Universal instability modes in internal and external flows

Two prototypical external and internal flows have been studied which display linear temporal instability followed by nonlinear saturation taking the flows to a new equilibrium state. Direct simulation results are obtained using a specific formulation and numerical methods with very high accuracy. These results are analyzed via proper orthogonal decomposition (POD), which reveal similar modes for flow past a circular cylinder and flow inside a lid-driven cavity, indicating universality of such modes. Unlike many other efforts on reduced order modeling via POD, here the emphasis has been on understanding the physical aspect of the flow instability which requires very high accuracy of the simulation. Then, the obtained POD modes are related to the instability modes (in the classical sense of defining the latter) and new generic types of instability modes are identified in the studied external and internal flows. These new modes have been reported for flow past a circular cylinder [Sengupta TK, Singh N, Suman VK. Dynamical system approach to instability of flow past a circular cylinder. J Fluid Mech 2010;656:82–115] which help one in understanding the instability sequence and the relative importance of these modes in the flow evolution starting from an impulsive start. Present comparative study, furthermore, reveals universality of such instability modes by showing their presence for the flow inside a lid-driven cavity as well. Despite seeming dissimilarities between these two flows, similarities between the instability portrait of these two flows suggest universality of such modes. From the equilibrium amplitude of vorticity time-series, we establish the presence of multiple modes and multiple bifurcation sequences for these flows in parameter space. Existing theory due to Landau and Stuart that considers only a single dominant mode and its self-interaction does not explain all these features. We invoke a multi-modal interaction model in the cited reference above, termed as Landau–Stuart–Eckhaus (LSE) equation in recognition of Eckhaus’ work in modifying the classical Stuart–Landau equation. We also show that the new instability modes do not follow either the classical Stuart–Landau or the newly proposed LSE model equations and for this reason we call these as anomalous modes. Two specific classes of anomalous modes are identified and classified in the present work. Empirical expressions for the evolution of these anomalous modes are presented and their unambiguous role during instabilities is discussed.     

Triglyceride composition of chrysalis oil,an insect lipid

Chrysalis oil, an insect fat obtained from the spent silk worm pupae, Bombyx mori, is a by-product of sericultural industry and represents a potential source of 1750 tons of linolenic-rich oil per annum for India. Fatty acid and triglyceride compositions of chrysalis oil have been determined by the combination of the techniques of lower temperature segregation, lipolysis, thin layer and gas liquid chromatography. Percentage contents of the component acids are: C_14:0, 0.6; C_16:0, 19.3; C_18:0 3.9; C_18:1, 17.7; C_18:2, 9.8, and C_18:3, 48.7. Major component triglycerides are, LLnLn, 5.2%; PLnO, 6.4%;OLnLn, 9.6%; LnLnLn, 10.5% and PLnLn, 14.0% (P, palmitic; O, oleic; L, linoleic and Ln, linolenic acids. On low temperature crystallization, Chrysalis oil yielded two fractions amounting together to 40% of the total with composition quite similar to that of linseed oil.     

Polyaniline as a Gas-Sensor Material

Polyaniline (PANI) was synthesized by oxidative polymerization of aniline using ammonium persulfate in an acid medium. The polyaniline salt was converted to base form by treatment with ammonium hydroxide. The polyaniline base was dissolved in N-methyl pyrrolidone (NMP) for film casting. The cast film was doped with HCl for obtaining higher conductivity. Both doped and undoped PANI films were characterized by UV-visible, FTIR, and XRD analyses. The electrical conductivity of the PANI film was studied by a four-point probe method at room temperature. Finally, ammonia gas-sensing characteristics of the prepared polyaniline film were studied by measuring the change in electrical conductivity on exposure to ammonia gas at different concentrations. The influence of concentration of acid during polymerization of aniline and dopant concentration on the gas sensing characteristics of PANI film are reported in this paper.     

Copper extraction into emulsion liquid membranes using LIX 984N-C®

The extraction of copper from aqueous sulfate media into ELMs using the extractant LIX 984N-C was studied. Appropriately characterized emulsions on the basis of viscosity and internal drop sizes were used to study the effect of different parameters on extraction. The effects of stirring speed, surfactant concentration, pH of the external continuous phase, carrier concentration, internal phase stripping acid concentration and initial copper concentration are reported. These results show that LIX 984N-C efficiently extracts copper at low pH values typical of leach solutions. It was found that LIX 984N-C could extract up to 80% copper from aqueous solutions at pH value of 1. Performance of LIX 984N-C was also compared with LIX 84 and LIX 84-I at different pH values. Results indicate that LIX 984N-C could open up new avenues for extraction of copper into ELMs, not only from dilute solutions, but also from sulfuric acid leach solutions.     

e-Commerce security — A life cycle approach

The rapid evolution of computing and communication technologies and their standardizations have made the boom in e-commerce possible. Lowering of the cost of operation, increase in the speed of transactions, and easy global reach to customers and vendors have been the reasons for the overwhelming popularity of this new way of commerce. This article examines the issues related to the security of the assets and transactions in the e-commerce components and activities. Since large public money is involved in the transactions, the role of information security and privacy is not exaggerated in this kind of business. After examining the technologies used in e-commerce, the article goes on to identify the security requirement of e-commerce systems from perceived threats and vulnerabilities. Then e-commerce security is viewed as an engineering management problem and a life cycle approach is put forward. How the e-commerce systems can be made secure using the life cycle approach is outlined. The relevant standards and laws are also discussed in the perspective of e-commerce. The article closes with some future research directions and conclusions.     

Electric and dielectric study of cobalt substituted MgMn nanoferrites synthesized by solution combustion technique

Cobalt substituted Mg–Mn nanoferrites with formulae Mg_0.9Mn_0.1Co_xFe_2?xO₄, x=0.0, 0.1, 0.2 and 0.3, have been synthesized for the first time by the solution combustion technique. The effects of Co²⁺ ions on the dc resistivity, dielectric constant and dielectric loss tangent of Mg–Mn nanoferrites at room temperature are presented in this paper. X-ray diffraction confirmed the formation of a single phase spinel structure. Particle size was found to increase, 20.9–23.9 nm, with increasing Co²⁺ concentration. The dc resistivity was increased by two order of magnitude with substitution of Co²⁺ ions while the dielectric constant was found to be decreasing with the increasing concentration of cobalt ions. The value of dc resistivity obtained for Mg_0.9Mn_0.1Fe₂O₄ nanoferrite in our work is greater than the value obtained for the same composition prepared by the conventional ceramic technique. Further, the dielectric constant and dielectric loss tangent were observed to be decreasing with the increase in frequency.     

Investigation of Eccentric Open Eye Formation in a Slab Caster Tundish

Metallurgical and Materials Transactions B - Inert gas shrouding in tundish can result in the formation of a tundish open eye (TOE) due to the presence of reversed flows on the upper surface of the...     

Efficacy of organophosphorus derivatives containing chalcones/chalcone semicarbazones against fungal pathogens of sugarcane

Ten newly synthesized organophosphorus derivatives containing substituted chalcones and substituted chalcone semicarbazones were tested for their antifungal efficacy against Colletotrichum falcatum, Fusarium oxysporum, Curvularia pallescens (all sugarcane pathogens). The O,O-diethylphosphate derivatives containing 2-chlorochalcone and 2-chlorochalcone semicarbazone exhibited 70-85% mycelial inhibition against all the test fungi at 1000 ppm. The screening results were correlated with structural features of the tested compounds.