Characterization of friction stir welded joint of low nickel austenitic stainless steel and modified ferritic stainless steel

Friction stir welding (FSW) of dissimilar stainless steels, low nickel austenitic stainless steel and 409M ferritic stainless steel, is experimentally investigated. Process responses during FSW and the microstructures of the resultant dissimilar joints are evaluated. Material flow in the stir zone is investigated in detail by elemental mapping. Elemental mapping of the dissimilar joints clearly indicates that the material flow pattern during FSW depends on the process parameter combination. Dynamic recrystallization and recovery are also observed in the dissimilar joints. Among the two different stainless steels selected in the present study, the ferritic stainless steels shows more severe dynamic recrystallization, resulting in a very fine microstructure, probably due to the higher stacking fault energy.     

Microstructure characterization and charpy toughness of P91 weldment for as-welded,post-weld heat treatment and normalizing & tempering heat treatment

The effect of weld groove design and heat treatment on microstructure evolution and Charpy toughness of P91 pipe weldments was studied. The P91 pipe weldments were subjected to subcritical post weld heat treatment (760 °C-2 h) and normalizing/tempering conditions (normalized-1040 °C/40 min, air cooled; tempered 760 °C/2 h, air cooled) were employed. The influence of subsequent PWHT and N&T treatment on the microstructure of various zone of P91 pipe weldments were also investigated. The present investigation also described the effect of PWHT and N&T treatment on hardness, grain size, precipitate size, inter-particle spacing and fraction area of precipitates present in each zone of P91 pipe weldments. The result indicated great impact of heat treatment on the Charpy toughness and microstructure evolution of P91 weldments. The N&T treatment was found to be more effective heat treatment compared to subsequent PWHT. Charpy toughness value was found to be higher for narrow-groove design as compared to conventional V-groove design.     

Effect of microstructure and chemical composition of hardfacing alloy on abrasive wear behavior

Hardfacing, a surface modification technique, is used to rebuild the surface of a workpiece. The economic success of the process depends on selective application of hardfacing material and its chemical composition for a particular application. In this context, three hardfacing electrodes having different chemical compositions have been selected and their abrasive wear responses was compared with that of mild steel. The emphasis has been made to realize the effect of microstructure and chemical composition on the wear response of the hardfacing material with respect to mild steel. It has been observed that the wear rate of hardfacing alloys is lower than that of mild steel. The hardfacing alloy having the highest chromium content exhibits the lowest wear rate.     

Ultrasonic evaluation of double poured rolls

Ultrasonic evaluation of the bonding characteristics in an infinitely chilled double poured rolls is carried out. During manufacturing process there are defects in the form of small holes or inclusions in these rolls. These defects act as points of stress in addition to the service stresses. By grinding, stress redistribution occurs. The shell–core interface is vulnerable to such stresses. Ultrasonic testing can be used to establish the critical points of these stress and hence predict their failure.     

Synthesis and characterization of phi-type zeolites LZ-276 and LZ-277: faulted members of the ABC-D6R family of zeolites

A new zeolite, LZ-276, was synthesized in an organic (TEAOH) system by varying the crystallization temperature in the procedure used by Jacobs and Martens for the synthesis of zeolite phi. LZ-276 (with SiO₂/Al₂O₃=7.8) is more siliceous than phi. Another silicon-rich zeolite, LZ-277 (SiO₂/Al₂O₃=6.6), was synthesized in a totally inorganic system. The similar chemical and physical properties of LZ-276 and LZ-277 are compared with those of zeolite phi described by Grose and Flanigen, and others. TEM [100] selected area diffraction patterns of LZ-277 can be indexed on a hexagonal unit cell with a=13.8 and c=15 Å. Twin spots and considerable streaking parallel to {00l} indicate mirror faulting along c. High resolution images on selected crystals of LZ-277 show that the most closely spaced mirror faults occur approximately every 18 Å. The bulk X-ray sample of LZ-276 is less faulted. A close match between the experimental synchrotron X-ray powder diffraction pattern of LZ-276 and one simulated by the DIFFaX program (with faulting probability=10%) indicates that the structures of these materials can be described as a chabazite (CHA) topology with faulting along c, the stacking direction in these ABC double six-ring (D6R) materials. The distribution of interior cages, including new larger cages that result from faulting, is presented.     

Apolipoprotein B mRNA editing and apolipoprotein gene expression in the liver of hyperinsulinemic fatty zucker rats: Relationship to very low density lipoprotein composition

We previously demonstrated increased apolipoprotein B (apoB) mRNA editing, elevated levels of mRNA for the catalytic component of the apoB mRNA editing complex, apobec-1, and increased secretion of the product of the edited mRNA, apoB48, in very low density lipoproteins (VLDL) in primary cultures of Sprague-Dawley rat hepatocytes following insulin treatment. In order to determine the effect of in vivo hyperinsulinemia on these processes, we determined apoB mRNA editing, apobec-1 expression, hepatic expression of mRNA for apoB and other VLDL apoproteins, and the quantity and composition of plasma VLDL in the hyperinsulinemic fatty Zucker rat. Total apoB mRNA content of the livers of the fatty rats and lean littermates did not differ, however, edited apoB message coding for hepatic apo B48, and abundance of mRNA for the catalytic subunit of the apoB mRNA editing complex, apobec-1, was increased by 1.7-and 3.3-fold, respectively, in fatty rats. ApoCIII mRNA abundance was increased in livers of fatty rats as well, but the abundance of hepatic apoE mRNA in the fatty animal was not different from that of the lean rat. Hepatic apoAI mRNA abundance was also increased in the fatty rats. Associated with increased apoB mRNA editing, was the 1.7-fold increase in the fraction of apoB in plasma as apoB48 in fatty rats. VLDL-triglyceride and-apoB in plasma were 15-and 3-fold higher, respectively, in fatty Zucker rats compared to lean littermates, indicating both enrichment of VLDL with triglycerides and increased accumulation of VLDL particles. Increased hepatic expression of mRNA for apoCIII and apoAI was associated with increased content of apoC (and relative depletion of apoE) in VLDL of fatty rats, and plasma apoAI was increased in fatty Zucker rats, primarily in the HDL fraction. The current study provides further evidence that chronic exposure to high levels of insulin influences both the quantity of and lipid/apoprotein composition of VLDL in plasma. The increased apoC and decreased apoE (as well as increased triglyceride) content of VLDL in the fatty Zucker rat observed in the current study may affect VLDL clearance and therefore may be a factor in the observed accumulation of VLDL in the plasma of the fatty hyperinsulinemic Zucker rats.     

Effect of Cooling Rate on Microstructure and Mechanical Properties of Eutectoid Steel Under Cyclic Heat Treatment

A systematic study has been carried out to ascertain the effect of cooling rate on structure and mechanical properties of eutectoid steel subjected to a novel incomplete austenitization-based cyclic heat treatment process up to 4 cycles. Each cycle consists of a short-duration holding (6 min) at 775 °C (above A₁) followed by cooling at different rates (furnace cooling, forced air cooling and ice-brine quenching). Microstructure and properties are found to be strongly dependent on cooling rate. In pearlitic transformation regime, lamellar disintegration completes in 61 h and 48 min for cyclic furnace cooling. This leads to a spheroidized structure possessing a lower hardness and strength than that obtained in as-received annealed condition. On contrary, lamellar disintegration does not occur for cyclic forced air cooling with high air flow rate (78 m³ h^?1). Rather, a novel microstructure consisting of submicroscopic cementite particles in a ‘interweaved pearlite’ matrix is developed after 4 cycles. This provides an enhancement in hardness (395 HV), yield strength (473 MPa) and UTS (830 MPa) along with retention of a reasonable ductility (%Elongation = 19) as compared to as-received annealed condition (hardness = 222 HV, YS = 358 MPa, UTS = 740 MPa, %Elongation = 21).     

Mechanical Anisotropy and Pressure Induced Structural Changes in Piroxicam Crystals Probed by In Situ Indentation and Raman Spectroscopy

The ability to correlate mechanical and chemical characterization techniques in real time is both lacking and powerful tool for gaining insights into material behavior. This is demonstrated through use of a novel nanoindentation device equipped with Raman spectroscopy to explore the deformation-induced structural changes in piroxicam crystals. Mechanical anisotropy was observed in two major faces (\( 0\bar{1}1 \)) and (011), which are correlated to changes in the interlayer interaction from in situ Raman spectra recorded during indentation. The results of this study demonstrate the considerable potential of an in situ Raman nanoindentation instrument for studying a variety of topics, including stress-induced phase transformation mechanisms, mechanochemistry, and solid state reactivity under mechanical forces that occur in molecular and pharmaceutical solids.     

Corrosion behaviour and characterisation of Ni–Nb<Subscript>2</Subscript>O<Subscript>5</Subscript> composites prepared by pulse electrodeposition

The Ni–Nb₂O₅ composites were prepared by pulse electrodeposition method. Operating variables were optimized for getting a good deposit. The quantity of Nb₂O₅ particles in the coating was analyzed by an energy-dispersive X-ray diffraction spectrometer. X-ray diffraction and scanning electron microscopy were used to analyze the structure and surface morphology of the coatings. Texture coefficient and hardness of the deposits were determined and discussed. The corrosion behavior of the coatings was analyzed by traditional weight loss and electrochemical methods. Comparisons of the corrosion behaviour of coatings obtained by direct current (DC) and pulse current (PC) were investigated.