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101.
Akzo Nobel Chemicals has recently introduced on the market an aromatic oligomeric phosphate (BDP) based on Bisphenol A. This product shows higher thermal and hydrolytic stability than other aryl phosphates. It provides similar or better fire retardant performance than an oligomeric phosphate (RDP) based on resorcinol. Fire retardant formulations with BDP based on polycarbonate/ABS plastic (PC/ABS) blend, polyphenylene oxide/high impact polystyrene (PPO/HIPS) blend, and HIPS alone show similar or better physical properties than those obtained with RDP. Upon thermal decomposition of the fire retarded polymers containing BDP, phosphorus tends to accumulate in the solid residue, a result which indicates that the primary fire retardant action of BDP is likely to occur in the condensed phase. 相似文献
102.
New efficient intermetallide catalysts for hydrogen storage in reversible processes of aromatics hydrogenation and naphthene dehydrogenation were studied. These catalysts provide an enhanced activity in the dehydrogenation of saturated organic molecules, with no side reactions like cracking, hydrogenolysis, ring opening, or coke formation occurring on these catalysts. The use of intermetallides provides some hydrogen storage capacity in the low-temperature region, while their catalytic activity in the dehydrogenation affords the hydrogen supply in the high-temperature range. 相似文献
103.
A new method and instrumentation are described for rapid compositional analysis of single-walled carbon nanotube (SWCNT) samples. The customized optical system uses multiple fixed-wavelength lasers to excite NIR fluorescence from SWCNTs individualized in aqueous suspensions. The emission spectra are efficiently captured by a NIR spectrometer with InGaAs multichannel detector and then analyzed by a computer program that consults a database of SWCNT spectral parameters. The identities and relative abundances of semiconducting SWCNTs species are quickly deduced and displayed in graphs and tables. Results are found to be consistent with those based on manual interpretation of full excitation-emission scans from a conventional spectrofluorometer. The new instrument also measures absorption spectra using a broadband lamp and multichannel spectrometers, allowing samples to be automatically characterized by their emission efficiencies. The system provides rapid data acquisition and is sensitive enough to detect the fluorescence of a few picograms of SWCNTs in ~50 μL sample volumes. 相似文献
104.
Sergei V. Kalinin Brian J. Rodriguez Albina Y. Borisevich Arthur P. Baddorf Nina Balke Hye Jung Chang Long‐Qing Chen Samrat Choudhury Stephen Jesse Peter Maksymovych Maxim P. Nikiforov Stephen J. Pennycook 《Advanced materials (Deerfield Beach, Fla.)》2010,22(3):314-322
The plethora of lattice and electronic behaviors in ferroelectric and multiferroic materials and heterostructures opens vistas into novel physical phenomena including magnetoelectric coupling and ferroelectric tunneling. The development of new classes of electronic, energy‐storage, and information‐technology devices depends critically on understanding and controlling field‐induced polarization switching. Polarization reversal is controlled by defects that determine activation energy, critical switching bias, and the selection between thermodynamically equivalent polarization states in multiaxial ferroelectrics. Understanding and controlling defect functionality in ferroelectric materials is as critical to the future of oxide electronics and solid‐state electrochemistry as defects in semiconductors are for semiconductor electronics. Here, recent advances in understanding the defect‐mediated switching mechanisms, enabled by recent advances in electron and scanning probe microscopy, are discussed. The synergy between local probes and structural methods offers a pathway to decipher deterministic polarization switching mechanisms on the level of a single atomically defined defect. 相似文献
105.
Dongxiang Zhang Hang Xu Min Xue Wenguo Xu V. Tarasov 《Frontiers of Chemical Engineering in China》2008,2(3):319-324
Ultra-fine zinc oxalate powders were prepared through a precipitation stripping method with bis(2-ethylhexyl) phosphate (HDEHP)
diluted by tetrachloride carbon as the extractant, and oxalic acid ethanol aqueous solution as the re-extractant and precipitator.
Zinc oxide powders were obtained by decomposing zinc oxalate powders at 450uC. The prepared zinc oxide powders were characterized
by transmission electron microscope (TEM), Scanning electron microscope (SEM), Thermogravimetric analysis (TG), X-ray diffraction
(XRD) and Fourier transmission infrared (FT-IR) spectrum. The photocatalytic performance of methylene blue by zinc oxide was
studied based on the Langmuir model and Photo-Layer model. The results show that some zinc oxide powders were micro-multipore
materials with hexagonal crystal. The particle size was around 32 nm. The photocatalytic process was the control step in the
chemical reaction. The photo catalytic process followed pseudo-first order kinetics and •OH concentration inside the photo-layer
in different reaction condition were calculated according to the Photo-Layer model.
__________
Translated from Transactions of Beijing Institute of Technology, 2007, 27(7): 641–645 [译自: 北京理工大学学报] 相似文献
106.
A. V. Grigorieva A. B. Tarasov E. A. Goodilin V. V. Volkov Yu. D. Tretyakov 《Glass Physics and Chemistry》2007,33(3):232-236
Vanadium oxide nanotubes are synthesized by the hydrothermal method with the use of polycrystalline vanadium oxide V2O5 and 1-hexadecylamine as a structural template. The structure of the vanadium oxide nanotubes is investigated using small-angle X-ray diffraction and transmission electron microscopy. It is demonstrated that the structure of the vanadium oxide nanotubes is characterized by a combination of fragments with different interlayer distances associated with the twisting of oxide layers in the form of “nanorolls.” The thermal stability, morphology, and surface properties of the nanotubes, as well as the role of the organic template in the formation of their structure, are discussed. 相似文献
107.
This review provides an insight into new developments in flame retardancy of the broad class of styrenic polymers but mostly focuses on commercially important styrene thermoplastics, on some blends based on polystyrene as well as on polystyrene foams. Although halogen‐based systems continue to dominate in flame retardancy of styrenic polymers, various alternative systems are being developed. Especially, activity is observed with phosphorus‐based flame retardants, where some systems are already commercially available. There is also significant activity with nanocomposites, where good results in retarding flame spread have been achieved, but the problem of ignition resistance has not been solved yet. Critical discussion of various flame‐retardant systems developed for styrenics is given. Copyright © 2007 Society of Chemical Industry 相似文献
108.
Evgueni Jak Peter C. Hayes Sergei Degterov Arthur D. Peiton 《Metallurgical and Materials Transactions B》2001,32(5):793-800
Experimental and thermodynamic modeling studies have been carried out on the Zn-Fe-Si-O system. This research is part of a
wider program to characterize zinc/lead industrial slags and sinters in the PbO-ZnO-SiO2-CaO-FeO-Fe2O3 system. Experimental investigations involve high-temperature equilibration and quenching techniques followed by electron
probe X-ray microanalysis (EPMA). Liquidus temperatures and solid solubilities of the crystalline phases were measured in
the temperature range from 1200 °C to 1450 °C (1473 to 1723 K) in the zinc ferrite, zincite, willemite, and tridymite primary-phase
fields in the Zn-Fe-Si-O system in air. These equilibrium data for the Zn-Fe-Si-O system in air, combined with previously
reported data for this system, were used to obtain an optimized self-consistent set of parameters of thermodynamic models
for all phases. 相似文献
109.
Denis V. Anokhin Yuli K. Godovsky Sergei N. Magonov Natalia N. Makarova Wim Bras 《Polymer》2007,48(16):4837-4848
The structure and phase transitions of cyclolinear polyorganosiloxane copolymer containing 12-member polysiloxane rings have been studied using synchrotron WAXS, DSC, TEM, variable-temperature AFM and polarized optical microscopy. The primary structure of this polymer can be viewed as a necklace of disk-shaped entities (cyclic groups) connected via flexible linkers.In the mesomorphic state, the presence of two different LC phases has been derived from the analysis of WAXS fiber diffractograms. The morphology of one of the phases shows a conventional hexagonal packing of LC chains where the chain axes are perpendicular to the plane of the 2D hexagonal lattice. The other one, so-called R-phase, has a vertically oriented rectangular 2D lattice formed by inter-chain correlations between the bulky polysiloxane cycles (disks). To our knowledge, such a disk-necklace mesophase in which the LC lattice is parallel to the backbone direction has not been reported in the literature so far. 相似文献
110.
The structure and function of the target-language generation module for KBMT-89 is described. The lexical selection module (which includes thematic-role subcategorization, a meaning distance metric, and syntactic subcategorization) is presented. We also describe the generation mapping rules, and rule interpretation in the generation of f-structures for target language utterances. 相似文献