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91.
Lee Seung Eun Kim Ji Hong Lee Young-Seak Im Ji Sun 《Journal of Applied Electrochemistry》2021,51(10):1407-1418
Journal of Applied Electrochemistry - In this study, Needle and Regular coke, which has different crystalline and orientation characteristics, were graphitized, and the effect of crystal changes on... 相似文献
92.
Seong-Joong Kim Yeojin Ahn Jeong F. Kim Seung-Eun Nam Hosik Park Young Hoon Cho Kyung-youl Baek You-In Park 《应用聚合物科学杂志》2021,138(7):49860
To overcome the plasticization effect in polyimide membranes, many researchers have proposed crosslinking method. This can reduce an inter-segmental mobility by tightening and rigidifying the polymer chains. However, it is difficult to modify the whole polymer chains throughout the membrane because the reaction can be hindered by the diffusion rate of the crosslinker. In particular, it is hard for bulky crosslinker to penetrate a dense membrane with a small d-spacing. This study investigated the effect of crosslinking a dense Matrimid membrane with p-phenylenediamine (p-PDA) via two different crosslinking methods (i.e., methanol-swelling crosslinking process [M-SCP] and liquid-phase crosslinking process [L-PCP]). Most of the crosslinking reaction in M-SCP occurs on the membrane surface due to difficulty in penetration of the bulky p-PDA into the Matrimid dense membrane. In contrast, the L-PCP allows uniform crosslinking across the membrane. The membranes crosslinked using L-PCP showed excellent chemical resistance. Furthermore, the plasticization phenomenon was not observed in the membranes crosslinked using L-PCP with p-PDA more than 15%. Meanwhile, the membrane crosslinked using M-SCP exhibited poor plasticization and chemical resistance properties. These results showed that the L-PCP method can be more effective for the crosslinking of dense membrane to deliver both high plasticization and chemical resistance. 相似文献
93.
Superplastic deformation and crystallization behavior of a Cu54Ni6Zr22Ti18 metallic glass were investigated. A maximum elongation of 650% was obtained at 733 K at 1 × 10−2 s−1 from the sheet fabricated by squeeze copper-mold casting method. At low strain rates, the strain-rate-sensitivity exponent value was close to 1, suggesting that Newtonian-like behavior governed the plastic flow. At a high strain rate around 10−2 s−1, a transition from Newtonian to non-Newtonian behavior took place with decrease in m value. Large strain hardening by crystallization occurred during the course of deformation. The strain hardening was found to be caused by crystallization according to the analyses of the relation of true stress vs. testing time, T-T-T diagram and DSC characteristics. The time periods up to the strain before strain hardening at 733 K for the Cu54Ni6Zr22Ti18 metallic glass were similar to that of the Zr65Al10Ni10Cu15 metallic glass at 696 K as 180–300 s (3–5 min). This coincidence could be explained by comparison of their T-T-T diagrams showing that the incubation times for crystallization of the Cu BMG at 733 K and for Zr BMG at 696 K are similar. 相似文献
94.
In the present study, the densification of Ti/TiB composites, the growth behavior ofin-situ formed TiB reinforcement, the effects of processing variables — such as reactant powder (TiB2, B4C), sintering temperature and time — on the microstructures and the mechanical properties ofin-situ processed Ti/TiB composites have been investigated. Mixtures of TiB2 or B4C powder with pure titanium powder were compacted and presintered at 700°C for 1 hr followed by sintering at 900, 1000, 1100,
1200, and 1300°C, respectively, for 3hrs. Some specimens were sintered at 1000°C for various times in order to study the formation
behavior of TiB reinforcementin-situ formed within the pure Ti matrix. TiB reinforcements were formed through different mechanisms, such as the formation of fine
TiB and the formation of coarse TiB by Ostwald ripening or the coalescence of fine TiB. There was no crystallographic relationship
between TiB reinforcement and the matrix. There were voids at the interface between the TiB reinforcement and the Ti matrix
due to the preferential growth of coarse TiB without a particular crystallographic relationship with pure Ti matrix and the
surface energy between the Ti matrix and TiB reinforcements. Therefore, the densification of Ti/TiB2 compacts was hindered by the preferential growth of coarse TiB reinforcements. The mechanical properties ofin-situ processed composites were evaluated by measuring the compressive yield strength at ambient and high temperatures. The compressive
yield strength of thein situ processed composites was higher than that of the Ti-6A1-4V alloy. It was also found that the compressive yield strength of
the composite made from TiB2 reactant powder was higher than that of the composite made from B4C at the same volume fraction of reinforcement. A crack path examination suggested that the bonding nature of interface between
matrix and reinforcement made from TiB2 reactant powder was better than that made from B4C. 相似文献
95.
Il Song Park Tae Gyu Woo Min Ho Lee Seung Geun Ahn Myung Sik Park Tae Sung Bae Kyeong Won Seol 《Metals and Materials International》2006,12(6):505-511
Anodic oxidation is the process of creating a titanium oxide layer with various defects more dense and stable. In this study,
a dense, stable and porous oxide layer was formed using anodic spark oxidation on pure titanium surface and hydroxyapatite
crystals were formed on its surface via a hydrothermal treatment. A mixture of 0.02M−GP (Glycerolphosphate disodium salt)
and 0.2M-CA (Calcium acetate) was used as an electrolyte. By increasing the anodizing voltage to 220, 260, 300, and 360 V,
the effects of the anodizing voltage were examined by evaluating the film properties after anodization and a hydrothermal
treatment. Breakdown occurred around 230 V. As the voltage increased after breakdown, the pore size increased. After the hydrothermal
treatment, the amount of HA crystal precipitation was also increased as the voltage increased. The mean surface roughness
(Ra) of the anodizing surface was also increased as the voltage increased. The Ra value was larger in the hydrothermally treated
group compared with the group treated with anodization as a result of the HA crystals present on the surface after the hydrothermal
treatment. Corrosion resistance of the surface modified by anodization was significantly increased in a saline solution compared
to that for the non-treated group; this increased further after the hydrothermal treatment. These increases were most likely
due to a thick stable oxide layer formed through anodization. Thus, it is believed that titanium with its surface modified
through anodic spark oxidation would be a suitable biomaterial due to its corrosion resistance and biocompatibility. 相似文献
96.
Sun-Chan Jeong Ichiro Katayama Hirokane Kawakami Yutaka Watanabe Hironobu Ishiyama Nobuaki Imai Yoshikazu Hirayama Hiroari Miyatake Masao Sataka Satoru Okayasu Hiroyuki Sugai Shin-Ichi Ichikawa Katsuhisa Nishio Shinichi Mitsuoka Takamitsu Nakanoya Masahito Yahagi Takanori Hashimoto Kazunori Takada Mamoru Watanabe Tomoko Ishikawa Akihiro Iwase 《Journal of Phase Equilibria and Diffusion》2005,26(5):472-476
For the effective use of short-lived radioactive beams, soon to be available at the Tokai Radioactive Ion Accelerator Complex, the authors have developed a radiotracer method for diffusion studies in solids. The experimental test was performed by the measurement of the diffusion coefficients of Li in a sample of the compound βLiAl using an α-emitting radiotracer of 8Li (T1/2=0.84 s). It was found that the time-dependent yields of the α particles from the diffusing 8Li that was initially implanted in the sample could be used as a measure of the diffusivity of the tracer in a nondestructive way. The method was applied to measure the self-diffusion coefficients of Li in βLiGa, and for investigating how the Li diffusion in the Li ionic conductors is affected by the concentration of atomic defects (i.e., the existence of the atomic vacancies of Li and the defects in Ga sites that are replaced by Li). 相似文献
97.
We study quantum teleportation between two different types of optical qubits using hybrid entanglement as a quantum channel under decoherence effects. One type of qubit employs the vacuum and single-photon states for the basis, called a single-rail single-photon qubit, and the other utilizes coherent states of opposite phases. We find that teleportation from a single-rail single-photon qubit to a coherent-state qubit is better than the opposite direction in terms of fidelity and success probability. We compare our results with those using a different type of hybrid entanglement between a polarized single-photon qubit and a coherent state. 相似文献
98.
We propose a control strategy that could steer the group of mobile agents in the plane to achieve a specified formation. The control law could be implemented in a fully decentralized manner so that each agent moves on their own local reference frame. Under the acyclic minimally persistent graph topology, each agent measures the relative displacements of neighboring agents and then adjusts the distances between them to achieve the desired formation. As well as achieving a fixed formation, we could resize the formation only by changing the leader edge, which connects the leader with the first‐follower in acyclic minimally persistent graph, without changing the structures of the control law. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
99.
Exploring the Relationship Between Green Consumption Value,Satisfaction, and Loyalty to Hybrid Car in Elderly Consumers 下载免费PDF全文
The study aimed to examine the relationship between green consumption value, satisfaction, and loyalty of driving hybrid cars among elderly consumers. Data were collected from a cross‐sectional survey of 314 elderly consumers who purchased hybrid cars in the United States. A partial least squares analysis revealed that elderly consumers’ social, price, and quality values positively influenced the satisfaction of their hybrid car experience, and their satisfaction significantly influenced their loyalty of hybrid car. The relationship between green consumption value, satisfaction, and loyalty toward driving hybrid cars among elderly consumers revealed insight into their value orientations toward the hybrid car. Special efforts are suggested in promoting hybrid car use to elderly consumer groups. Marketers should pay attention to changing beliefs and increasing perceived values of driving a hybrid car for consumers to encourage them to use green products. 相似文献
100.
Sam Dong Jung Jeong Soo Kim Jung Won Park Jong Hwa Won Moon Kyum Kim 《Multimedia Tools and Applications》2015,74(20):9017-9029
A technique is developed to clearly establish the shear resistance of a cellular structure, retaining wall composed of a steel frame and fill materials with both continuous and discontinuous characteristics. To overcome the limitation of the existing analysis approach based on continuum mechanics, in which the shear behavior and interaction between the frames and fill material of this type of structure are difficult to describe, this paper introduces displacement incremental analysis into the distinct element method. The results obtained by using the proposed approach are compared with experimental results to verify its accuracy. The results show an internal friction angle of fill materials and overburdening load are major factor determining the shear resistance of a retaining wall with a cellular structure type. From the results of the parametric study on the shear behavior of this type of structure, this paper also proposes a shear resistance moment-shear displacement formula for designing a retaining wall with a cellular structure type. 相似文献