Changes in kinetic parameters of decomposition of MgH2 destabilized by irradiation with C ions

In attempt to improve desorption behaviour of MgH₂, the influence of well-defined structural changes induced within a thin surface layer of MgH₂ have been investigated. The defects were induced by 30 keV C²⁺ ions irradiation using different fluencies ranging from 10¹²–10¹⁶ ions/cm². The hydrogen desorption properties were investigated by thermal desorption spectroscopy analysis (TDS), while kinetics parameters were deduced using non-isothermal kinetic approach. The existence of multiple TDS peaks and different curve shapes indicate difference in desorption mechanism. To understand changes in the rate limiting step, shapes of all desorption peaks have been analyzed using different kinetic models. Regarding the irradiated sample, the function based on Avrami–Erofeev model with n=4$n=4$ gives the best fit over θ   range from 0.3 to 0.8 while for untreated sample the best fit is obtained for Avrami–Erofeev model with n=3$n=3$. The change in mechanism can be attributed to the different way of nuclei growth.     

Optimisation of microwave‐assisted extraction of phenolic compounds from broccoli and its antioxidant activity

The effect of independent variables of microwave‐assisted extraction (MAE), extraction temperature (50–90 °C), microwave power (100–200 W), solvent concentration (methanol/water, 50–90%, v/v) and extraction time (1–27 min) on total phenolics and flavonoids contents as well as antioxidant activity of broccoli extracts was investigated. Response surface methodology was successfully applied for optimisation and the high correlation of the mathematical model indicated that a quadratic polynomial model could be used for optimisation of investigated responses. Considering the maximum amount of extracted total phenolics, total flavonoids and antioxidant activity expressed as ORAC value, the optimal conditions for all three investigated responses were obtained (temperature ?71.11 °C; microwave power ?167.03 W; solvent concentration ?75.95%; and extraction time 16.34 min), which is in agreement with optimal conditions obtained for each investigated responses. The development of simultaneously MAE methods for total phenolics, total flavonoids and antioxidant activity of broccoli extracts might simplify assessment of broccoli as valuables source of antioxidants.     

Marangoni heat transfer in subcooled nucleate pool boiling

The liquid motion induced by surface tension variation, termed the Marangoni effect, and its contribution to boiling heat transfer has been an issue of much controversy. Boiling heat transfer theory, although acknowledging its existence, considers its contribution to heat transfer to be insignificant in comparison with buoyancy induced convection. However, recent microgravity experiments have shown that although the boiling mechanism in a reduced gravity environment is different, the corresponding heat transfer rates are similar to those obtained under normal gravity conditions, raising questions about the validity of the assumption. An experimental investigation was performed in which distilled water was gradually heated to boiling conditions on a copper heater surface at four different levels of subcooling. Photographic investigation of the bubbles appearing on the surface was carried out in support of the measurements. The results obtained indicate that Marangoni convection associated with the bubbles formed by the air dissolved in the water which emerged from solution when the water was heated sufficiently, significantly influenced the heat transfer rate in subcooled nucleate pool boiling. A heat transfer model was developed in order to explain the phenomena observed.     

Repeating of positive and negative high electric field stress and corresponding thermal post-stress annealing of the n-channel power VDMOSFETs

We have subjected n-channel power VDMOSFETs to a positive and negative high electric field stress (HEFS) followed by biased annealing at 150 °C. Stress-induced defects have been monitored using midgap-subthreshold and charge-pumping techniques, the use of which in tandem has enabled an insight into behaviours of fixed and switching traps in the gate oxide and oxide/silicon interface. The repetition of the stress/annealing sequence has resulted in some quantitative but no qualitative differences in response compared to the original sequence. We have observed complex kinetics of different types the stress-induced defects during post-HEFS annealing, including an intriguing latent buildup of “true” interface traps. Comparison of post-HEFS and post-irradiation annealing data has indicated differences of the nature of defects induced by Fowler-Nordheim injection and irradiation in our samples.     

Performance trade-offs in single-photon avalanche diode miniaturization

Single-photon avalanche diodes (SPADs) provide photons' time of arrival for various applications. In recent years, attempts have been made to miniaturize SPADs in order to facilitate large-array integration and in order to reduce the dead time of the device. We investigate the benefits and drawbacks of device miniaturization by characterizing a new fast SPAD in a commercial 0.18 microm complementary metal oxide semiconductor technology. The device employs a novel and efficient guard ring, resulting in a high fill factor. Thanks to its small size, the dead time is only 5 ns, resulting in the fastest reported SPAD to date. However, the short dead time is accompanied by a high after-pulsing rate, which we show to be a limiting parameter for SPAD miniaturization. We describe a new and compact active-recharge scheme which improves signal-to-noise tenfold compared with the passive configuration, using a fraction of the area of state-of-the-art active-recharge circuits, and without increasing the dead time. The performance of compact SPADs stands to benefit such applications as high-resolution fluorescence-lifetime imaging, active-illumination three-dimensional imagers, and quantum key distribution systems.     

Integrating rush orders into existent schedules for a complex job shop problem

This paper investigates the problem of inserting new rush orders into a current schedule of a real world job shop floor. Effective rescheduling methods must achieve reasonable levels of performance, measured according to a certain cost function, while preserving the stability of the shop floor, i.e. introducing as few changes as possible to the current schedule. This paper proposes new and effective match-up strategies which modify only a part of the schedule in order to accommodate the arriving jobs. The proposed strategies are compared with other rescheduling methods such as “right shift” and “insertion in the end”, which are optimal with respect to stability but poor with respect to performance, and with “total rescheduling” which is optimal with respect to performance but poor with respect to stability. Our results and statistical analysis reveal that the match-up strategies are comparable to the “right shift” and “insertion in the end” with respect to stability and as good as “total rescheduling” with respect to performance.     

Adsorption of lipase from Candida rugosa on multi walled carbon nanotubes

In this work lipase from Candida rugosa was adsorbed on unmodified surface of multi walled carbon nanotubes (raw-MWCNT). The effects of immobilization time, initial enzyme concentration and buffer ionic strength on enzyme loading and activity of immobilized preparations were tested. High loadings are attained. The immobilized enzyme obtained at lowest initial enzyme concentration and high ionic strength retained 85% of initial enzyme activity. It is assumed that immobilization on hydrophobic surface led to conformational changes that resulted in the adsorption of lipase in active conformation. Immobilized preparations were characterized, with FT-IR spectroscopy, AFM, and cyclic voltammetry.