全文获取类型
收费全文 | 2003篇 |
免费 | 205篇 |
国内免费 | 17篇 |
专业分类
电工技术 | 40篇 |
综合类 | 8篇 |
化学工业 | 603篇 |
金属工艺 | 67篇 |
机械仪表 | 109篇 |
建筑科学 | 85篇 |
矿业工程 | 6篇 |
能源动力 | 123篇 |
轻工业 | 276篇 |
水利工程 | 39篇 |
石油天然气 | 32篇 |
无线电 | 158篇 |
一般工业技术 | 337篇 |
冶金工业 | 44篇 |
原子能技术 | 15篇 |
自动化技术 | 283篇 |
出版年
2024年 | 10篇 |
2023年 | 40篇 |
2022年 | 69篇 |
2021年 | 160篇 |
2020年 | 139篇 |
2019年 | 169篇 |
2018年 | 191篇 |
2017年 | 179篇 |
2016年 | 187篇 |
2015年 | 105篇 |
2014年 | 166篇 |
2013年 | 235篇 |
2012年 | 156篇 |
2011年 | 133篇 |
2010年 | 98篇 |
2009年 | 71篇 |
2008年 | 36篇 |
2007年 | 17篇 |
2006年 | 15篇 |
2005年 | 10篇 |
2004年 | 11篇 |
2003年 | 5篇 |
2002年 | 5篇 |
2000年 | 2篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1989年 | 2篇 |
1980年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有2225条查询结果,搜索用时 15 毫秒
71.
Hassan Elmkhah Mohammad-Rashed Mohammadi Maryam Molaei Ashkan Zolriasatein Mostafa Meghdari Arash Fattah-alhosseini 《International Journal of Applied Ceramic Technology》2022,19(6):3072-3083
This study aims to investigate how the predeposition machining processes such as magnetic grinding, turning machining, and wire electrical discharge machining can influence the surface properties including electrochemical and tribological behavior of TiCrN nanostructured coating applied on Mo40 steel substrate. A physical vapor deposition technique using cathodic arc evaporation was used to apply the coating. The crystallographic phases and the microstructure of the coating were studied by X-ray diffraction and scanning electron microscope, respectively. Rockwell-C, electrochemical impedance spectroscopy and potentiodynamic polarization, and pin-on-disk wear tests were employed to evaluate the adhesion strength, corrosion behavior, and tribological property of specimens, respectively. The electrochemical results after 24 h of exposure to 3.5 wt% NaCl solution showed that TiCrN coating pretreated with a turning process with polarization resistance of about 3525.32 Ω.cm2 had the best corrosion resistance among all specimens. This was because of the improvement of the smoothness, surface quality, and adhesion after the turning process. On the other, the friction coefficient of the grounded sample is less than that of other ones. This is probably due to its higher adhesion strength and higher surface smoothness. 相似文献
72.
Synthesis of biocompatible and degradable microspheres based on 2‐hydroxyethyl methacrylate via microfluidic method 下载免费PDF全文
Mohammad Tarameshlou Seyed Hassan Jafari Iraj Rezaeian Hossein Ali Khonakdar 《应用聚合物科学杂志》2014,131(20)
Monodisperse poly(2‐hydroxyethyl methacrylate), p‐HEMA, microspheres in size ranging from 16 to 340 (μm) were synthesized by in situ emulsion photopolymerization of HEMA monomer with polyethylene glycol diacrylate (p‐EGDA) by means of a three‐dimensional microfluidic flow‐focusing device. An aqueous solution of HEMA, p‐EGDA as chain extender and UV‐photoinitiator serving as dispersed phase formed microdroplets in a continuous oil phase mainly consisting of n‐heptane. A downward coaxial orifices design in the device led to confinement of the reaction admixtures thread to central axis of the microchannels. This design strategy could solve the wetting problem of dispersed phase with the microchannels leading to a successful production of monodisperse microspheres with size variation of less than 4%. The effects of concentration of p‐EGDA, surfactant, and flow rate ratios on microsphere size were examined. It was observed that increasing the concentration of p‐EGDA slightly increases the size whereas increasing the flow rate ratios of continuous to dispersed phase effectively decreases the size of microspheres. The rapid continuous synthesis of p‐HEMA based microspheres via the microfluidic route with reliable control over size, size distribution, and composition opens new doors for mass production of biocompatible and degradable polymeric microspheres for enormous biotechnological applications. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40925. 相似文献
73.
Rheological,crystal structure,barrier, and mechanical properties of PA6 and MXD6 nanocomposite films
Maryam Fereydoon Seyed H. Tabatabaei Abdellah Ajji 《Polymer Engineering and Science》2014,54(11):2617-2631
In this study, rheological, crystal structure, barrier, and mechanical properties of polyamide 6 (PA6), poly(m‐xylene adipamide) (MXD6) and their in situ polymerized nanocomposites with 4 wt % clay were studied. The extent of intercalation and exfoliation as well as type of crystals, crystallinity, and thermal transitions were investigated using X‐ray diffraction (XRD) and differential scanning calorimetry (DSC), respectively. Dynamic rheological measurements revealed that incorporation of nanoclay significantly increases complex viscosity of MXD6 nanocomposites at low frequencies, which was related to the formation of a nanoclay network and exchange reaction between MXD6 chains. The comparative study of dynamic characteristics (G′ (ω) and G″ (ω)) for aliphatic and aromatic polyamide nanocomposites with their neat resins as well as the relaxation spectra for both polymer systems confirmed the possibility of the aforementioned phenomena. Although, the crystallinity of MXD6 films was lower as compared to PA6 films, the permeability to oxygen was more than 5 times better for the former. Incorporating 4 wt% clay enhanced the barrier property, tensile modulus, and yield stress of PA6 and MXD6 nanocomposite films in both machine and transverse directions without sacrificing much puncture and tear resistances. The PA6‐based films showed higher tear and puncture strength as compared to MXD6 films. POLYM. ENG. SCI., 54:2617–2631, 2014. © 2013 Society of Plastics Engineers 相似文献
74.
Mohsen Gholami Mohammad Reza Talaie Seyed Foad Aghamiri 《Korean Journal of Chemical Engineering》2014,31(2):322-326
A bi-modal porous structure MCM-41 (BPS-MCM-41) was synthesized and functionalized by 3-[2-(2-Aminoethylamino)ethylamino]propyltrimethoxysilane (TRI); also, its performance in amine grafting and CO2 capturing was compared with that of pore-expanded MCM-41 [1]. To create larger pores beside the mesoporous structure of MCM-41, carbon black nanoparticles were used as the solid template. Characterizing the BPS-MCM-41 using the BET and BJH techniques resulted in the surface reduction of 29.3 percent and volume increase of 68.46 percent. The pore size distribution showed two peaks: a narrow peak at 2.24 nm diameter, which belonged to micelles, and a wide one at about 50 nm due to the presence of used nanoparticles. The functionalization confirmed that BPS-MCM-41 is capable of accommodating a large quantity of amine groups. The CO2 adsorption measurement indicated that internal volume of the adsorbent was a critical factor affecting the adsorption capacity of the amine grafted adsorbents. 相似文献
75.
Seyed Hamidreza Yousefi Alireza Eslamian Fariborz Rashidi 《Korean Journal of Chemical Engineering》2014,31(1):20-28
Gas condensate reservoirs present complicated thermodynamic behavior when pressure falls below the dew point pressure, due to fluid dropout and change in the fluid composition. Condensate blockage in the near wellbore region reduces the well deliverability. Mixture composition change in the reservoir makes the interpretation of well tests in gas condensate reservoirs a serious challenge. In this study, at first the capillary number effect and Non-Darcy Flow on compositional simulation of gas condensate reservoirs were investigated and then well test analysis was carried out. The main objective of this work was to examine gas condensate well test analysis using single-phase gas pseudo-pressure and radial composite model assuming capillary number effect and Non-Darcy Flow. For this purpose some fluid samples were selected and results compared. Results indicate that estimation of reservoir properties below the dew point is in good agreement with actual input, particularly for lean fluid samples. 相似文献
76.
Hasan Kouchakzadeh Seyed Abbas Shojaosadati Fazel Shokri 《Chemical Engineering Research and Design》2014
Herein, the poorly water-soluble drug, Tamoxifen (Tmx), was loaded in the amphipathic matrix of human serum albumin (HSA) nanoparticles by a modified desolvation method. In order to enhance the drug loading (DL) and drug entrapment efficiency (DEE) (<2% and 10%, respectively), ultrasonication of Tmx-HSA mixture was performed prior to desolvation process. Tmx loading and entrapment efficiency were optimized by employment of the response surface methodology (RSM)-central composite design (CCD) of experiments. Under the optimum conditions of 1.59 mg Tmx/ml concentration, 7.76 pH and 5 h incubation of HSA-Tmx, the DL of 6.7% and DEE of 74% are achievable. Particles with the average size of 195 nm, zeta potential of −21 mV and polydispersity index of 0.09 were produced under these conditions. A more sustained Tmx release behavior was observed from polyethylene glycol (PEG) conjugated nanoparticles in comparison to the non-PEGylated ones. The short-term stability investigation showed no alteration in physicochemical properties of nanoparticles at 4 and 37 °C, but small increase in nanoparticles size was observed after three months of storage at room temperature. This is the first report for efficient production of a Tmx delivery system based on HSA nanoparticles. 相似文献
77.
Seyed A. Shojaosadati Hamid R. Sanaei Seyed M. Fatemi 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1996,67(4):362-366
Modifications of the conventional ethanol fermentation process using biomass and stillage recycle were investigated and the advantages of the technique were studied. The biomass recycle method resulted in a reduction in the use of approximately 8% raw material (molasses). The recycle of 15–70% of stillage (dealcoholised) from a previous fermentation was also tested successfully. Generally the results of these experiments revealed 13–47% less water consumption and consequently about 13–47% reduction of stillage volume, which was more economical for further treatments. 相似文献
78.
Sevda Dehghani Ahad Hanifpour Mehdi Nekoomanesh-Haghighi Samahe Sadjadi Seyed Amin Mirmohammadi Ali Farhadi Naeimeh Bahri-Laleh 《应用聚合物科学杂志》2020,137(22):49018
The main aim of this research is to decrease the amount of AlCl3 content that is very corrosive and hazardous in the catalytic system, required for the α-olefin oligomerization without substantial change of final oil features. This was successfully achieved by supporting AlCl3 on different carriers. More precisely, a series of supported bimetallic catalysts was synthesized by immobilization of AlCl3 and TiCl4 onto Al2O3, SiO2, and mixed supports, that is, Al2O3/FeCl3 and SiO2/FeCl3. It was found that silica and alumina-based catalysts had higher catalytic activities compared to support free AlCl3; however, this enhancement for silica-based supports was more significant. According to gel permeation chromatography (GPC) results, the use of single supports, that is, Al2O3 and SiO2, increased oligomer's molecular weight, while the application of mixed supports resulted in the decrease of molecular weight of the oligomers. Viscosity characteristics of the synthesized oligomers have also been studied at two different temperatures of 40 and 100°C (KV40 and KV100). The viscosity index (VI) values, derived from KV40 and KV100, of the prepared oligomers were in the range of 126–145. The molecular weight and termination mechanisms of the oligomers were studied by 1H-NMR spectroscopy. The obtained results disclosed that the employed reaction conditions led to the production of oligomer chains with various structures including vinylidene (Vd), and di and three-substituted vinylene (2Vn, 3Vn) structures. 相似文献
79.
Mohammad Shayan Asenjan Seyed Ali Reza Sabet Mehdi Nekoomanesh 《Iranian Polymer Journal》2020,29(4):301-307
This research explores mechanical and high velocity impact response of hybrid long carbon/glass fiber-reinforced polypropylene thermoplastic composites (HLFT) with different fiber lengths. The work examines three hybrid long fiber thermoplastic composites, i.e., 5, 10 and 20 mm. The HLFTs were prepared by a combination of extrusion and pultrusion processes and using a cross-head die. Tensile and Izod impact tests were carried out to evaluate the mechanical performance of each HLFT compound. A gas gun with a spherical projectile was used to conduct high velocity impact tests at three velocities of 144, 205 and 240 m/s. The results showed that internal mixing operation caused extensive reduction in fiber length of all three LFT lengths. Tensile strength, modulus and Izod impact test results were the indications of higher values with increase in HLFT length. Comparison of these results for the HLFT with that of corresponding glass/PP LFTs, adopted from earlier work by Shayan Asenjan et al. (J Compos Mater 53:353–360, 2019), showed better performance of HLFT. The high velocity impact results showed a steady higher impact performance with the increase in HFLT fiber length for all impact velocities tested. Comparison of HLFT high velocity impact performance revealed better results for all impact velocities tested with that of the corresponding glass/PP LFT composite. 相似文献
80.
Combustion of heavy fuels is one of the main sources of greenhouse gases, particulate emissions, ashes, NOxand SOx. Gasification is an advanced and environmentally friendly process that generates combustible and clean gas products such as hydrogen. Some entrained flow gasifiers operate with Heavy Fuel Oil(HFO) feedstock. In this application, HFO atomization is very important in determining the performance and efficiency of the gasifiers.The atomization characteristics of HFO(Mazut) discharging from a pressure-swirl atomizer(PSA) are studied for different pressures difference(Δp) and temperatures in the atmospheric ambient. The investigated parameters include atomizer mass flow rate( _m), discharge coefficient(CD), spray cone angle(θ), breakup length(Lb), the unstable wavelength of undulations on the liquid sheet(λs), global and local SMD(sauter mean diameter) and size distribution of droplets. The characteristics of Mazut sheet breakup are deduced from the shadowgraph technique. The experiments on Mazut film breakup were compared with the predictions obtained from the liquid film breakup model. Validity of the theory for predicting maximum unstable wavelength was investigated for HFO(as a highly viscous liquid). A modification on the formulation of maximum unstable wavelength was presented for HFO. SMD decreases by getting far from the atomizer. The measurement for SMD and θ were compared with the available correlations. The comparisons of the available correlations with the measurements of SMD andθ show a good agreement for Ballester and Varde correlations, respectively. The results show that the experimental sizing data could be presented by Rosin-Rammler distributions very well at different pressure difference and temperatures. 相似文献