Temperature effect on the electrical properties of undoped and vanadium-doped ZnTe thin films

Vanadium-doped ZnTe films of composition 0 to 10 wt% V, were prepared onto glass substrate by e-beam evaporation of the element in vacuum at 8×10⁻⁴ Pa. The effects of various deposition conditions on the electrical properties of the films have been studied in detail. The deposition rate of the ZnTe films was at about 2.05 nm s⁻¹. X-ray diffraction (XRD) study shows that the as-deposited ZnTe films are amorphous in nature.The effects of temperature on the electrical properties of the ZnTe and ZnTe:V films were studied in details. The heating and cooling cycles of the samples are reversible in the investigated temperature range after successive heat treatments in air. Thickness dependence of electrical conductivity is well in conformity with the Fuchs–Sondheimer theory. Temperature dependence of electrical conductivity shows a semiconducting behavior with a spectrum of activation energy. The value of activation energy for undoped ZnTe films do agree well with earlier reported values. Dopant vanadium concentration increases the conductivity of the samples. The composition and thickness dependence of the activation energy as well as thermoelectric power studies were done in the 300–413 K temperature range. The results of d.c. conductivity and thermopower obey an activated conduction mechanism. The thermopower of undoped ZnTe films indicates a p-type conductivity. Thermopower results of ZnTe:V films also suggest that the simultaneous bipolar conduction of both carriers take place.     

Farmer's view on soil organic matter depletion and its management in Bangladesh

Bangladesh is an agricultural country. About 80% of the total population live in rural areas. The contribution of agriculture to the gross domestic product is 30%. Rice is the major food crop while jute, sugarcane and tea are the main cash crops. Other important crops are wheat, tobacco, pulses, vegetables and fruits. Overall productivity in Bangladesh is stagnating or declining. The implication of yield stagnation or declining productivity is severe, since these trends have occurred despite rapid growth in the use of chemical fertilisers. Depletion of soil organic matter is the main cause of low productivity, which is considered one of the most serious threats to the sustainability of agriculture in Bangladesh. In Bangladesh, most soils have less than 17 g/kg and some soils have less than 10 g/kg organic matter. Farmers realise that there is a problem with soil fertility related to organic matter depletion. Farmers say that organic matter increases yield, reduces the production cost, improves crop growth and the economy, increases water-holding capacity and improves the soil structure. They recognise soil with higher organic matter content by darker brownish to black in colour. Some farmers are using fast-growing trees such as Flemingia macrophyla, Ipilipil (Leucaen leucophala), Glyricidia sepium, Boga Medula (Tephrosia candida), Dhol Kolmi (Ipomoea fistulosa), etc., as living fences, which can be used as fuel, fertiliser and fodder. To increase the soil organic matter, farmers use green manure crops, compost, quick compost, cow dung, azolla, etc. However, fuel for cooking purposes is limited and cow dung and crop residues are largely used as fuel. Crop residues are also used as fodder for livestock. Farmers expressed the wish to learn more about organic fertilizer management. However, sufficient food should be produced to keep pace with population growth. To alleviate the hunger and poverty is to increase the intensity of agricultural production and maintain favorable ecological conditions. Therefore, more organic matter should be used in the farmers' fields to sustain the soil fertility in an intensive farming system. This revised version was published online in June 2006 with corrections to the Cover Date.     

Arsenic groundwater contamination and its health effects in the state of Uttar Pradesh (UP) in upper and middle Ganga plain, India: a severe danger

This communication presents results of our 2-year survey on groundwater arsenic contamination in three districts Ballia, Varanasi and Gazipur of Uttar Pradesh (UP) in the upper and middle Ganga plain, India. Analyses of 4,780 tubewell water samples revealed that arsenic concentrations in 46.5% exceeded 10 microg/L, in 26.7%, 50 microg/L and in 10% 300 microg/L limits. Arsenic concentrations up to 3,192 microg//L were observed. The age of tubewells (n=1,881) ranged from less than a year to 32 years, with an average of 6.5 years. Our study shows that older tubewells had a greater chance of contamination. Depth of tubewells (n=3,810) varied from 6 to 60.5 m with a mean of 25.75 m. A detailed study in three administrative units within Ballia district, i.e. block, Gram Panchayet, and village was carried out to assess the magnitude of the contamination. Before our survey the affected villagers were not aware that they were suffering from arsenical toxicity through contaminated drinking water. A preliminary clinical examination in 11 affected villages (10 from Ballia and 1 from Gazipur district) revealed typical arsenical skin lesions ranging from melanosis, keratosis to Bowens (suspected). Out of 989 villagers (691 adults, and 298 children) screened, 137 (19.8%) of the adults and 17 (5.7%) of the children were diagnosed to have typical arsenical skin lesions. Arsenical neuropathy and adverse obstetric outcome were also observed, indicating severity of exposure. The range of arsenic concentrations in hair, nail and urine was 137-10,900, 764-19,700 microg/kg, and 23-4,030 microg/L, respectively. The urine, hair and nail concentrations of arsenic correlated significantly (r=0.76, 0.61, and 0.55, respectively) with drinking water arsenic concentrations. The similarity to previous studies on arsenic contamination in West Bengal, Bihar and Bangladesh indicates that people from a significant part of the surveyed areas in UP are suffering and this will spread unless drives to raise awareness of arsenic toxicity are undertaken and an arsenic safe water supply is immediately introduced.     

The effect of inertia on free convective plumes in porous media

The boundary layer approximation to the flow induced by a line source of heat embedded in a porous medium predicts that seepage velocities become large as the source is approached, and therefore it is expected that inertia (form drag) should become significant. Such an inertia-dominated regime was studied by Ingham [1], but we extend that analysis to intermediate distances from the source by computing the smooth transition between the inertia-dominated and inertia-free regimes.     

Biaxial stress relaxation of high impact polystyrene (HIPS) above the glass transition temperature

A procedure was developed and experiments were performed to measure the biaxial stress relaxation of High Impact Polystyrene (HIPS) sheets above the glass transition temperature. Tests were performed at various temperatures and strain magnitudes. The data were normalized to unity at time zero to isolate the time dependence of the stress from the strain dependence. The results show that the time dependent biaxial stress relaxation properties were independent of the magnitude of the stress or strain for small strains. The stress relaxation curves were fitted to a Prony series and i1 was found that time‐temperature superposition could be applied to interpolate the normalized relaxation. Uniaxial stress relaxation tests were also performed and the results were compared to that of the biaxial testing program.     

Influence of Grain Phase on Slag Corrosion of Low-Cement Castable Refractories

The grain phase has a significant influence on the extent and mechanism of attack of low-cement castables with similar bond systems in a crucible corrosion test. The general corrosion mechanism, as determined by post mortem scanning electron microscopic examination of corroded samples and thermodynamic calculations for all four grain types examined (white-fused alumina (WFA), tabular alumina (TA), brown-fused alumina (BFA), and alumina-rich spinel (S)), involves initial reaction of the most penetrating slag (enriched in calcium, manganese, and iron, because these elements diffuse rapidly) with the fine alumina and calcium aluminates of the matrix. This reaction gives a CaO-rich local liquid, which can then react with each grain predominantly to form calcium hexaluminate (CA₆) and hercynitic spinel. In the WFA system, a complete CA₆ layer forms around the grain, whereas in the TA system, this layer is incomplete. In both systems, extensive penetration occurs, although corrosion is low. In the BFA system, titanates are released from the grain into the bond, leading to increased densification of the refractory, via liquid-phase sintering, and consequent low penetration. However, the resulting fluid liquid dissolves easily in the slag, so that corrosive wear is high, even though a CA₆ layer forms around the grain. In the S grain system, uptake of the rapidly diffusing cations into the spinel crystal structure leads to silica-rich and viscous local liquid, which leads to low penetration and corrosion.     

Effect of tanniniferous Terminalia chebula extract on rumen biohydrogenation, ∆(9)-desaturase activity, CLA content and fatty acid composition in longissimus dorsi muscle of kids

Conjugated linoleic acid, a fatty acid found in milk fat and ruminant meat is one of the functional food components. Modifying fatty acid composition so as to increase CLA and other beneficial PUFA/MUFA level and reducing SFA levels might be a key to enhance the neutraceutical and therapeutic value of ruminant-derived food products. In the present experiment, the effect of supplementation of polyphenol rich Terminalia chebula plant extract at different concentrations (1.06 g/kg and 3.18 g/kg of body weight in T1 and T2 groups, respectively) was investigated on fatty acid composition of rumen fluid, plasma, intramuscular fat and Δ9-desaturase activity in longissimus dorsi muscle of crossbred kids. Total MUFA and PUFA content in muscle were enhanced by 25 and 35%, respectively, whereas SFA was reduced by 20% thereby improving the desaturation index. Δ9-desaturase activity also increased by 47% resulting in an enhancement of total CLA content (58.73%) in muscle.     

Novel multiplex PCR-RFLP assay discriminates bovine,porcine and fish gelatin substitution in Asian pharmaceuticals capsule shells

Gelatin is widely used in pharmaceuticals as a protective coating, such as soft and hard capsule shells. However, the animal source of gelatin is a sensitive issue because certain gelatins such as porcine and bovine gelatins are not welcome in Halal, Kosher and Hindus’ consumer goods. Recently, we have documented DNA barcoding and multiplex PCR platforms for discriminating porcine, bovine and fish gelatins in various fish and confectionary products; but those assays were not self-authenticating and also not tested in highly refined pharmaceutical products. To address this knowledge gap, here we report a self-authenticating multiplex PCR-restriction fragment length polymorphism (RFLP) assay to identify animal sources of various gelatin in pharmaceutical capsules. Three different restriction enzymes, BsaAI, Hpy188I and BcoDI were used to yield distinctive RFLP patterns for gelatin-based bovine (26, 94 bp), fish (97, 198 bp) and porcine (17, 70 bp) DNA in control experiments. The specificity was cross-tested against 16 non-target species and the optimised assay was used to screen gelatin sources in 30 halal-branded pharmaceuticals capsule shells. Bovine and porcine DNA was found in 27 and 3 of the 30 different capsules products. The assay was suitable for detecting 0.1 to 0.01 ng total DNA extracted from pure and mixed gelatins. The study might be useful to authenticate and monitor halal, kosher, vegetarian and Hindu compliant pharmaceuticals, foods and cosmetics.     

Inflammation Causes Exacerbation of COVID-19: How about Skin Inflammation?

COVID-19 is a recently emerged viral infection worldwide. SARS-CoV-2, the causative virus, is believed to have emerged from bat coronaviruses, probably through host conversion. The bat coronavirus which has the highest gene homology to SARS-CoV-2 specifically infects deep forest bats in China whose habitat extends through the Middle East to Southern Europe. Host conversion might have occurred due to the deforestation by humans exposing wild bats to the environment they had never encountered before. SARS-CoV-2 infects cells through two mechanisms: through its receptor ACE2 with the help of enzyme TMPRSS and through membrane fusion with the help of elastases in the inflammatory condition. Obesity, hypertension, diabetes mellitus, and pulmonary diseases cause poor prognosis of COVID-19. Aging is another factor promoting poor prognosis. These diseases and aging cause low-level and persistent inflammation in humans, which can promote poor prognosis of COVID-19. Psoriasis and atopic dermatitis are the major inflammatory skin diseases. These inflammatory skin conditions, however, do not seem to cause poor prognosis for COVID-19 based on the epidemiological data accumulated so far. These mechanisms need to be elucidated.     

Silver-Decorated Silicon Nanostructures: Fabrication and Characterization of Nanoscale Terraces as an Efficient SERS-Active Substrate

Rich and highly dense surface-enhanced Raman (SERS) hotspots available in the SERS-active platform are highly anticipated in SERS measurements. In this work, conventional silicon wafer was treated to have wide exposure to terraces available within the silicon nanostructures (Si-NSs). High-resolution field emission scanning electron microscopic (FESEM) investigations confirmed that the terraces were several microns wide and spread over different steps. These terraces were further decorated with silver nanoparticles (Ag-NPs) of different shapes and sizes to achieve SERS-active hotspots. Based on more than 150 events, a histogram of the size distribution of Ag-NPs indicated a relatively narrow size distribution, 29.64 ± 4.66 nm. The coverage density was estimated to be ~4 × 10¹⁰ cm⁻². The SERS-activity of Ag-NPs -decorated Si-NSs was found to be enhanced with reference to those obtained in pristine Si-NSs. Finite difference time domain models were developed to support experimental observations in view of electromagnetic (EM) near-field distributions. Three archetype models; (i) dimer of same constituent Ag-NPs, (ii) dimer of different constituent Ag-NPs, and (iii) linear trimer of different constituent Ag-NPs were developed. EM near-field distributions were extracted at different incident polarizations. Si-NSs are well-known to facilitate light confinement, and such confinement can be cascaded within different Ag-NPs-decorated terraces of Si-NSs.