Evaluation of fracture toughness degradation of CrMoV rotor steels based on ultrasonic nonlinearity measurements

The objective of this paper is to develop a nondestructive method for estimating the fracture toughness (K _IC) of CrMoV steels used as the rotor material of steam turbines in power plants. To achieve this objective, a number of CrMoV steel samples were heat-treated, and the fracture appearance transition temperature (FATT) was determined as a function of aging time. Nonlinear ultrasonics was employed as the theoretical basis to explain the harmonic generation in a damaged material, and the nonlinearity parameter of the second harmonic wave was the experimental measure used to be correlated to the fracture toughness of the rotor steel. The nondestructive procedure for estimating theK _IC consists of two steps. First, the correlations between the nonlinearity parameter and the FATT are sought. The FATT values are then used to estimateK _IC, using theK _IC versus excess temperature (i.e.,T-FATT) correlation that is available in the literature for CrMoV rotor steel.     

Effect of gas mixing ratio on etch behaviors of Ba2Ti9O20 (BTO) and Pt thin films in Cl2/Ar inductively coupled plasma

An investigation of the Ba₂Ti₉O₂₀ (BTO) and Pt thin films etch mechanism in the Cl₂/Ar inductively coupled plasma was carried out. It was found that an increase in Ar mixing ratio at fixed gas pressure and input power causes a fast decrease in the BTO etch rate (26.9-1.2 nm/min for 0-100% Ar) while the Pt etch rate increases slightly from 17.4-23.0 nm/min. Langmuir probe diagnostics and zero-dimensional plasma modeling provided the data on plasma parameters, steady-state composition and fluxes of active species on the etched surface. From the model-based analysis of etch kinetics, it was shown that the behavior of the BTO etch rate corresponds to the reaction-rate-limited etch regime, where the etch rate is limited neither by physical sputtering of the main material nor by the ion-stimulated desorption of low-volatile reaction products. The etch process of Pt appears in the transitional regime and is controlled by the neutral and ion fluxes together.     

Effect of sintering temperature on varistor properties and aging characteristics of ZnO–V2O5–MnO2 ceramics

The microstructure, electrical properties, dielectric characteristics, and DC accelerated aging behavior of the ZVM-based varistors were investigated for different sintering temperatures of 800–950 °C. The microstructure of the ZVM-based ceramics consisted of mainly ZnO grain and secondary phase Zn₃(VO₄)₂, which acts as liquid-phase sintering aid. The Zn₃(VO₄)₂ has a significant effect on the sintered density, in the light of an experimental fact, which the decreases of the Zn₃(VO₄)₂ distribution with increasing sintering temperature resulted in the low sintered density. The breakdown field exhibited the highest value (17,640 V/cm) at 800 °C in the sintering temperature and the lowest value (992 V/cm) at 900 °C in the sintering temperature. The nonlinear coefficient exhibited the highest value, reaching 38 at 800 °C and the lowest value, reaching 17 at 850 °C. The varistor sintered at 900 °C exhibited not only high nonlinearity with 27.2 in nonlinear coefficient, but also the highest stability, in which %ΔE_1 mA = −0.6%, %Δα = −26.1%, and %Δ tan δ = +21.8% for DC accelerated aging stress of 0.85 E_1 mA/85 °C/24 h.     

Crystal structure of (Ba1−x Lax) [Mg(1 + x)/3Nb(2−x)/3]O3 ceramics

The crystal structure of (Ba_1–x La _x )[Mg_{(1 + x)/3}Nb_(2–x)/3]O₃ (BLMN) ceramics with 0 x 1 was investigated using X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). When the La content, x, was above 0.1, the 1:2 ordered hexagonal structure found in Ba(Mg_1/3Nb_2/3)O₃ (BMN) was transformed into the 1:1 ordered cubic structure. The 1:1 ordered cubic structure was maintained up to x = 0.7. When x exceeded 0.7, however, BLMN exhibited a 1:1 ordered monoclinic structure, rather than a 1:1 ordered cubic structure. La(Mg_2/3Nb_1/3)O₃ (LMN) has a 1:1 ordered monoclinic P2₁/n structure with a = 5.6004 Å, b = 5.6414 Å, c = 7.9346 Å, and = 89.9819°. The monoclinic LMN has the in-phase and the anti-phase tilt of oxygen octahedra. The anti-parallel shift of A-site cations was also found in LMN.     

Stress-dependent hardening-to-softening transition of hydrogen effects in nanoindentation of a linepipe steel

We explored the influences of hydrogen on small-scale strength of a linepipe steel through nanoindentation experiments with four pyramidal indenters. Interestingly, a transition from hydrogen-induced hardening to softening was observed as indenter sharpness increases. The transition was analyzed based on the enhancement in hydrogen's elastic shielding effects for a sharper indenter, which could be indirectly evidenced by the stress effects on indentation pile-up, dislocation density, and rate dependency of hardness.     

On the influence of deformation rate on intergranular crack propagation in Type 304 stainless steel

The influence of deformation rate on the stable intergranular crack propagation behaviour of Type 304 stainless steel, as reflected in the crack width, length, and angular orientation parameters was examined. Specimens deformed to failure in the slow tension and creep-rupture modes at 650°C were studied. The results indicate that a rapid, step-wise crack propagation between grain-boundary triple junctions does not occur for these specimens, but that the triple junctions do provide a significant barrier to crack propagation. The crack angular orientation and width, as a function of deformation rate, were concluded to be the parameters which reflect the crack growth rate for the test conditions employed in this work.     

Effect of sintering time on electrical characteristics and DC accelerated aging behaviors of Zn-Pr-Co-Cr-Dy oxide-based varistors

The electrical properties and DC accelerated aging behaviors for nonlinear properties and dielectric characteristics of the varistors, which are composed of ZnO–Pr₆O₁₁CoO–Cr₂O₃–Dy₂O₃ (ZPCCD)-based ceramics, were investigated for different sintering times. The increase of sintering time deteriorated nonlineacy by decreasing a nonlinear exponent from 66.6 to. 46.5 and increasing a leakage current from 1.2 to 3.5 μA. But, the appropriate sintering time decreased a dissipation factor and improved the DC accelerated aging characteristics. The varistors sintered for 2 h exhibited not only relatively high nonlinearity, with the nonlinear exponent of 54.8, the leakage current of 2.5 μA, and dissipation factor of 0.0263 but also the highest stability, in which the variation rates of varistor voltage, nonlinear exponent, leakage current, and dissipation factor are ?1.19%, ?4.0%, +75.8%, and +43.8%, respectively. As sintering time increases, the donor concentration and density of interface states increased in the range of 1.08 × 10¹⁸–1.48× 10¹⁸/cm³ and 3.40 × 10¹²–3.86 × 10¹²/cm², respectively. However the barrier height increased with increasing sintering time.