Augmenting the performance of acrylonitrile–butadiene–styrene plastics for low‐noise dynamic applications

The main objective of this study was to enhance the performance of acrylonitrile–butadiene–styrene (ABS) plastics for dynamic structural applications, including those of automobile relevance. First, ABS was modified by blending with maleic anhydride grafted styrene–ethylene–butadiene–styrene block copolymer (MA‐g‐SEBS) in various proportions. Squeaking noise characteristics were evaluated by measurement of the frictional behavior in an in‐house fabricated friction testing apparatus, and the results are explained on the basis of the change in surface energy upon modification. Detailed dynamic mechanical analyses (strain, frequency, and temperature sweep) revealed significant improvements in the damping characteristics of the modified ABS, especially that modified with 10 wt % MA‐g‐SEBS, without much sacrifice in its mechanical strength. The modulus values predicted with Kerner's model of the blends were well correlated with the morphological changes upon modification. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Improved area—energy targeting for fired heater integrated heat exchanger networks

Effective integration of various subsystems into the overall process, results in an energy efficient and economic plant design. In this paper, issues related to the area-energy targeting for fired heater integrated heat exchanger networks are studied. Performance of a fired heater is affected by the variables such as fuel fired and air-preheat temperature. These variables along with the minimum approach temperature difference for the heat recovery of the background process, affect the performance of the overall system. A methodology is proposed for the area-energy targeting for fired heater integrated processes. In the proposed methodology, the fired heater heat duty split between the radiation and the convection section is determined using the one gas zone furnace model.     

Quantifying the stress relaxation modulus of polymer thin films via thermal wrinkling

The viscoelastic properties of polymer thin films can have a significant impact on the performance in many small-scale devices. In this work, we use a phenomenon based on a thermally induced instability, termed thermal wrinkling, to measure viscoelastic properties of polystyrene films as a function of geometric confinement via changes in film thickness. With application of the appropriate buckling mechanics model for incompressible and geometrically confined films, we estimate the stress-relaxation modulus of polystyrene films by measuring the time-evolved wrinkle wavelength at fixed annealing temperatures. Specifically, we use time-temperature superposition to shift the stress relaxation curves and generate a modulus master curve for polystyrene films investigated here. On the basis of this master curve, we are able to identify the rubbery plateau, terminal relaxation time, and viscous flow region as a function of annealing time and temperatures that are well-above its glass transition. Our measurement technique and analysis provide an alternative means to measure viscoelastic properties and relaxation behavior of geometrically confined polymer films.     

Amorphous silicon–carbon based nano-scale thin film anode materials for lithium ion batteries

The buffering effect of carbon on the structural stability of amorphous silicon films, used as an anode for lithium ion rechargeable batteries, has been studied during long term discharge/charge cycles. To this extent, the electrochemical performance of a prototype material consisting of amorphous Si thin film (∼250 nm) deposited by radio frequency magnetron sputtering on amorphous carbon (∼50 nm) thin films, denoted as a-C/Si, has been investigated. In comparison to pure amorphous Si thin film (a-Si) which shows a rapid fade in capacity after 30 cycles, the a-C/Si exhibits excellent capacity retention displaying ∼0.03% fade in capacity up to 50 cycles and ∼0.2% after 50 cycles when cycled at a rate of 100 μA/cm² (∼C/2) suggesting that the presence of thin amorphous C layer deposited between the Cu substrate and a-Si acts as a buffer layer facilitating the release of the volume induced stresses exhibited by pure a-Si during the charge/discharge cycles. This structural integrity combined with microstructural stability of the a-C/Si thin film during the alloying/dealloying process with lithium has been confirmed by scanning electron microscopy (SEM) analysis. The buffering capacity of the thin amorphous carbon layer lends credence to its use as the likely compliant matrix to curtail the volume expansion related cracking of silicon validating its choice as the matrix for bulk and thin film battery systems.     

Role of spacer lengths of gemini surfactants in the synthesis of silver nanorods in micellar media

In this work, we have prepared Ag-nanorods using biscationic gemini surfactant micelles as the media by a seed-mediated wet synthesis method. Towards this end, we first synthesized Ag-nanoseeds of diameter ~7 nm stabilized by trisodium citrate (as the capping agent). Then these Ag-nanoseeds were used to synthesize Ag-nanorods of different aspect ratios. With decreasing Ag-nanoseed concentration, the aspect ratios of the Ag-nanorods stabilized by these gemini surfactants increased gradually. Various Ag-nanoseeds and Ag-nanospecies were characterized using UV-Vis spectroscopy (to know the surface plasmon bands), transmission electron microscopy (to find out their particle sizes and distribution), energy-dispersive X-ray spectroscopy and X-ray diffraction. When we used micelles derived from gemini surfactants of shorter spacer -(CH(2))(n)- (n = 2 or 4) to stabilize the Ag-nanorods, the λ(max) of the longitudinal band shifted more towards the blue region compared to that of the gemini surfactant micelles with a longer spacer -(CH(2))(n)- (n = 5, 12) at a given amount of the Ag-nanoseed solution. So, the growth of Ag-nanorods in the gemini micellar solutions depends on the spacer-chain length of gemini surfactants employed.     

Resistive switching memory characteristics of Ge/GeOx nanowires and evidence of oxygen ion migration

The resistive switching memory of Ge nanowires (NWs) in an IrO_x/Al₂O₃/Ge NWs/SiO₂/p-Si structure is investigated. Ge NWs with an average diameter of approximately 100 nm are grown by the vapor–liquid-solid technique. The core-shell structure of the Ge/GeO_x NWs is confirmed by both scanning electron microscopy and high-resolution transmission electron microscopy. Defects in the Ge/GeO_x NWs are observed by X-ray photoelectron spectroscopy. Broad photoluminescence spectra from 10 to 300 K are observed because of defects in the Ge/GeO_x NWs, which are also useful for nanoscale resistive switching memory. The resistive switching mechanism in an IrO_x/GeO_x/W structure involves migration of oxygen ions under external bias, which is also confirmed by real-time observation of the surface of the device. The porous IrO_x top electrode readily allows the evolved O₂ gas to escape from the device. The annealed device has a low operating voltage (<4 V), low RESET current (approximately 22 μA), large resistance ratio (>10³), long pulse read endurance of >10⁵ cycles, and good data retention of >10⁴ s. Its performance is better than that of the as-deposited device because the GeO_x film in the annealed device contains more oxygen vacancies. Under SET operation, Ge/GeO_x nanofilaments (or NWs) form in the GeO_x film. The diameter of the conducting nanofilament is approximately 40 nm, which is calculated using a new method.     

Quasi-elliptic filter characteristics of an asymmetric defected ground structure

An asymmetric defected ground structure (DGS) with respect to a microstrip line is proposed. Its unit cell consists of two square slots connected with a rectangular slot by meandered transverse slots. The simulated, measured and equivalent circuit responses have been presented. The unit DGS pattern under microstrip line produces wide rejection bandwidth and high sharpness factor. Its elliptic band-reject filter response is modelled by appropriate LC equivalent circuit. Two such DGS cells under a microstrip line produce 3-pole quasi-elliptic bandstop filter response, which shows deeper attenuation without appreciable change in pole frequencies in comparison to single cell structure. Unit DGS pattern under coupled gap microstrip lines produces band-accept filtering characteristics. The frequency characteristics show a quasi-elliptic highpass filtering characteristics with sharp lower transition knee. Accordingly, an LC equivalent circuit is proposed. A cascaded band-accept and band-reject filter is proposed for designing a wideband bandpass filter. The bandwidth and centre frequency of the bandpass filter can be varied by choosing different set of DGS dimensions.     

Design of solar thermal systems utilizing pressurized hot water storage for industrial applications

A large number of industrial processes demand thermal energy in the temperature range of 80–240 °C. In this temperature range, solar thermal systems have a great scope of application. However, the challenge lies in the integration of a periodic, dilute and variable solar input into a wide variety of industrial processes. Issues in the integration are selection of collectors, working fluid and sizing of components. Application specific configurations are required to be adopted and designed. Analysis presented in this paper lays an emphasis on the component sizing. The same is done by developing a design procedure for a specific configuration. The specific configuration consists of concentrating collectors, pressurized hot water storage and a load heat exchanger. The design procedure follows a methodology called design space approach. In the design space approach a mathematical model is built for generation of the design space. In the generation of the design space, design variables of concern are collector area, storage volume, solar fraction, storage mass flow rate and heat exchanger size. Design space comprises of constant solar fraction curves traced on a collector area versus storage volume diagram. Results of the design variables study demonstrate that a higher maximum storage mass flow rates and a larger heat exchanger size are desired while limiting storage temperature should be as low as possible. An economic optimization is carried out to design the overall system. In economic optimization, total annualized cost of the overall system has been minimized. The proposed methodology is demonstrated through an illustrative example. It has been shown that 23% reduction in the total system cost may be achieved as compared to the existing design. The proposed design tool offers flexibility to the designer in choosing a system configuration on the basis of desired performance and economy.     

Neuro fuzzy model for adaptive filtering of oscillatory signals

In this paper we have developed a neuro fuzzy model for adaptive filtering of oscillatory signals embedded with white noise. Such type of fuzzy adaptive filters are constructed from a set of fuzzy IF-THEN rules, which change adaptively to minimise the cost function until a desired information is available. Here we have used a generalised cost function for better convergence of the error. This algorithm is simulated on a digital signal processor in order to track the signal and to filter out the disturbances present in the signal at a particular instant of time. The system presented here, can measure both types of information like numerical as well as linguistic.     

Process integration of organic Rankine cycle

An organic Rankine cycle (ORC) uses an organic fluid as a working medium within a Rankine cycle power plant. ORC offers advantages over conventional Rankine cycle with water as the working medium, as ORC generates shaft-work from low to medium temperature heat sources with higher thermodynamic efficiency. The dry and the isentropic fluids are most preferred working fluid for the ORC. The basic ORC can be modified by incorporating both regeneration and turbine bleeding to improve its thermal efficiency. In this paper, 16 different organic fluids have been analyzed as a working medium for the basic as well as modified ORCs. A methodology is also proposed for appropriate integration and optimization of an ORC as a cogeneration process with the background process to generate shaft-work. It has been illustrated that the choice of cycle configuration for appropriate integration with the background process depends on the heat rejection profile of the background process (i.e., the shape of the below pinch portion of the process grand composite curve). The benefits of integrating ORC with the background process and the applicability of the proposed methodology have been demonstrated through illustrative examples.