Investigation of Tool Wear and Surface Finish by Analyzing Vibration Signals in Turning Assab-705 Steel

Various occurrences in machining influence the machining dynamics and thus produce vibration in the cutting tool-workpiece arrangement. In this investigation, with tri-axial accelerometer mounted on the tool-holder in turning ASSAB-705 steel, vibration signals have been captured with and without cutting. The nature of vibrations arising in the cutting tool at different cutting conditions has been investigated. It has been observed that the RMS amplitude of vibration along all three axes for the increasing cutting speed was mixed in nature; however, an increasing trend was noticed in the vibrations along the feed, V_x and radial, V_y directions. The vibration along the main cutting direction, V_z was mixed, initiated by large vibration and then decreased until a particular cutting speed was reached and finally increased steadily. The feed vibration component, V_x has a similar response to the change of the workpiece surface roughness, while the other two components, V_y and V_z have the more coherent response to the rate of flank wear progression throughout the tool life. The natural frequency of different machine parts vibration has been found to be within the band of 0 Hz – 4.2 kHz, whereas the frequencies of different occurrences in turning varied between 98 Hz and 42 kHz.     

Molecular dynamics simulations of deformation mechanisms of amorphous polyethylene

Molecular dynamics simulations were used to study deformation mechanisms during uniaxial tensile deformation of an amorphous polyethylene polymer. The stress-strain behavior comprised elastic, yield, strain softening and strain hardening regions that were qualitatively in agreement with previous simulations and experimental results. The chain lengths, number of chains, strain rate and temperature dependence of the stress-strain behavior was investigated. The energy contributions from the united atom potential were calculated as a function of strain to help elucidate the inherent deformation mechanisms within the elastic, yield, and strain hardening regions. The results of examining the partitioning of energy show that the elastic and yield regions were mainly dominated by interchain non-bonded interactions whereas strain hardening regions were mainly dominated by intra-chain dihedral motion of polyethylene. Additional results show how internal mechanisms associated with bond length, bond angle, dihedral distributions, change of free volume and chain entanglements evolve with increasing deformation.     

Sulfonated poly(ether sulfone) electrolytes structured with mesonaphthobifluorene graphene moiety for PEMFC

Sulfonated poly(ether sulfone)s containing a mixture of cis and trans mesonaphthobifluorene moiety were synthesized, and their properties were characterized. The mesonaphthobifluorene graphene moiety contained 6 phenyl rings and was conjugated together to form planar sheets of sp²-bonded carbon. Poly(arylene ether sulfone)s containing a mixture of cis and trans tetraphenyl ethylene units were synthesized by polycondensation, and converted into graphene by intramolecular Friedel–Craft cyclization with Lewis acid (FeCl₃). The sulfonation was taken selectively on mesonaphthobifluorene units with concentrated sulfuric acid. The structural properties of the sulfonated polymers were investigated by ¹H NMR spectroscopy. The membranes were studied with regard to ion exchange capacity (IEC), water uptake, and proton conductivity.     

Properties of controlled low-strength materials incorporating cement kiln dust and slag

This research evaluated the potential use of cement kiln dust (CKD) together with slag to replace the use of cement in the production of controlled low-strength material (CLSM). The low strength requirements of CLSM compared to conventional concrete enable the use of industrial by-products for the production of CLSM. In this study, the workability-related fresh properties of CLSM mixtures were observed through slump flow diameter, V-funnel flow time and filling capacity. Setting times, temperature rise, air content and unit weight of CLSM mixtures were also determined as part of fresh properties. The hardened properties that were monitored for 28 days included the unconfined compressive strength. The test results presented herein show that a combination of less than 50 kg/m³ slag and up to 300 kg/m³ CKD provides a good mix that satisfies the requirements of a CLSM with similar or better properties to that of CKD-based CLSM mix containing Portland cement. Suitable CLSM mixtures with reasonable fresh and hardened properties could also be developed by using CKD alone. However, reduced strength in such CLSM mixtures may limit their field application. The slag significantly assisted in increasing compressive strength of CKD-based CLSM mixtures. A CLSM mix containing a combination of slag and CKD was shown to have excellent characteristics for flowable backfill and excavatable base material. Therefore, producing CKD/slag based CLSM through the use of co-generated products from the cement and iron manufacturing processes can provide leadership for the construction industry in the transition for sustainable development.     

Flexural response of hybrid carbon fiber thin cement composites

It is evident that the carbon-fiber-reinforced cementitious composites are being used in the structural and construction works owing to the synergetic action from two components viz. fiber and mortar matrix. Incorporation of a very nominal percentage of carbon fibers into a mortar mixture produces a strong and durable composite that leads the product of smart material properties. Flexural behavior of cement-based matrices carrying carbon fibers reinforcement of different percentage and size is studied in this paper. Influence of fiber content and length of the fiber is quantified using load–deflection curves. Specimens containing fiber of 0.0, 0.5, 1.0 and 1.5% with 3 mm (0.12 in.), 6 mm (0.36 in.), and their combination are prepared and tested. It is demonstrated that combination of 3 mm (0.12 in.) and 6 mm (0.36 in.) fibers enhances the bearing capacity to crack- and ultimate-stresses as well as the Young’s modulus of the fiber reinforced cement composites. The paper emphasizes the desired performances after the initiation of cracks and discusses the pre- and post-cracking load–deflection characteristics of the composites.     

Effect of surface roughness and surface modification of indium tin oxide electrode on its potential response to tryptophan

The effect of surface modification of indium tin oxide (ITO) electrode on its potential response to tryptophan was investigated for ITO substrates with different surface roughness. It was found that a small difference in surface roughness, between ∼1 and ∼2 nm of R_a evaluated by atomic force microscopy, affects the rest potential of ITO electrode in the electrolyte. A slight difference in In:Sn ratio at the near surface of the ITO substrates, measured by angle-resolved X-ray photoelectron spectrometry and Auger electron spectroscopy is remarkable, and considered to relate with surface roughness. Interestingly, successive modification of the ITO surface with aminopropylsilane and disuccinimidyl suberate, of which essentiality to the potential response to indole compounds we previously reported, improved the stability of the rest potential and enabled the electrodes to respond to tryptophan in case of specimens with R_a values ranging between ∼2 and ∼3 nm but not for those with R_a of ∼1 nm. It was suggested that there are optimum values of effective work function of ITO for specific potential response to tryptophan, which can be obtained by the successive modification of ITO surface.     

Impacts of CO2 emission constraints on technology selection and energy resources for power generation in Bangladesh

This paper examines the impacts of CO₂ emission reduction target and carbon tax on future technologies selection and energy use in Bangladesh power sector during 2005–2035. The analyses are based on a long-term energy system model of Bangladesh using the MARKAL framework. The analysis shows that Bangladesh will not be able to meet the future energy demand without importing energy. However, alternative policies on CO₂ emission constraints reduce the burden of imported fuel, improve energy security and reduce environmental impacts. The results show that the introduction of the CO₂ emission reduction targets and carbon taxes directly affect the shift of technologies from high carbon content fossil-based to low carbon content fossil-based and clean renewable energy-based technologies compared to the base scenario. With the cumulative CO₂ emission reduction target of 10–20% and carbon tax of 2500 Taka/ton, the cumulative net energy imports during 2005–2035 would be reduced in the range of 39–65% and 37%, respectively, compared to the base scenario emission level. The total primary energy requirement would be reduced in the range of 4.5–22.3% in the CO₂ emission reduction targets and carbon tax 2500 Taka/ton scenarios and the primary energy supply system would be diversified compared to the base scenario.     

Contrast-based evaluation of mar resistance of thermoplastic olefins

The physical aspect of mar behavior is studied by applying a standardized progressive sliding load methodology to smooth and textured automotive-grade thermoplastic olefins. It is shown that surface texture has a strong effect on light scattering and, hence, the propensity for mar visibility. It is also shown that digital imaging via a desktop scanner can be used to quantitatively and objectively assess mar resistance using contrast as a basis. Incorporation of slip agent definitively improves the mar resistance for both types of surfaces. Relationships between contrast, gloss and surface roughness in relation to mar visibility are discussed.     

A general inelastic internal state variable model for amorphous glassy polymers

This paper presents the formulation of a constitutive model for amorphous thermoplastics using a thermodynamic approach with physically motivated internal state variables. The formulation follows current internal state variable methodologies used for metals and departs from the spring-dashpot representation generally used to characterize the mechanical behavior of polymers like those used by Ames et al. in Int J Plast, 25, 1495–1539 (2009) and Anand and Gurtin in Int J Solids Struct, 40, 1465–1487 (2003), Anand and Ames in Int J Plast, 22, 1123–1170 (2006), Anand et al. in Int J Plast, 25, 1474–1494 (2009). The selection of internal state variables was guided by a hierarchical multiscale modeling approach that bridged deformation mechanisms from the molecular dynamics scale (coarse grain model) to the continuum level. The model equations were developed within a large deformation kinematics and thermodynamics framework where the hardening behavior at large strains was captured using a kinematic-type hardening variable with two possible evolution laws: a current method based on hyperelasticity theory and an alternate method whereby kinematic hardening depends on chain stretching and material plastic flow. The three-dimensional equations were then reduced to the one-dimensional case to quantify the material parameters from monotonic compression test data at different applied strain rates. To illustrate the generalized nature of the constitutive model, material parameters were determined for four different amorphous polymers: polycarbonate, poly(methylmethacrylate), polystyrene, and poly(2,6-dimethyl-1,4-phenylene oxide). This model captures the complex character of the stress–strain behavior of these amorphous polymers for a range of strain rates.     

A hygrometer comprising a porous silicon humidity sensor with phase-detection electronics

A novel hygrometer is presented, comprising a capacitive humidity sensor with a porous silicon (PS) dielectric and electronics. The adsorption of water vapor by the PS layer leading to change of its effective dielectric constant is modeled with an effective medium approximation (EMA). A simple, but precise, phase-sensitive electronic circuit has been developed. This detects any change of phase of a sinusoidal signal transmitted through the PS dielectric and correlates to ambient humidity. It is outlined how the nonlinear response of the sensor is compensated through piecewise linearization. The sensor is tested in combination with the phase detection circuitry. Excellent linearity over the entire range of relative humidity is achieved. Experimental results show a resolution better than 0.1% and an accuracy of 2% (near the transition region) and better than 0.1% (otherwise). The response time is less than 10 s with good stability.