549.
Strontium chloride (SrCl
2) as ammonia (NH
3) carriers has been widely exploited due to its high ammonia uptake capacity and low energy penalty for ammonia release. However, the dramatic volume swing during absorption–desorption cycles, from SrCl
2 to Sr(NH
3)
8Cl
2 to SrCl
2, imposes a challenge to structure SrCl
2 for ammonia storage applications. Herein, a novel porous SrCl
2 structure with SrCl
2 loading up to 96 wt%, scaffolded by reduced graphene oxide (rGO) networks is reported. The optimized porous SrCl
2-rGO composite with 80 wt% SrCl
2 loading maintains the macro- and micro-structure accommodating the volume swing during ammonia absorption–desorption cycles without disintegration, whereas structured SrCl
2 pellets disintegrates directly after the first cycle of NH
3 absorption. The structured porous 80 wt% SrCl
2-rGO composite demonstrates rapid absorption–desorption kinetics, 140% faster in absorption and 540% faster in desorption compared with pure SrCl
2 pellet. The enhancement of the surface area and the presence of SrCl
2 particles in the pores of rGO networks result in a robust and stable structure offering rapid ammonia absorption–desorption kinetics while countermining the volume swing by self-adjusting “breathing.”
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