Influence of surface modification on the apatite formation and corrosion behavior of Ti and Ti-15Mo alloy for biomedical applications

Commercially pure Ti and Ti-15Mo specimens were subjected to alkali-hydrogen peroxide and subsequent heat treatment to produce a nanoporous titanate gel layer with anatase phase. The surface morphology of the untreated, alkali-hydrogen peroxide treated and alkali-hydrogen peroxide heat treated specimens before and after 7 days of immersion in simulated body fluid was characterized using X-ray Diffractometer (XRD), Atomic Force Microscopy (AFM), Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FT-IR). The formation of nanoporous titanate gel layer and the growth of apatite layer over the surface modified specimens after 7 days of immersion in simulated body fluid were confirmed. Further, the electrochemical corrosion behavior of all the specimens was examined using potentiodynamic polarization and electrochemical impedance spectroscopic techniques.     

Process Parameter Optimization in Jatropha Methyl Ester Yield Using Taguchi Technique

Among all alternate fuel sources available, the biodiesel of Jatropha curcas appears to be a potential fuel as it widely exists in Asia. The Jatropha methyl ester (JME) is produced by transesterification process. In the transesterification process, alkyl group of ester exchanges with that of an alcohol. This work focuses on optimizing various parameters like quantities of methanol, KOH, and stirrer speed, which influence high JME yield. Based on L₉ orthogonal array, experiments are conducted by using Taguchi technique. All the nine combinations of L₉ orthogonal array are experimentally done for extraction of JME, and then it is used for analysis in Taguchi technique. The analysis of maximum yield is done on the basis of “larger is better” signal to noise ratio (S/N ratio). The best combination in the L₉ orthogonal array is found to be methanol (110 ml), KOH (1.306 gm), and stirrer speed (1200 rpm). The influence of methanol, KOH, and stirrer speed on the yield is found by analysis of variance (ANOVA). Based on the results of ANOVA, it is found that the influence of methanol, KOH, and stirrer speed on the yield are obtained as 70.10%, 20.35%, and 5.78%, respectively.     

In vitro corrosion behaviour of plasma nitrided Ti–6Al–7Nb orthopaedic alloy in Hanks solution

Titanium alloy (Ti–6Al–7Nb) used for orthopaedic applications was nitrided using a conventional dc plasmatechnique. Load-dependent microhardness measurements exhibit a hardness of 2087 H_v at 25 g load for the alloy nitrided at 900 8C for 8 h. Cyclic polarization measurement in Hanks solution show maximum corrosion rate and minimum areaof repassivation for the alloy nitrided for 8 h at 900 8C. Electrochemical impedance measurements show an increase in charge transfer resistance and decrease in double layer capacitance when compared to untreated alloy.     

Dispatching rules for scheduling in assembly jobshops - Part 1

Research on jobshop scheduling has tended to concentrate on the development of dispatching rules for jobs that are independent, i.e. single-component jobs. However, in real-life situations, many jobs involve assembly operations that require scheduling of multiple components through the jobshop where both serial and parallel operations take place. In this two-part paper, we consider the problem of scheduling in assembly jobshops, i.e. jobshops that manufacture multi-level assembly jobs. The development of new and efficient dispatching rules with a view to address various measures of performance related to flowtime and staging delay of jobs is first undertaken. A new concept, called 'operation synchronization date' is introduced and made use of in the new dispatching rules. The best existing dispatching rules and the proposed dispatching rules are relatively evaluated by an exhaustive simulation study. The results indicate that the proposed rules emerge to be superior to the existing ones for most measures of performance.     

Molecular dynamics study of anisotropic shock responses in oriented α-quartz single crystal

Journal of Materials Science - This paper presents an investigation aimed at understanding the shock wave propagation response of oriented α-quartz single crystals by using molecular dynamics...     

A partition of unity‐based ‘FE–Meshfree’ QUAD4 element for geometric non‐linear analysis

The recently published ‘FE–Meshfree’ QUAD4 element is extended to geometrical non‐linear analysis. The shape functions for this element are obtained by combining meshfree and finite element shape functions. The concept of partition of unity (PU) is employed for the purpose. The new shape functions inherit their higher order completeness properties from the meshfree shape functions and the mesh‐distortion tolerant compatibility properties from the finite element (FE) shape functions. Updated Lagrangian formulation is adopted for the non‐linear solution. Several numerical example problems are solved and the performance of the element is compared with that of the well‐known Q4, QM6 and Q8 elements. The results show that, for regular meshes, the performance of the element is comparable to that of QM6 and Q8 elements, and superior to that of Q4 element. For distorted meshes, the present element has better mesh‐distortion tolerance than Q4, QM6 and Q8 elements. Copyright © 2009 John Wiley & Sons, Ltd.     

Effect of ZrO2 on conductivity of PVC-PMMA-LiBF4-DBP polymer electrolytes

The preparation and characterization of composite polymer electrolytes of PVC-PMMA-LiBF₄-DBP for different concentrations of ZrO₂ have been investigated. FTIR studies indicate complex formation between the polymers, salt and plasticizer. The electrical conductivity values measured by a.c. impedance spectroscopy is found to depend upon the ZrO₂ concentration. The temperature dependence of the conductivity of the polymer films seems to obey the VTF relation. The conductivity values are presented and results discussed.     

Influence of different conducting substrates on magnetic properties of electrodeposited Ni–Fe thin films

Electrodeposition of Ni–Fe soft magnetic alloy on copper and stainless steel substrates was performed in chloride bath. The deposition parameters such as current density, pH, temperature and deposition time have been investigated. From the investigation the optimized deposition parameters were current density 3.5 mA/cm², pH 3, temperature 30 °C and deposition time 15 min. The Ni–Fe magnetic alloys deposited on copper and stainless steel substrates under optimized deposition parameters are subjected to various characterizations. The structural and surface morphology of the Ni–Fe films were detected by using X-ray diffractogram (XRD) and scanning electron microscope (SEM) respectively. The constituents in the films were determined by energy dispersive X-ray spectroscopy (EDAX) technique. The magnetic properties such as the coercivity (H_c) and saturation magnetization of the films were studied with the help of vibrating sample magnetometer (VSM). From the magnetic studies it is concluded that the grain size are create a considerable impact on magnetic behavior of the films on both the substrates. The films prepared on stainless steel substrate of 0.1 M concentration at optimized deposition parameters exhibits higher coercivity (5010 Oe) which seems to be ideal for magnetic sensor applications.     

Foley catheters functionalised with a synergistic combination of antibiotics and silver nanoparticles resist biofilm formation

Foley catheters are inevitable in health care unit. Pathogens colonise and form biofilm on catheter causing catheter‐associated urinary tract infection. Therefore, the authors aimed to functionalise catheter to resist biofilm formation. The authors impregnated urinary catheters with a synergistic combination of antibiotics and silver nanoparticles (SNPs) to evaluate antibiofilm efficacy in vitro and in vivo. SNPs were synthesised using Spirulina platensis. Synergy between the SNPs and antibiotics was determined by the checker‐board method. In vivo efficacy of the functionalised catheters was assessed in mice. Liver and kidney function tests of mice were performed. The in vitro anti‐adherence activity of the functionalised catheters was evaluated after 2 years. Nanoparticle sizes were 42–75 nm. Synergistic activity was observed among SNPs (2 µg/ml), amikacin (6.25 µg/ml), and nitrofurantoin (31.25 µg/ml). In mice, catheters functionalised with combinations of antibiotics and SNPs exhibited no colonisation until Day 14. Blood, liver, and kidney tests were normal. After 2 years, catheters functionalised with antibiotics exhibited 25% inhibition of bacterial adhesion, and catheters functionalised with the nanoparticle‐antibiotic combination exhibited 90% inhibition. Impregnation of urinary catheters with a synergistic combination of antibiotics and SNPs is an efficient and promising method for preventing biofilm formation.Inspec keywords: catheters, drugs, silver, nanoparticles, nanomedicine, liver, kidney, blood, microorganisms, adhesion, biomechanics, cellular biophysicsOther keywords: Foley catheters, synergistic nanoparticle‐antibiotics combination, silver nanoparticles, biofilm formation resitance, health care unit, pathogens, urinary tract infection, SNP, Spirulina platensis, checker‐board method, liver function, kidney function, vitro antiadherence activity, amikacin, nitrofurantoin, blood, bacterial adhesion, size 42 nm to 75 nm, Ag     

Valence Charge Fluctuations and Tc Retention in Tl1−xPbxSr1+xLa1−xCuO5−y (0.0 ≤ x ≤0.5) System

Structural and x-ray photoelectron spectroscopy (XPS) studies of the Tl_1?xPb_xSr_1+xLa_1?xCuO_5?y (0.0≤x≤0.5) system have been carried out. The unit cell parameters increase with x. Irrespective of x the T_c is retained in this series and the optimum hole concentration (n_h) is maintained for x≤ 0.5. An increase in Tl 4f and O ls binding energy with x suggests a reduction in their oxidation state. Origin of holes is discussed in terms of charge transfer between Tl, Pb and CuO₂ layers.