Dithieno[3,2‐b:2′,3′‐d]pyrrol‐Cored Hole Transport Material Enabling Over 21% Efficiency Dopant‐Free Perovskite Solar Cells

Dopant‐free hole transport materials (HTMs) are essential for commercialization of perovskite solar cells (PSCs). However, power conversion efficiencies (PCEs) of the state‐of‐the‐art PSCs with small molecule dopant‐free HTMs are below 20%. Herein, a simple dithieno[3,2‐b:2′,3′‐d]pyrrol‐cored small molecule, DTP‐C6Th, is reported as a promising dopant‐free HTM. Compared with commonly used spiro‐OMeTAD, DTP‐C6Th exhibits a similar energy level, a better hole mobility of 4.18 × 10^?4 cm² V^?1 s^?1, and more efficient hole extraction, enabling efficient and stable PSCs with a dopant‐free HTM. With the addition of an ultrathin poly(methyl methacrylate) passivation layer and properly tuning the composition of the perovskite absorber layer, a champion PCE of 21.04% is achieved, which is the highest value for small molecule dopant‐free HTM based PSCs to date. Additionally, PSCs using the DTP‐C6Th HTM exhibit significantly improved long‐term stability compared with the conventional cells with the metal additive doped spiro‐OMeTAD HTM. Therefore, this work provides a new candidate and effective device engineering strategy for achieving high PCEs with dopant‐free HTMs.     

Homogeneous and polymorphic transformations to ordered intermetallics in nanostructured Au–Cu multilayer thin films

Journal of Materials Science - Atomic arrangements in the nanostructured grains and interfaces of thermally evaporated Au/Cu multilayer thin films on polycrystalline Si substrate have been explored...     

Preorder-based triangle: a modified version of bilattice-based triangle for belief revision in nonmonotonic reasoning

Bilattice-based triangle provides an elegant algebraic structure for reasoning with vague and uncertain information. But the truth and knowledge ordering of intervals in bilattice-based triangle cannot handle repetitive belief revisions which is an essential characteristic of nonmonotonic reasoning. Moreover, the ordering induced over the intervals by the bilattice-based triangle is not sometimes intuitive. In this work, we construct an alternative algebraic structure, namely preorder-based triangle and we formulate proper logical connectives for this. It is also demonstrated that Preorder-based triangle serves to be a better alternative to the bilattice-based triangle for reasoning in application areas, that involve nonmonotonic fuzzy reasoning with uncertain information.     

Selective greedy routing: exploring the path diversity in backbone mesh networks

This paper proposes a new routing protocol for IEEE 802.11s wireless mesh network to overcome the problems associated with the conventional proactive and reactive routing approaches. The proposed ‘Selective Greedy’ (SelG) routing protocol operates in two phases. In the first phase it exploits the proactive mode of Hybrid Wireless Mesh Protocol, the standard routing protocol for IEEE 802.11s mesh, and constructs a set of potential forwarders for every mesh point, that can act as the next-hop relay. In the second phase, during the actual data communication, a candidate is selected from the set of potential forwarders based on a local optimization. The optimization procedure considers the statistical effect of local link quality fluctuation and interference over the global routing path selection. This way the SelG protocol reduces the control packet flooding in the network (a major drawback for reactive protocols). At the same time, the optimization procedure captures the network dynamics, and thus avoids the possibility of routing based on stale information (a drawback for proactive protocols). The routing properties and the correctness of the SelG protocol is established theoretically, and the performance of the protocol is analyzed through simulation results. The proposed protocol is implemented in an indoor wireless mesh testbed, and the performance is evaluated and compared with other traditional approaches.     

Topology Management Ensuring Reliability in Delay Sensitive Sensor Networks with Arbitrary Node Failures

The lifetime of a sensor network is influenced by the efficient utilization of the resource constrained sensor nodes. The tree-based data gathering offers good quality of service (QoS) for the running applications. However, data gathering at the sink reduces the network lifetime due to a fast failure of highly loaded nodes. Loss of connectivity and sensing coverage affect the performance of the applications that demand critical QoS. In this paper, a data gathering tree management scheme has been proposed to deal with arbitrary node failures in delay-sensitive sensor networks. A load-balanced distributed BFS tree construction procedure has been introduced for an efficient data gathering. Based on the initial tree construction, a tree maintenance scheme and an application message handler have been designed to ensure the reliable delivery of the application messages. The correctness of the proposed scheme has been verified both theoretically and with the help of simulation. The proposed scheme offers low overhead, enhanced network lifetime and good QoS in terms of delay and reliability of the application messages.     

DEICA: A differential evolution-based improved clustering algorithm for IoT-based heterogeneous wireless sensor networks

With the evolution of technology, many modern applications like habitat monitoring, environmental monitoring, disaster prediction and management, and telehealth care have been proposed on wireless sensor networks (WSNs) with Internet of Things (IoT) integration. However, the performance of these networks is restricted because of the various constraints imposed due to the participating sensor nodes, such as nonreplaceable limited power units, constrained computation, and limited storage. Power limitation is the most severe among these restrictions. Hence, the researchers have sought schemes enabling energy-efficient network operations as the most crucial issue. A metaheuristic clustering scheme is proposed here to address this problem, which employs the differential evolution (DE) technique as a tool. The proposed scheme achieves improved network performance via the formulation of load-balanced clusters, resulting in a more scalable and adaptable network. The proposed scheme considers multiple parameters such as nodes' energy level, degree, proximity, and population for suitable network partitioning. Through various simulation results and experimentation, it establishes its efficacy over state-of-the-art schemes in respect of load-balanced cluster formation, improved network lifetime, network resource utilization, and network throughput. The proposed scheme ensures up to 57.69%, 33.16%, and 57.74% gains in network lifetime, energy utilization, and data packet delivery under varying network configurations. Besides providing the quantitative analysis, a detailed statistical analysis has also been performed that describes the acceptability of the proposed scheme under different network configurations.     

Stabilizing adaptive controller for uncertain dynamical systems: An LMI approach

Adaptive stabilization of a class of linear systems with matched and unmatched uncertainties is considered in this paper. The proposed controller indeed stabilizes the uncertain system for any positive values of its non-adaptive gain that may be tuned to enhance dynamic response of system. The performance of uncertain system along with the Algebraic Riccati Equation that arises from the adaptive stabilizing controller is now formulated as a multi-objective Linear Matrix Inequality optimization problem. The decay rate and a factor governing the ultimate bound of the system states are considered to characterize the closed loop system performance. Finally, the effectiveness of the proposed controller is illustrated via stabilizing a mass-spring system. Recommended by Editorial Board member Gang Tao under the direction of Editor Young Il Lee. The authors would like to thank the reviewers for their valuable comments and suggestions that have improved the quality of this paper. Sandip Ghosh received the B.E. in Electrical Engineering from Bengal Engineering College (D.U.), Howrah, and Master in Control System Engineering from Jadavpur University, Kolkata, India, in 1999 and 2003 respectively. Presently he is pursuing the Ph.D. degree at Indian Institute of Technology, Kharagpur, India. His research interests include adaptive control, robust control and control of time-delay systems. Sarit K. Das is a Professor of Electrical Engineering Department, Indian Institute of Technology, Kharagpur, India. He received the Ph.D. degree in 1985 from the same department. His research interests include design of periodic controller, decoupling of multivariable systems, modeling and robust control of complex systems. Goshaidas Ray is a Professor of Electrical Engineering Department, Indian Institute of Technology, Kharagpur, India. He received the Ph.D. degree in 1982 from Indian Institute of Technology Delhi, India. His research interests include modeling, estimation, model-based control, intelligent control, robotic systems and distributed control systems.     

Multisensor-based monitoring of weld deposition and plate distortion for various torch angles in pulsed MIG welding

Manufacturing companies often fail to maintain good weld quality due to poor arc stability and distortion after welding. Weld quality can be improved by reducing the transverse shrinkage and the angular distortion in butt welding. The welding deposition efficiency is also an important economic factor. In this work, various pulse voltage parameters have been varied along with welding torch angle in pulsed metal inert gas (P-MIG) welding. The experimental results revealed that the peak voltage is the dominant pulse voltage parameter. Various sensors were also used to monitor arc current, arc voltage, arc sound, and also weld temperature. A strong relationship between arc sound (as well as arc power) and transverse distortion (as well as metal deposition) was found to exist in P-MIG welding. The frequency domain features of welding arc sound were also extracted and correlated to the process characteristics.     

Semi‐global stabilization of discrete‐time systems subject to non‐right invertible constraints

This paper investigates time‐invariant linear systems subject to input and state constraints. We study discrete‐time systems with full or partial constraints on both input and state. It has been shown earlier that the solvability conditions of stabilization problems are closely related to important concepts such as the right invertibility or non‐right invertibility of the constraints, the location of constraint invariant zeros, and the order of constraint infinite zeros. In this paper, for general time‐invariant linear systems with non‐right invertible constraints, necessary and sufficient conditions are developed under which semi‐global stabilization in the admissible set can be achieved by state feedback. Sufficient conditions are also developed for such a stabilization in the case where measurement feedback is used. Such sufficient conditions are almost necessary. Controllers for both state feedback and measurement feedback are constructed as well. Copyright © 2009 John Wiley & Sons, Ltd.     

Prediction of metal deposition from arc sound and weld temperature signatures in pulsed MIG welding

The weld deposition efficiency is an important economic factor like productivity and weld quality in gas metal arc welding (GMAW). There is a strong relationship between arc sound signals and arc stability (or deposition efficiency) in GMAW. In this work, the variation of weld deposition efficiency with various pulse parameters in pulsed metal inert gas welding was investigated. The arc sound signal along with current and voltage signals were acquired and analyzed in time domain as well as in frequency domain. The sound signal kurtosis and arc power were found to be highly correlated with welding process stability. The weld deposition efficiency was also related to weld surface peak temperature. Finally, an attempt was made to correlate the sound time domain as well as frequency domain features of sound signal with the deposition efficiency. The variation of pulse shape with the duty factor also influenced the deposition efficiency as evidenced by in fast Fourier transform analysis.