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排序方式: 共有173条查询结果,搜索用时 15 毫秒
21.
Yinhui Kan Sebastian K. H. Andersen Fei Ding Shailesh Kumar Changying Zhao Sergey I. Bozhevolnyi 《Advanced materials (Deerfield Beach, Fla.)》2020,32(16):1907832
Single photons carrying spin angular momentum (SAM), i.e., circularly polarized single photons generated typically by subjecting a quantum emitter (QE) to a strong magnetic field at low temperatures, are at the core of chiral quantum optics enabling nonreciprocal single-photon configurations and deterministic spin-photon interfaces. Here, a conceptually new approach to the room-temperature generation of SAM-coded single photons (SSPs) is described, which entails QE nonradiative coupling to surface plasmons being transformed, by interacting with an optical metasurface, into a collimated stream of SSPs with the designed handedness. Design, fabrication, and characterization of SSP sources, consisting of dielectric circular nanoridges with azimuthally varying widths deterministically fabricated on a dielectric-protected silver film around a nanodiamond containing a nitrogen-vacancy center, are reported. With properly engineered phases of QE-originated fields scattered by nanoridges, the outcoupled photons are characterized by a well-defined SAM (with the chirality >0.8) and high directionality (collection efficiency up to 92%). 相似文献
22.
Shailesh Mishra Sushrut Das Shyam S. Pattnaik Sachin Kumar Binod K. Kanaujia 《国际射频与微波计算机辅助工程杂志》2020,30(1)
In this article, a three‐port nonplanar multiple‐input‐multiple‐output/diversity antenna with very high isolation between the radiating elements is presented. To realize diversity from the proposed three‐dimensional (3‐D) antenna configuration, three monopole radiating elements are arranged at an angle of 120°. The isolation between the radiators is enhanced by using a multilayered cylindrical decoupling structure and defected ground structure (DGS). The DGS reduces the coupling due to surface waves while the cylindrical decoupling structure reduces the coupling due to space waves. The proposed antenna offers consistent pervasive connectivity in the wireless communication environment due to its 3‐D geometry with multiple radiating elements and good diversity performance. The prototype is fabricated and measured result shows that more than 42 dB isolation is obtained at the center frequency 1.45 GHz. An increment of 1.2 dBi in the antenna gain is also achieved by using DGS and decoupling structure arrangement. The proposed antenna can be easily placed inside the cylindrical housing or it can be integrated with the existing electronics chip, thus nullifying the requirement for dedicated location in the system. 相似文献
23.
Wireless Personal Communications - The presented antenna is a novel highly isolated compact four-element Multiple Input Multiple Output (MIMO) antenna with common ground, which can reject three... 相似文献
24.
Shailesh V. Potnis Terry G. Lenz Eric H. Dunlop 《Chemical Engineering Communications》1995,139(1):41-49
A relatively simple method was employed for measurement of water diffusivity in aqueous lithium bromide and lithium chloride solutions. The twin bulb apparatus used for these measurements was developed using an analogy between this apparatus and the conventional diaphragm cell apparatus. Tritiated water (TOH) was used as a tracer for these experiments because of its chemical similarity and proximity to the molecular weight of water. High tracer activity used at the beginning of the experiments allowed the use of relatively shorter time duration for each experiment (s;≈ 20 h) and a quasi-steady state equation to calculate the diffusivity from the observed tracer activity data
Initially, the water diffusivity in lithium bromide solutions for concentrations varying from 0.5 M to 3 M (22.1 weight percent) was measured to obtain a comparison with published values. The lithium bromide concentration was further varied from 3 M to 11 M (57.4 weight percent) to obtain data in the concentration range usually employed in absorption cooling applications, which is near the solubility limit. The water diffusivity was found to vary with lithium bromide concentration, and to have a maximum of 16.7 × 10-10m2/s at 4 M. These diffusivity values were also compared with those obtained using an equation proposed by Rosevaere etal. (1941) for nonideal solutions. The water diffusivity in lithium chloride solutions was measured at concentrations of 7 M (25.7 weight percent) and 8 M (28.87 weight percent) to obtain a comparison with published values. The lithium choride concentration was further varied from 8 M to 13 M (43.24) weight percent) to gather data beyond those of other researchers. Similar to the trend of water diffusivity in lithium bromide solutions, water diffusivity in lithium chloride solutions was also found to vary with concentration with a minimum of 6.2 × 10-10m2/s near the solubility limit. 相似文献
Initially, the water diffusivity in lithium bromide solutions for concentrations varying from 0.5 M to 3 M (22.1 weight percent) was measured to obtain a comparison with published values. The lithium bromide concentration was further varied from 3 M to 11 M (57.4 weight percent) to obtain data in the concentration range usually employed in absorption cooling applications, which is near the solubility limit. The water diffusivity was found to vary with lithium bromide concentration, and to have a maximum of 16.7 × 10-10m2/s at 4 M. These diffusivity values were also compared with those obtained using an equation proposed by Rosevaere etal. (1941) for nonideal solutions. The water diffusivity in lithium chloride solutions was measured at concentrations of 7 M (25.7 weight percent) and 8 M (28.87 weight percent) to obtain a comparison with published values. The lithium choride concentration was further varied from 8 M to 13 M (43.24) weight percent) to gather data beyond those of other researchers. Similar to the trend of water diffusivity in lithium bromide solutions, water diffusivity in lithium chloride solutions was also found to vary with concentration with a minimum of 6.2 × 10-10m2/s near the solubility limit. 相似文献
25.
Shailesh Singh Chouhan Kari Halonen 《Analog Integrated Circuits and Signal Processing》2017,92(3):343-353
This work presents a two-stage voltage multiplier (VM) useful in RF energy harvesting based applications. The proposed circuit is based on the conventional differential drive rectifier, in which the input RF signal has been level shifted using a simple arrangement. This signal is then used to drive the next stage, which has been formed by using gate cross-coupled transistors. As a result, the load driving capability of the proposed architecture increases. The load in this work has been emulated in terms of a parallel RC circuit. The architecture has been implemented using standard 0.18 \(\mu\)m CMOS technology. The measurements of the two-stage conventional VM (CVM) and proposed VM circuits were performed at ISM frequencies 13.56, 433, 915 MHz and 2.4 GHz for R\(_L\) of values 1, 5, 10, 3 and 100 K\(\Omega\) with a fixed value of C\(_L\) equal to 20 pF. The performance evaluation has been done in terms of the power conversion efficiency (PCE) and average output DC voltage. The measured results show an improvement in PCE of 5% (minimum) for 13.56, 433 and 915 MHz frequencies, and up to 2% improvement for a frequency value of 2.4 GHz at the targeted load condition of 5 K\(\Omega ||\)20 pF, when compared with the measured results of the CVM circuit. 相似文献
26.
Phylogenetic Studies,Gene Cluster Analysis,and Enzymatic Reaction Support Anthrahydroquinone Reduction as the Physiological Function of Fungal 17β‐Hydroxysteroid Dehydrogenase 下载免费PDF全文
Leon Fürtges David Conradt Dr. Michael A. Schätzle Shailesh Kumar Singh Dr. Nada Kraševec Prof. Dr. Tea Lanišnik Rižner Prof. Dr. Michael Müller Dr. Syed Masood Husain 《Chembiochem : a European journal of chemical biology》2017,18(1):77-80
17β‐Hydroxysteroid dehydrogenase (17β‐HSDcl) from the filamentous fungus Curvularia lunata (teleomorph Cochliobolus lunatus) catalyzes NADP(H)‐dependent oxidoreductions of androgens and estrogens. Despite detailed biochemical and structural characterization of 17β‐HSDcl, its physiological function remains unknown. On the basis of amino acid sequence alignment, phylogenetic studies, and the recent identification of the physiological substrates of the homologous MdpC from Aspergillus nidulans and AflM from Aspergillus parasiticus, we propose an anthrahydroquinone as the physiological substrate of 17β‐HSDcl. This is also supported by our analysis of a secondary metabolite biosynthetic gene cluster in C. lunata m118, containing 17β‐HSDcl and ten other genes, including a polyketide synthase probably involved in emodin formation. Chemoenzymatic reduction of emodin by 17β‐HSDcl in the presence of sodium dithionite verified this hypothesis. On the basis of these results, the involvement of a 17β‐HSDcl in the biosynthesis of other anthrahydroquinone‐derived natural products is proposed; hence, 17β‐HSDcl should be more appropriately referred to as a polyhydroxyanthracene reductase (PHAR). 相似文献
27.
Shailesh N. Sharma Himani Sharma Gurmeet Singh S.M. Shivaprasad 《Materials Chemistry and Physics》2008,110(2-3):471-480
This work reports the interaction of aliphatic (triethyl amine, butyl amine) and aromatic amines (PPD, aniline) with CdSe quantum dots of varied sizes. The emission properties and lifetime values of CdSe quantum dots were found to be dependent on the oxidation potential of amines and crystallite sizes. Smaller CdSe quantum dots (size 5 nm) ensure better surface coverage of amines and hence higher quenching efficiency of amines could be realized as compared to larger CdSe quantum dots (size 14 nm). Heterogeneous quenching of amines due to the presence of accessible and inaccessible set of CdSe fluorophores is indicated. PPD owing to its lowest oxidation potential (0.26 V) has been found to have higher quenching efficiency as compared to other amines TEA and aniline having oxidation potentials 0.66 and >1.0 V, respectively. Butyl amine on the other hand, plays a dual role: its post-addition acts as a quencher for smaller and enhances emission for larger CdSe quantum dots, respectively. The beneficial effect of butyl amine in enhancing emission intensity could be attributed to enhance capping effect and better passivation of surface-traps. 相似文献
28.
Hem Joshi Bryan R. Moser Shailesh N. Shah Anurag Mandalika Terry Walker 《European Journal of Lipid Science and Technology》2010,112(7):802-809
The low temperature operability and oxidative stability of cottonseed oil methyl esters (CSME) were improved with four anti‐gel additives as well as one antioxidant additive, gossypol. Low temperature operability and oxidative stability of CSME was determined by cloud point (CP), pour point (PP), cold filter plugging point (CFPP), and oxidative stability index (OSI). The most significant reductions in CP, PP, and CFPP in all cases were obtained with Technol®, with the average reduction in temperature found to be 3.9 °C. Gunk®, Heet®, and Howe's® were progressively less effective, as indicated by average reductions in temperature of 3.4, 3.0, and 2.8 °C, respectively. In all cases, the magnitude of CFPP reduction was greater than for PP and especially CP. Addition of gossypol, a polyphenolic aldehyde, resulted in linear improvement in OSI (R2 = 0.9804). The OSI of CSME increased from 5.0 to 8.3 h with gossypol at a concentration of 1000 ppm. 相似文献
29.
Namrta Purwar Jason Tenboer Shailesh Tripathi Marius Schmidt 《International journal of molecular sciences》2013,14(9):18881-18898
Time-resolved spectroscopic experiments have been performed with protein in solution and in crystalline form using a newly designed microspectrophotometer. The time-resolution of these experiments can be as good as two nanoseconds (ns), which is the minimal response time of the image intensifier used. With the current setup, the effective time-resolution is about seven ns, determined mainly by the pulse duration of the nanosecond laser. The amount of protein required is small, on the order of 100 nanograms. Bleaching, which is an undesirable effect common to photoreceptor proteins, is minimized by using a millisecond shutter to avoid extensive exposure to the probing light. We investigate two model photoreceptors, photoactive yellow protein (PYP), and α-phycoerythrocyanin (α-PEC), on different time scales and at different temperatures. Relaxation times obtained from kinetic time-series of difference absorption spectra collected from PYP are consistent with previous results. The comparison with these results validates the capability of this spectrophotometer to deliver high quality time-resolved absorption spectra. 相似文献
30.
Shailesh J. Patil 《Chemical Engineering Communications》2019,206(5):605-618
Jatropha oil is a promising nonedible feedstock for producing renewable diesel. In this work, the hydrotreatment processing of jatropha oil was investigated. Instead of using conventional alumina-supported Co–Mo, Ni–Mo, and Ni–W catalysts that need sulfidation pretreatment, noble metals such as Pd and Ru were chosen. Trials were performed in an isothermal trickle-bed reactor and the reaction conditions were as follows: temperature 603–663?K, weight hourly space velocity (WHSV) 1 to 4/h, pressure 1.5–3?MPa, and H2/oil ratio 200–800 (v/v). Yield of n-C15 to n-C18 hydrocarbons was maximized (70.3 and 43.8% for Pd/Al2O3 and Ru/Al2O3, respectively) at the following conditions: T?=?663 K, WHSV?=?2/h, P?=?3?MPa, and H2/oil ratio?=?600 (v/v). Since Ru favored cracking reactions to a larger extent than Pd, the yield of C15 to C18 hydrocarbons over Ru/Al2O3 was lowered. Using simple first-order plots for oil conversion, activation energies for the hydrotreating process over Pd/Al2O3 and Ru/Al2O3 were found and they were equal to 109 and 121?kJ/mol, correspondingly. 相似文献