate the capability of the proposed model in evaluating various effects of the reliability consideration.  相似文献   
86.
    
The use of quality control tool for authentication of Jadwar (Delphinium denudatum Wall. ex Hook.f. & Thomson), a folk herbal drug used for the treatment of different ailments, was studied. People face problems of adulteration for this drug at global, regional, national and local levels. Two different plant species are commercially marketed in the Indo‐Pak Subcontinent under the same trade name of Jadwar. One is D. denudatum Wall. ex Hook.f. & Thomson and the other is Aconitum heterophyllum Wall. ex Royle. To focus on this problem, a marketable available drug sample of Jadwar was authenticated by using basic microscopy tools (LM) and advanced chemo‐taxonomic markers. Authentication, quality and standardization of this drug was achieved using morphology, organoleptography, UV and IR analyses, scanning electron microscopy of pollen and anatomical investigations. The techniques used for authentication marked the clear difference between the studied plants. Microscopic studies, chemotaxonomic investigation and other techniques used in this project provided the basis for the authentication of this species.  相似文献   
87.
88.
Disconnect switches are one of the components of an electrical substation that are vulnerable to the effects of earthquake shaking. Three vertical-break and two horizontal-break 230 kV switches of porcelain and composite construction were tested on a triaxial earthquake simulator in various configurations. Three-pole switches were mounted on a stiff, low-profile frame and tested according to the industry standard IEEE-693-1997. The vulnerable components of the switches were the aluminum spacers at the base of the switch posts and the welded post-blade connections and the bolted connections at the base of the posts. Single-degree-of-freedom models of the switch insulator posts were developed using experimental data to establish the amplification of seismic demand on the switches when mounted on frames of different heights and stiffness.  相似文献   
89.
This work was undertaken to explore the formation of weld defects in FSWed copper metals via both numerical and experimental approaches. The 4 mm-thick copper sheets were friction stir welded at a tool rotational speed of 710 rpm and tool translational speed of 40 mm/min. Microstructural evaluations were performed on the welded specimens. Also a 3D arbitrary Lagrangian Eulerian numerical model was developed to obtain temperature and material velocity profiles. To this aim, DEFORM-3D was implemented for developing the numerical simulation. Numerical results for temperature values showed good agreement with the recorded experimental data. They also suggest that on the advancing side (AS) of the trailing side, the pin velocity has the minimum amount (zero), and this is the main reason for the formation of tunneling cavity. Experimental results show that a force is created between the reminder of material at the joint and the rim of AS. This force causes a prong of surface material from the AS rim to penetrate into lower parts of weld. It seems that the inadequate pressure (low values of the plunge depth), inadequate surface materials, and the trapped air are the main causes for the formation of the weld defects.  相似文献   
90.
Designing a cellular manufacturing (CM) system involves three major decisions: cell formation (CF), cellular layout (CL), and cellular scheduling (CS). The integrated design of CM systems is investigated in this paper by proposing two mathematical models. The first model integrates cellular layout problem with cell formation problem to determine optimal cell configuration and the layout of machines and cells in order to minimize the total movement costs. The second model takes also the cellular scheduling into consideration with the objective of minimizing the total completion time of parts. Two genetic algorithms are developed to solve the real-sized problems. The proposed models are formulated as mixed integer linear programming, and two numerical examples are solved in order to investigate the effects of integration in the CM systems design. The results show that considering CF, CL, and CS decisions in a simultaneous manner can significantly improve the performance of the CM systems.  相似文献   
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