Determination of atomistic deformation of tricalcium silicate paste with high-volume fly ash

We examined the effect of incorporating high-volume fly ash on the atomic arrangement and interatomic deformation behavior of calcium silicate hydrates in tricalcium silicate paste upon exposure to external forces. The interatomic structural changes and strains under compressive load were assessed using synchrotron in situ high-energy X-ray scattering-based atomic pair distribution function analysis. Three different types of strains, which were (a) macroscopic strains from gauges on the surfaces of specimen, (b) strains in a reciprocal space (Bragg peak shift), and (c) strains in real space (PDF peak shift), were compared to each other. All monitored and calculated strains for tricalcium silicate-fly ash (50 wt% fly ash) paste were compared with the counterparts of the pure tricalcium silicate paste. Pair distribution function analysis in the range of r < 10 Å indicated that the atomic arrangement of tricalcium silicate-fly ash was similar to that of synthetic calcium silicate hydrates followed by that of pure tricalcium silicate paste. Moreover, the pair distribution function refinement results revealed that the calcium silicate hydrate structure in tricalcium silicate-fly ash paste was similar to tobermorite 11 Å, unlike that in pure tricalcium silicate paste. The interatomic strain of tricalcium silicate-fly ash in the real space (r < 20 Å) was smaller than that of tricalcium silicate under compression, which suggested that the incompressibility of calcium silicate hydrates at atomistic scale was enhanced by the incorporation of fly ash into it. This was likely to be caused by the increased silicate polymerization of calcium silicate hydrates, which was attributed to the increase in the amount of silicate in their structure via the addition of fly ash.     

A time-varying lot sizes approach for the economic lot scheduling problem with returns

We consider the economic lot scheduling problem with returns by assuming that each item is returned by a constant rate of demand. The goal is to find production frequencies, production sequences, production times, as well as idle times for several items subject to returns at a single facility. We propose a heu ristic algorithm based on a time-varying (TV) lot sizes approach. The problem is decomposed into two distinct portions: in the first, we find a combinatorial part (production frequencies and sequences) and in the second, we determine a continuous part (production and idle times) in a specific production sequence. We report computational results that show that, in many cases, the proposed TV lot sizes approach with consideration of returns yields a relatively minor error.     

Texture development and deformation behavior of a statically recrystallized Mg-Al-Zn alloy sheet

A statically recrystallized Mg-3Al-1Zn alloy was fabricated by low temperature roll heating (140 °C) processes and subsequent annealing at 250 °C for 5 min. The fabricated sheet, with a grain size of 4.1 m, shows an improved planar anisotropy and higher elongations to failure at room temperature and 200 °C, compared with those of the sheet fabricated by conventional hot rolling processes, due to the weak basal texture along with the refined microstructure.     

Role of spheroidized carbides on the fatigue life of bearing steel

The fatigue characteristics of bearing steel in ultrasonic fatigue tests are investigated with regard to the role of spheroidized carbides. The results show that, despite a similar hardness level, the bearing steel with spheroidized carbide has a much longer fatigue life than steel without, and that the failure mechanism differs in each case. All the samples of SAQT-processed steel examined using ultrasonic fatigue tests were characterized by a conventional fish-eye structure, which implies they went through subsurface-originated or interior inclusion-induced failure. On the contrary, it was shown that surface-induced failure prevailed in the QT-processed steel without spheroidized carbide. The results suggest spheroidized carbide may strengthen the tempered martensitic matrix of the bearing steel and concentrate the stress around an inclusion rather than at the surface, allowing for prolonged fatigue life over the steel without spheroidized carbide.     

Flexible sodium‐ion supercapacitor based on polypyrrole/carbon electrode by use of harmless aqueous electrolyte for wearable devices

With the emergence of various wearable devices, supercapacitors have gained immense attention because of their fast response rates. However, most supercapacitors use hazardous electrolyte materials, such as H₂SO₄, KOH, and acetonitrile. Leakage of these types of electrolytes during use would be very harmful to human skin. Therefore, a supercapacitor that does not employ hazardous materials is an attractive option for use in the energy‐storage components of wearable devices. Herein, we successfully demonstrate a Na‐ion supercapacitor (NISC) with a polypyrrole/carbon‐coated heat‐treated carbon felt electrode and an aqueous 0.4 M NaCl electrolyte, which is not harmful. Furthermore, our NISC with polypyrrole/carbon‐coated heat‐treated carbon felt exhibits a high specific capacitance (31.09 F g^?1) and a fast response rate (chargeable at 0.5‐s intervals). The proposed NISC with no harmful materials in the electrolyte has an excellent response rate. It will establish useful guidelines for the energy‐storage components in wearable devices Copyright © 2017 John Wiley & Sons, Ltd.     

Inhibitory effect of cinnamon essential oils on selected cheese-contaminating fungi (Penicillium spp.) during the cheese-ripening process

The antifungal effects of essential oils (EOs) on cultures of the known cheese fungal contaminants Penicillium spp. were evaluated. Cinnamon leaf and bark EOs were the most effective among 8 EOs tested. The main components of both cinnamon EOs were eugenol, cinnamaldehyde, and linalool. Both inhibited growth of Penicillium spp. at a concentration of 10% v/v (2,000 ppm/mm²) on a lawn cell plate. When tested using 3 commercially available cheese starters, cinnamon EOs showed no effect against the FD-DVS ABT-5 cheese starter. However, growth of lactobacilli was inhibited in the presence of ≥10% (v/v) of leaf and bark EOs for the KAZU 1 starter, and ≥5% (v/v) for the FD-DVS FLORA-DANICA starter. A concentration of 4,000 ppm/mm² of cinnamon EOs completely inhibited growth of the Penicillium spp. that naturally contaminates the surface of Appenzeller cheese.     

Development of an apparatus for removing magnetic sludge by permanent magnets setup in the condenser of the power plant

In this paper, permanent magnets are used to remove magnetic sludge in the condenser of the power plant. To obtain the flow characteristics and magnetic information that are needed for determining a proper design of the magnetic sludge removal apparatus, we performed numerical simulations through the use of two commercial codes, ANSYS Workbench-Emag and CFX. We also performed experiments on various kinds and sizes of magnets to obtain the magnetic information through a gauss meter. By analyzing the results of simulations and experiments, the minimum magnetic force that is able to remove the any size of the magnetic sludge in the condenser was calculated, and the design of the removal apparatus was confirmed. We made the test model which was confirmed by the simulations and experiments for the tests of efficiency of the removal apparatus. After testing, the test results were compared with those of numerical simulations and have good agreements.     

Carbon-coated iron oxide nanoparticles as contrast agents in magnetic resonance imaging

Coprecipitated ferrite nanoparticles were coated with carbon using a hydrothermal method. From transmission electron microscope pictures, we could see that the coated iron oxide nanoparticles were spherical in shape with an average diameter of 90 nm. The strong bonding of carbon on the nanoparticle surfaces was checked by noting the C = O and C = C vibrations in Fourier transform infrared spectra. The spin-lattice relaxation process [T ₁] and spin-spin relaxation process [T ₂] relaxivities of hydrogen protons in the aqueous solution of coated nanoparticles were determined to be 1.139 (mM·s)^-1 and 1.115 (mM·s)^-1, respectively. These results showed that the carbon-coated iron oxide nanoparticles are applicable as both T ₁ and T ₂ contrast agents in magnetic resonance imaging.     

Selective hydrogenation of 4-isobutylacetophenone over a sodium-promoted Pd/C catalyst

The effect of sodium promotion on the selective hydrogenation of 4-isobutylacetophenone, 4-IBAP, was investigated over a Pd/C catalyst. A precipitation and deposition method was used to prepare the catalyst, and sodium was promoted on the Pd/C catalyst via post-impregnation while varying the sodium content. The sodium-promoted Pd/C catalyst resulted in a significantly improved yield greater than 96% of the desired product, 1-(4-isobutylphenyl) ethanol (4-IBPE), compared with the non-patented literature results under a mild hydrogenation condition. A detailed hydrogenation network over the Pd/C catalyst was suggested. The reaction mechanism for the yield and selectivity enhancement of 4-IBPE induced-by the promoted Pd/C was elucidated in relation to the geometric and electronic effects of reactant molecules in the microporous support depending on the reaction steps.