In this paper the effect of two pre-treatment methods are compared experimentally for the filtration of (i) a spent sulphite liquor (17.8 wt.% dry solids) using a 20 kg mol−1 molar mass cut off (MMCO) fluoropolymer membrane and (ii) a molasses solution (45° Brix) using a polysulphone (Psf) membrane (1.5 μm pore size). Both feeds are industrially relevant, and subject to severe fouling issues when membranes are used in their subsequent processing. The pre-treatment methods evaluated were: (i) conditioning with water at 60 °C only [Protocol 1], and (ii) conditioning with water at 60 °C followed by cleaning with 0.5 wt.% NaOH [Protocol 2]. Results are presented that confirm the benefits of sodium hydroxide preconditioning upon performance, supporting the suggestion by some membrane manufacturers that this step be included as part of the pre-treatment protocol. 相似文献
The performance of a portable infrared system combined with pattern recognition to discriminate between organically and conventionally produced bovine butter samples as well as to predict the levels of conjugated linoleic acid (CLA) were evaluated. Sixty butter (27 organic and 33 conventional) samples were used in this study. Bovine butter–fat were applied onto an attenuated total reflectance infrared (ATR‐IR) accessory equipped with a five‐bounce ZnSe crystal set at 65 °C for spectral collection. In addition, ATR‐IR spectra of bovine butter were directly collected at room temperature to avoid phase separation. The fatty acid profile and the levels of CLA were determined using reference FAME‐GC‐FID analysis. SIMCA models showed well separated clusters that discriminated between organic and conventional bovine butters due to C=C trans bending out of the plane vibration modes band at 967 cm?1. Additionally, strong PLSR models were developed to predict CLA levels using butter–fat and bovine butter spectra with SEP of 0.05 % and RPD of 4.7, indicating that the models are suitable for quality control applications. Portable IR technology offers the ability for “in situ” analysis of butters that is much less time consuming than current analytical practices for authentication and quality control efforts by the industry. 相似文献
Experience of retrofitting sustainable drainage systems (SuDS) in the United Kingdom is limited, and there are no well‐established procedures for evaluating the feasibility, value or cost‐effectiveness of doing this, particularly at the catchment scale. This paper demonstrates a two‐phase process for evaluating the potential to retrofit SuDS to address combined sewer discharges in three subcatchments within the Thames Tideway catchment of London. The first phase evaluates what might be achieved with various levels of disconnection (‘global’ disconnection scenarios) using hydraulic models, while the second phase considers how disconnection might practically be achieved. High levels of disconnection are technically possible but practicably difficult. In selected cases, and with aggressive implementation of SuDS, combined sewer overflow CSO discharges could potentially be eliminated or reduced to acceptable levels without the need for any modifications to underground assets. However, retrofit SuDS could not eliminate the requirement for some form of sewer modification in any subcatchments. 相似文献
In cake filtration processes with an air-blowing step, cracking is an undesirable phenomenon as it leads to deterioration of the filtration process by highly increasing gas throughput. This leads to higher residual moisture if the pressure difference cannot be maintained and an increase in overall cost. Crack formation can be avoided by compacting the filter cake before desaturation. While this action will make the separation process applicable by highly reducing gas consumption, there are also potential negative effects. Compaction increases filter cake resistance and might therefore slow down desaturation kinetics. Therefore, the authors investigated how the filter cake characteristics governing desaturation change from the nonconsolidated to the consolidated state of the filter cake and compared these findings to the actual dewatering kinetics. The results showed that for the case where cracking could be oppressed, dewatering kinetics of the consolidated cake are actually faster than for the nonconsolidated cake, despite higher resistance of the consolidated cake. Thus, compaction is an appropriate action when dealing with filter cake cracking. 相似文献
Microneedles are small needle‐like structures that are almost invisible to the naked eye. They have an immense potential to serve as a valuable tool in many medical applications, such as painless vaccination. Microneedles work by breaking through the stratum corneum, the outermost barrier layer of the skin, and providing a direct path for drug delivery into the skin. A lot of research has been presented over the past two decades on the applications of microneedles, yet the fundamental mechanism of how they interact, pressure, and penetrate the skin in its native state is worth examining further. As such, a major difficulty with understanding the mechanism of microneedle–skin interaction is the lack of an artificial mechanical human skin model to use as a standardized substrate. In this research news, the development of an artificial mechanical skin model based on a thorough mechanical study of fresh human and porcine skin samples is presented. The artificial mechanical skin model can be used to study the mechanical interactions between microneedles and skin, but not diffusion of molecules across skin. This model can assist in improving the performance of microneedles by enhancing the reproducibility of microneedle depth insertions for optimal drug delivery and biosensing.
Buildings feature a prominent role in electric grid loading, as they use about 75% of the total electricity generated in the United States and are main drivers of electric peak demand in the summer due to electrically driven air conditioning systems. Energy storage is a key technology that can increase energy cost savings, and add flexibility to the grid. However, cost is an important factor to consider. This study proposes a rapid approach that allows for visualization of potential cost savings by introducing energy storage as a peak load control for residential buildings in California. A combination of EnergyPlus load data generation, Matlab post-processing, and Google Fusion Tables data presentation analyses the potential cost savings when energy storage is implemented and TOU rates are applied. The study presents potential annual cost savings of $420 per home with storage capacities of 24?kWh. 相似文献
Two green nanocomposites of Co3O4 decorated CTAB/bentonite (Co@CT/BE) and chitosan/bentonite (Co@CH/BE) were synthesized as enhanced and environmental photocatalysts and antibacterial agents. As photocatalysts, the products were applied in the effective oxidation of toxic methyl parathion pesticide (MP) in wastewater under a visible light source. The application of Co@CH/BE (0.02 g) resulted in the complete oxidation of MP (50 mg/L) after 40 min and complete mineralization after 60 min. while the complete oxidation and mineralization of MP (50 mg/L) by Co@CT/BE was recognized after 75 min and 100 min, respectively. The Co@CH/BE composite is of higher activity than Co@CT/BE and can cause complete oxidation for MP at high concentrations up to 100 mg/L after 75 min. The oxidation pathway was illustrated considering the existence of the hydroxyl radicals as the active oxidizing species and the identified secondary organic compounds during the oxidation tests. The detected intermediate converted into end products of CO2 and inorganic anions of SO4?2, NO3?, and PO4?3 at the final stages of the oxidation processes. As antibacterial agents, the two composites exhibit considerable inhabitation zones of about 20 mm against both the Gram-positive Staphylococcus aureus and Gram-negative bacterium Vibrio Sp. The synthetic Co@CH/BE showed the best antibacterial properties with 200 μg/mL as minimum inhibitory against Staphylococcus aureus.
Metallurgical and Materials Transactions A - Gas atomization is the most used powder production technique since it provides good control on particles shape, surface oxidation and dimension. It is a... 相似文献