Optimization of hydraulic cylinder housing

This paper concerns the optimization of the fatigue-critical part of a hydraulic cylinder. The investigation includes optimization, fatigue testing, residual stress measurements, life predictions and, finally, reliability computations. The optimization reduced the critical parameter, the stress intensity factor in the end weld root, by 40%. The fatigue tests verified this reduction. Life predictions based on available da/dN data, combined with computed and tabulated stress intensity factor solutions, were in good agreement with the fatigue test data. Fractography of the fatigue sites revealed the existence of initial cracks of size 0.02 to 0.06 mm in all the welded joints examined. Reliability computations based on the test results and long-term load data demonstrate the type of results that are of major interest for designers.     

Electron transfer between an organic solute and intrinsic molecular organic electrode

Electron transfer between N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD) and a compacted TTF-TCNQ electrode was observed in 0.1M aqueous potassium chloride using cyclic voltammetry. The positions of cathodic and anodic peaks are at 0.20 – 0.22 V and 0.31 – 0.33 V, respectively, vs. a silver/silver chloride electrode, suggesting quasi-reversible electron transfer. This is the first demonstration of electron transfer between an organic solute and a molecular organic electrode. Mechanistic aspects of the electron transfer are discussed. Attempts to use the new conductor prepared from TTF and 2,3-dicyano-p-benzoquinone as an electrode were thwarted by partial solubility of the electrode in aqueous and alcoholic solutions.     

Inactivation of Cryptosporidium parvum oocysts with ozone and free chlorine

The objective of this study is to investigate the synergy involved in the sequential inactivation of C. parvum oocysts with ozone followed by free chlorine at 1-20 degrees C. Primary ozone and free chlorine inactivation curves are characterized by an initial lag-phase, followed by one or two post-lag-phase segments, the first segment at a faster rate than the second, of pseudo-first-order inactivation. The kinetics of primary inactivation with ozone and free chlorine has a relatively strong temperature dependence, and vary both with oocyst lot and oocyst age. Synergy is observed for the sequential inactivation of C. parvum oocysts with ozone/free chlorine. Ozone pre-treatment results in the disappearance of the lag-phase and the occurrence of a secondary free chlorine inactivation curve with generally two pseudo-first-order segments, the first segment at a faster rate than the second. The kinetics of both secondary segments is significantly faster than the post-lag-phase rate of inactivation with free chlorine alone. The temperature dependence for both phases of the secondary free chlorine inactivation kinetics is weaker compared to that for primary inactivation with ozone or free chlorine. As a result, the level of synergy in sequential disinfection with ozone/free chlorine increases with decreasing temperature within the range relevant to drinking water utilities. Good agreement is found between the kinetics determined using the modified in-vitro excystation method of viability assessment and animal infectivity data recently reported in the literature for both primary inactivation with ozone, and sequential disinfection with ozone/free chlorine.     

Analysis of a simplified calibration procedure for 18 design-phase building energy models

This paper evaluates the accuracy of 18 design-phase building energy models, built according to LEED Canada protocol, and investigates the effectiveness of model calibration steps to improve simulation predictions with respect to measured energy data. These calibration steps, applied in professional practice, included inputting actual weather data, adding unregulated loads, revising plug loads (often with submetered data), and other simple updates. In sum, the design-phase energy models underpredicted the total measured energy consumption by 36%. Following the calibration steps, this error was reduced to a net 7% underprediction. For the monthly energy use intensity (EUI), the coefficient of variation of the root mean square error improved from 45% to 24%. Revising plug loads made the largest impact in these cases. This step increased the EUI by 15% median (32% mean) in the models. This impact far exceeded that of calibrating the weather data, even in a sensitivity test using extreme weather years.     

A radio frequency single-electron transistor based on an InAs/InP heterostructure nanowire

We demonstrate radio frequency single-electron transistors fabricated from epitaxially grown InAs/InP heterostructure nanowires. Two sets of double-barrier wires with different barrier thicknesses were grown. The wires were suspended 15 nm above a metal gate electrode. Electrical measurements on a high-resistance nanowire showed regularly spaced Coulomb oscillations at a gate voltage from -0.5 to at least 1.8 V. The charge sensitivity was measured to 32 microe rms Hz(-1/2) at 1.5 K. A low-resistance single-electron transistor showed regularly spaced oscillations only in a small gate-voltage region just before carrier depletion. This device had a charge sensitivity of 2.5 microe rms Hz(-1/2). At low frequencies this device showed a typical 1/f noise behavior, with a level extrapolated to 300 microe rms Hz(-1/2) at 10 Hz.     

Transients in the formation of nanowire heterostructures

We present results on the effect of seed particle reconfiguration on the growth of short InAs and InP nanowire segments. The reconfiguration originates in two different steady state alloy compositions of the Au/In seed particle during growth of InAs and InP. From compositional analysis of the seed particle, the In content in the seed particle is determined to be 34 and 44% during InAs and InP growth, respectively. When switching between growing InAs and InP, transient effects dominate during the time period of seed particle reconfiguration. We developed a model that quantitatively explains the effect and with the added understanding we are now able to grow short period (<10 nm) nanowire superlattices.     

GaAs/AlGaAs nanowire heterostructures studied by scanning tunneling microscopy

We directly image the interior of GaAs/AlGaAs axial and radial nanowire heterostructures with atomic-scale resolution using scanning tunneling microscopy. We show that formation of monolayer sharp and smooth axial interfaces are possible even by vapor-phase epitaxy. However, we also find that instability of the ternary alloys formed in the Au seed fundamentally limits axial heterostructure control, inducing large segment asymmetries. We study radial core-shell nanowires, imaging even ultrathin submonolayer shells. We demonstrate how large twinning-induced morphological defects at the wire surfaces can be removed, ensuring the formation of wires with atomically flat sides.