全文获取类型
收费全文 | 8540篇 |
免费 | 710篇 |
国内免费 | 7篇 |
专业分类
电工技术 | 65篇 |
综合类 | 6篇 |
化学工业 | 1971篇 |
金属工艺 | 129篇 |
机械仪表 | 170篇 |
建筑科学 | 355篇 |
矿业工程 | 23篇 |
能源动力 | 224篇 |
轻工业 | 2264篇 |
水利工程 | 82篇 |
石油天然气 | 73篇 |
无线电 | 463篇 |
一般工业技术 | 1689篇 |
冶金工业 | 390篇 |
原子能技术 | 45篇 |
自动化技术 | 1308篇 |
出版年
2024年 | 15篇 |
2023年 | 93篇 |
2022年 | 119篇 |
2021年 | 290篇 |
2020年 | 227篇 |
2019年 | 255篇 |
2018年 | 387篇 |
2017年 | 409篇 |
2016年 | 390篇 |
2015年 | 289篇 |
2014年 | 393篇 |
2013年 | 830篇 |
2012年 | 573篇 |
2011年 | 599篇 |
2010年 | 498篇 |
2009年 | 467篇 |
2008年 | 477篇 |
2007年 | 441篇 |
2006年 | 340篇 |
2005年 | 218篇 |
2004年 | 196篇 |
2003年 | 206篇 |
2002年 | 202篇 |
2001年 | 154篇 |
2000年 | 139篇 |
1999年 | 125篇 |
1998年 | 177篇 |
1997年 | 108篇 |
1996年 | 82篇 |
1995年 | 84篇 |
1994年 | 71篇 |
1993年 | 46篇 |
1992年 | 32篇 |
1991年 | 32篇 |
1990年 | 26篇 |
1989年 | 28篇 |
1988年 | 23篇 |
1987年 | 16篇 |
1986年 | 21篇 |
1985年 | 25篇 |
1984年 | 33篇 |
1983年 | 26篇 |
1982年 | 17篇 |
1981年 | 7篇 |
1980年 | 11篇 |
1979年 | 9篇 |
1977年 | 7篇 |
1976年 | 15篇 |
1973年 | 5篇 |
1971年 | 5篇 |
排序方式: 共有9257条查询结果,搜索用时 15 毫秒
71.
Ricardo I. Perez-Martin Jose M. Franco Santiago Aubourg Jose M. Gallardo 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1988,187(5):432-435
Summary The effects of cooking and sterilization at several temperatures on the free amino acids (FAA) content in albacore (Thunnus alalunga) muscle were studied during the processing of canned tuna. FAAs were derivatized witho-phtalaldehyde, separated on a C18 column by HPLC and detected by both fluorescence and ultra-violet detectors. After cooking the loss of FAAs was not significant. However, in the final product sterilized at 115 °C and 110 °C (throughout the whole process) there were significant losses with regard to the start material, but not at 118 °C (all temperatures leading to the same lethal F-value). The influence of the thermal process time at 115 °C was evaluated for 60 and 100 min. Significant losses were found between both canned products (25%) and between the raw fish and the final product (12% and 34%, process time 60 and 100 min, respectively). The determination of the content of FAA present in canned albacore may be a useful indication of the severity of the thermal processing.
Veränderung im Gehalt an freien Aminosäuren in Thunfischmuskel (Tunnus alalunga) während der Wärmebehandlung
Zusammenfassung Die Wirkung des Kochens und Sterilisierens bei verschiedenen Temperaturen auf den Gehalt an freien Aminosäuren (FAA) im Thunfischmuskel (Thunnus alalunga) wurde während der Herstellung von Thunfischkonserven untersucht. Die freien Aminosäuren wurden mito-Phtalaldehyd derivatisiert, auf einer C-18-Kolonne mit HPLC abgetrennt und durch Fluorescenz und UV-Detektoren nachgewiesen. Nach dem Kochen war der Verlust an FAA nicht signifikant, jedoch in dem bei 110° und 115 °C sterilisierten Endprodukt ergaben sich signifikante Verluste bezogen auf das Ausgangsmaterial, aber nicht auf das bei 118 °C erhitzte; alle Erhitzungstemperaturen führen zu demselben letalen F-Wert. Der Zeiteinfluß der Erhitzung bei 115 °C wurde bei 60 und 100 min bewertet. Signifikante Verluste sind bei beiden Dosenkonserven aufgetreten (25%) und zwischen diesen und dem Rohfisch ( 12% und 34%) bei einer Erhitzungszeit von 60 und 100 min). Die Bestimmung des FAA-Gehalts in Thunfischkonserven kann für den Nachweis der Einwandfreiheit des thermischen Prozesses sehr nützlich sein.相似文献
72.
The perovskite-type oxide PrCoO3 has been studied by means of X-ray photoelectron spectroscopy (XPS), reduction in H2 and X-ray diffraction. Two types of oxygen were detected: lattice oxygen (binding energy = 528.4 eV) and adsorbed oxygen (binding energy = 530.9 eV). The increase in relative intensity of the peak corresponding to the latter species after reduction of PrCo03 to 3e– per molecule is assigned to the formation of hydroxyl groups. Temperature-programmed reduction (TPR) results showed two reduction steps: to 1 e– per molecule (Co3.1 Co2+) at 475 to 635 K, and to 3e– per molecule (Co21 Co0) at 725 to 815 K. Reduction in the first and second steps occurs according to the contracting sphere model and the nucleation mechanism, respectively. Reduction of Co3+ to Co2+ causes minimal structural changes in the perovskite. Reduction to 3e– per molecule yielded Pr2O3 and metallic cobalt. After this reduction and reoxidation at 973 K, the perovskite structure was regained. By XPS and TPR it was shown that PrCo03 is more easily reducible than LaCo03. It is concluded that the cation in the A position of the structure plays a significant role in the bulk and surface properties of LnCo03 (Ln, lanthanide elements) oxides. 相似文献
73.
Victor Sosa J. A. Azamar-Barrios J. L. Peña L. Francisco Garfias A. I. Oliva P. Quintana 《Journal of Materials Science》1992,27(22):6131-6133
Synthesis of ceramic YBa2Cu3O7– by solid-state reaction was performed under different conditions. Different values of cooling rate and oxygen flow were used, and no significant influence on superconducting characteristics of the samples was observed. A major influence on their mechanical properties was found. 相似文献
74.
75.
María A. Vasco-Mogorrn Jos A. Campillo Adela Periago Valentin Cabaas Mercedes Berenguer María C. García-Garay Lourdes Gimeno María F. Soto-Ramírez María D. Martínez-Hernndez Manuel Muro Alfredo Minguela 《International journal of molecular sciences》2021,22(8)
Proliferation and apoptosis of neoplastic cells are prognostic biomarkers in plasma cell neoplasms (PCNs). The prognostic capacity of proliferation to apoptosis ratio (Ratio-PA) in the era of immunomodulatory treatments is re-evaluated in 316 gammopathy of undetermined significance (MGUS), 57 smoldering multiple myeloma (SMM), and 266 multiple myeloma (MM) patients. Ratio-PA of 0.77 ± 0.12, 1.94 ± 0.52, and 11.2 ± 0.7 (p < 0.0001) were observed in MGUS, SMM, and MM patients. Ten-year overall survival (10y-OS) rates for patients with low/high Ratio-PA were 93.5%/77.3% p < 0.0001) for MGUS, 82.5%/64.7% (p < 0.05) for SMM, and 62.3%/47.0% (p < 0.05) for MM. For patients with low, intermediate, and high risk, 10y-OS for low/high Ratio-PA were 95.5%/72.9% (p < 0.0001), 74.2%/50.4% (p < 0.0001), and 35.3%/20.0% (p = 0.836), respectively. Ratio-PA was an independent prognostic factor for OS (HR = 2.119, p < 0.0001, Harrell-C-statistic = 0.7440 ± 0.0194) when co-analyzed with sex, age, and standard risk. In patients with Ratio-PAhigh, only first-line therapy with VRd/VTd, but not PAD/VCD, coupled with ASCT was associated with high 10y-OS (82.7%). Tumor cell Ratio-PA estimated at diagnosis offers a prognostic biomarker that complements standard risk stratification and helps to guide the clinical management of pre-malignant and symptomatic PCNs. Every effort should be made to provide first-line therapies including VTd or VRd associated with ASCT to patients with Ratio-PAhigh at higher risk of progression and death. 相似文献
76.
Fernando Corvillo Laura Gonzlez-Snchez Alberto Lpez-Lera Emilia Arjona Giovanni Ceccarini Ferruccio Santini David Araújo-Vilar Rebecca J Brown Joan Villarroya Francesc Villarroya Santiago Rodríguez de Crdoba Teresa Caballero Pilar Nozal Margarita Lpez-Trascasa 《International journal of molecular sciences》2021,22(12)
77.
Patricia Muñoz-Escalona Shreyes Melkote Kai Liu 《Journal of Materials Engineering and Performance》2005,14(5):582-590
In recent years, the finite element method (FEM) has become the main tool for simulating the metal cutting process because
research based on trial and error is time consuming and requires high investment. Early studies were done by different investigators.
In this research AISI 52100, hardened steel (62 HRC) was selected for an orthogonal machining process as well as metal cutting
simulation using the software DEFORM-2D. This software is based on a forging process and has been adapted to an orthogonal
machining process. The results of simulated cutting forces were compared with experimental cutting force data to validate
the orthogonal cut simulation. Also, the surface roughness was measured, and the influence of the stress, strain, and temperature
on the surface roughness was studied. 相似文献
78.
E. I. Basaldella J.C. Tara G. Aguilar Armenta M. E. Patiño Iglesias 《Journal of Porous Materials》2007,14(3):273-278
Samples of mesoporous silica SBA-15 were prepared under hydrothermal conditions where Cu cations were incorporated to the
structure by impregnation in order to compare the adsorption behavior in the presence and absence of this element. The adsorption/desorption
equilibrium isotherms of propylene, propane, and N2 were measured to evaluate their usefulness in the propane/propylene separation.
All the adsorption isotherms of SBA-15 measured in the absence of Cu cations were described by the Freundlich equation, while
the adsorption isotherms of propane on Cu/SBA-15 were better represented by the Henry equation and those of propylene were
satisfactorily described by the Langmuir model in the range P < 100 Torr. The adsorption uptake of propylene increased and that of propane decreased in Cu/SBA-15 as compared to the amounts
observed in the SBA-15 sample. The presence of Cu atoms in the adsorbent lattice increased the selectivity towards propylene.
Under some working conditions the adsorbed amount of propylene in Cu/SBA-15 sample was totally reversible and the propane
uptake, negligible. 相似文献
79.
Raffaele Sacchi Isabel Medina Santiago P. Aubourg Francesco Addeo Livio Paolillo 《Journal of the American Oil Chemists' Society》1993,70(3):225-228
Based on proton nuclear magnetic resonance (1H-NMR) spectroscopy, a rapid and structure-specific method for the determination of ω-3 polyunsaturated fatty acids (PUFAs)
in fish lipids is presented. The different chemical shift observed for the methyl resonance of ω-3 PUFAs (δ=0.95 ppm) with
respect to the methyl resonance of all other fatty acids (δ=0.86 ppm) has provided the possibility of proposing a new and
rapid method for the determination of ω-3 PUFA content. Twenty-four fish lipid samples (raw, cooked and canned albacore tuna)
produced results that showed good agreement between1H-NMR analysis and gas chromatographic determination. Raw and cooked samples showed significantly higher levels of ω-3 PUFA
than canned tuna. 相似文献
80.
A series of semi-interpenetrating polymer networks (semi-IPN's) based on different compositions of an acyclic polyethylene terephthalate oligomer and unsaturated polyester resin (UP) were prepared. The oligomer was dissolved in the resin containing styrene crosslinker. Later this mixture was crosslinked at room temperature using methyl ethyl ketone peroxide catalyst and cobalt naphtanate as promoter. The tensile strength of the IPN's decreases as the concentration of oligomer increases, whereas, elongation to break increases. A characterization of the oligomer used is also presented. 相似文献