CFD analysis of natural convection heat transfer augmentation from square conductive horizontal and inclined pin fin arrays

Numerical investigations on natural convection heat transfer from a vertical isothermal plate with pin fins have been made by solving the Navier–Stokes equation along with the energy equation. Average Nusselt number for the plate with different configurations of pin fins have been obtained. It was observed that the maximum increase of the average Nusselt number occurs at S_v/L?=?0.2 for θ?=?45° with fin height of 24?mm (H/t?=?8). The average Nusselt number increases with fin aspect ratio and decreases with angle of inclination. There is not much difference between the average Nusselt number for in-line and staggered arrangement of fins for the range of parameters studied in the present work. A correlation is developed to predict the average Nusselt number of the plate as a function of fin spacing in stream- and span-wise direction, aspect ratio of fins and its angle of inclination.     

Comparative delivery of Diltiazem hydrochloride through synthesized polymer: Hydrogel and hydrogel microspheres

In this study, interpenetrating polymer network (IPN) hydrogel based on polyvinyl alcohol (PVA) networking with polyacrylic acid (PAA) were prepared by a non‐conventional emulsion method without any added crosslinker, using benzoyl peroxide as initiator and sodium chloride (NaCl) as additive. The IPN hydrogel was characterized by using Fourier transformed infrared (FTIR) spectrophotometry, Thermo gravimetric analysis (TGA), and Scanning electron microscopy (SEM). (PVA‐co‐PAA)/NaCl normal IPN hydrogel (H) were fabricated into hydrogel microspheres (HM) by modified emulsion crosslinking method using glutaraldehyde‐saturated toluene as crosslinker and were loaded with Diltiazem hydrochloride (DL). The IPN hydrogel showed more swelling in simulated intestinal fluid (SIF). (PVA‐co‐PAA)/NaCl HM formulation A1 showed comparatively higher DL entrapment (79%) and better control over DL release up to 24 h. By comparing antihypertensive activity of DL loaded two formulations in normotensive rats, HM formulation A1 found more effective in reducing blood pressure to 40.1%. The experimental results demonstrated that (PVA‐co‐PAA)/NaCl HM had the greater potential than normal hydrogel to be used as a drug carrier. A single use of the prepared hydrogel microsphere system of DL can effectively control hypertension in rats. The system holds promise for clinical studies. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Preparation of thermal resistant gas barrier chitosan nanobiocomposites

Nanobiocomposites of chitosan/clay were prepared by solution method using CuSO₄/glycine chelate complex as the catalyst with variable percentage of clay loading. The chemical interaction of chitosan and clay was studied by Fourier transform infrared spectroscopy. The structure of chitosan and clay nanobiocomposites was investigated by X‐ray diffraction and high resolution transmission electron microscopy. From thermogravimetric analysis, it was found that chitosan/clay nanobiocomposites were more thermally stable as compared to pure chitosan. A substantial reduction in oxygen permeability was obtained from the gas permeameter with increase in clay concentrations by which the synthesized nanocomposites materials may be used for packaging applications. POLYM. COMPOS., 35:2324–2328, 2014. © 2014 Society of Plastics Engineers     

Ultra Low-Dose Radiation: Stress Responses and Impacts Using Rice as a Grass Model

We report molecular changes in leaves of rice plants (Oryza sativa L. - reference crop plant and grass model) exposed to ultra low-dose ionizing radiation, first using contaminated soil from the exclusion zone around Chernobyl reactor site. Results revealed induction of stress-related marker genes (Northern blot) and secondary metabolites (LC-MS/MS) in irradiated leaf segments over appropriate control. Second, employing the same in vitro model system, we replicated results of the first experiment using in-house fabricated sources of ultra low-dose gamma (γ) rays and selected marker genes by RT-PCR. Results suggest the usefulness of the rice model in studying ultra low-dose radiation response/s.     

Synthesis and analysis of lead-free tungsten bronze ferroelectrics

The polycrystalline Ba₂Sr₃GdTi₃V₇O₃₀, a member of tungsten bronze structural family, was prepared by a solid-state reaction method at high temperature (calcination and sintering temperatures at 950 and 1,000 °C, respectively). Preliminary structural study showed that the compound has orthorhombic crystal structure at room temperature. Study of surface morphology of the compound by scanning electron microscopy exhibits the uniform grain distribution on the surface of the sample with less number of voids. The dielectric anomaly observed at 313 °C is considered as a ferroelectric-paraelectric phase transition temperature which has been confirmed by appearance of hysteresis loop at room temperature. The trend of variation of ac conductivity with inverse of absolute temperature provides the nature of conduction mechanism in the material. The different value of activation energy in different temperature regions suggests that the conduction process in the material is of mixed-type (i.e., ionic–polaronic and space charge due to the oxygen ion vacancies).     

Polyelectrolyte screening effects on the dissolution of whey protein gels at high pH conditions

The literature reports an optimum NaOH concentration for the alkaline cleaning of whey deposits or gels; at NaOH concentrations higher than this optimum, cleaning proceeds much more slowly. Although this phenomenon is of great importance in the cleaning of dairy equipment, no conclusive physical explanation has yet been presented. In this study, we present strong evidence that the dissolution rate is affected by the equilibrium-swelling ratio in β-lactoglobulin (βLg) gels. The swelling ratio is greatly reduced in the presence of salts due to the polyelectrolyte screening effect of the cations. This has been observed in free-swelling βLg gels using gravimetrical analysis and in the uniaxial swelling of WPC gel deposits using fluid dynamic gauging. At high dissolution pH (>13.3), the high Na⁺ concentration reduces swelling in spite of the high surface charge of the protein. It is proposed that the reduction of the free volume inside the gel impedes the transport of the protein aggregates out of the NaOH penetration zone. We have also observed that the final dissolution rate of gels pre-soaked in 1 M NaOH or NaCl is similar, despite the difference in pH, and much lower than for untreated gels: the high Na⁺ concentration in the soaked gels hinders swelling, inhibiting the disentanglement of the protein clusters regardless of the high pH.     

Diagnosis of Wireless Sensor Networks in Presence of Permanent and Intermittent Faults

In this paper we consider the problem of distributed fault diagnosis in Wireless Sensor Networks (WSNs). The proposed Fault Diagnosis Algorithm (FDA) aims to handle both permanent and intermittent faults. The sensor nodes with permanent communication faults can be diagnosed by using the conventional time-out mechanism. In contrast, it is difficult to detect intermittent faults due to their inherent unpredictable behavior. The FDA is based on the comparison of sensor measurements and residual energy values of neighboring sensor nodes, exploiting their spatial correlations. To handle intermittent faults, the comparisons are made for \(r\) rounds. Two special cases of intermittent faults are considered: one, when an intermittently faulty node sends similar sensor measurement and similar residual energy value to some of its neighbors in all \(r\) rounds; another, when it sends these values, either or both of which deviates significantly from that of some neighbors in all \(r\) rounds. Through extensive simulation and analysis, the proposed scheme is proved to be correct, complete, and efficient to handle intermittent faults and hence, well suited for WSNs.