Neutral Pd(II) and Ni(II) Acetylide Catalysts for the Polymerization of Methyl Methacrylate

Homogenous polymerization of methyl methacrylate using Pd(II)- and Ni(II)-based acetylide complexes as initiators has been investigated. M(PR'₃)₂(CCR)₂ (M=Pd, Ni; R'=PPh₃, Pn-Bu₃; R=Ph, CH₂OH, CH₂OOCCH₃, CH₂OOCPh, CH₂OOCPhOH-o) were found to be a novel type of effective initiators for the polymerization of methyl methacrylate. Among them, Pd(C CPh)₂(PPh₃)₂ (PPP) shows the highest activity in the MMA polymerization and the PMMA obtained is a syndiotactic polymer with high number-average molecular weight (M _n) of 14.1 × 10⁴. Some features and kinetic behavior of MMA polymerization initiated by PPP were studied in detail. The polymerization reaction is first-order with respect to both [PPP] and [MMA]. Radical polymerization mechanism is proposed.     

ICP-AES法测定钼钇合金中钇的质量分数

用电感耦合等离子体发射光谱法（ICP-AES）对钼钇合金中钇的质量分数进行了测定．对被测元素的分析谱线,仪器的主要参数,酸度的影响进行了试验,确定了最佳工作条件．结果表明,该方法的线性范围为0-10ug／mL,回收率为95．0％～106．2％,相对标准偏差小于3．34％．通过对钼钇合金试样的加标回收实验和反复测定,说明该方法稳定、快速和准确．     

混合测试框架的研究与实现

为有效解决NP(网络处理器)仿真器测试问题,研究了自动化测试框架的原理与技术.针对NP仿真器的特点,基于混合测试驱动框架,提出了一种简单的测试框架.只需编写少量脚本即可实现复杂的测试.测试框架降低了测试成本,提高了效率和质量.     

一种拟合误差驱动的自适用隐式曲面重建算法

针对散乱数据,提出一种拟合误差驱动的自适应隐式曲面重建算法。算法根据二次曲面的拟合误差进行自适应拟合,改变了传统方法从八叉树中顶层节点开始拟合,减少了拟合次数,加快了重建速度;并修正权函数,加入密度函数,削弱由于散乱数据密度的不一致对重建曲面影响。实验结果表明,该算法原理简单,重建速度快,重建效果良好。     

Factors influencing magnetic polymer microspheres prepared by dispersion polymerization

Magnetic iron oxide (Fe₃O₄) was prepared by a coprecipitation method. Core–shell composite magnetic polymer microspheres with carboxyl groups were synthesized by the dispersion polymerization of styrene and acrylic acid in the presence of magnetic oxide, and dibenzoyl peroxide was used as an initiator. The synthesized magnetic polymer microspheres were characterized with X‐ray diffraction, transmission electron microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, and so forth. The results indicated that the product was single‐phase Fe₃O₄, and its average size was about 10 nm. The configuration of the microspheres, which contained carboxyl groups, was spherical, and the average size was about 2 μm. The results of vibrating sample magnetometry tests showed that the magnetic powders produced by different surfactants had different saturation magnetizations. When poly(ethylene glycol) with a weight‐average molecular weight of 4000 was used as a surfactant, the saturation magnetization of the samples reached 69.2 emu/g. The factors that affected the shape, magnetism, size, and distribution of the microspheres were also studied. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

高压变频器在冲渣泵调速系统中的应用研究

介绍一种基于罗宾康高压变频器的调速监控系统,详细阐述了系统构成、工作原理。在分析了ModBus通信协议的基础上,设计并完成了基于VB的调速系统远程监控软件的开发。工程应用效果良好,实现了某钢厂冲渣工艺的节能自动控制。该系统的软硬件设计方案对同类型系统设计有参考价值。     

智能电能表质量数据采集与质量监控技术研究

针对智能电能表非常容易发生开关跳闸、断电无法工作等故障问题,研究出了一种完善的解决方法;通过调研智能电能表生产企业的信息化系统和生产过程数据,发现生产企业的信息化系统在不同企业间都存在各个信息系统之间分割严重的问题,导致企业内部的数据分布在各个数据仓库内,数据分散,需要对每个生产企业采集装置的采集功能进行定制化对接,基于边缘计算技术的业务系统能够更加切合采集终端,并进行数据处理;本研究将SVG技术和Ajax技术结合使用,构成智能电能表质量监控系统方案框架;经过实验结果表明,通过SVG技术和Ajax技术对智能电力表各项数据信息处理,得到了很好的效果.     

新型玉米精密播种机排种监视器设计

针对目前市场上排种监视器计数不准、抗干扰能力差等缺点,采用微计算机智能控制与光电检测技术相结合的方法,设计一种新型玉米精密播种机排种监视器。该监视器在固定时间间隔内,根据光电传感器实时监测的玉米落籽情况,统计漏播指数、重播指数及合格指数等重要参数,并且具有面积自动统计、掉电计数及漏播报警等功能。经实际使用结果证明,该监视器结构合理,性能稳定可靠,对农业生产具有巨大的生产意义和经济效益。     

基于随机共振原理的低频弱信号检测方法研究

介绍了双稳系统,讨论了产生随机共振的条件以及输出频谱的特性。针对原双稳系统不能检测中低频率信号的问题,利用参数变换原理,推导出了一种新的模型,阐述与分析了该模型的参数变化对输出混合信号的影响。模型相对于经典双稳系统模型降低了对输入的要求。     

Logistic映射及其混沌序列特性分析

提出了一种基于频谱特征分析Logistic映射工作状态的方法.首先,对典型Logistic迭代映射函数,在给定初值的情况下随参数μ变化得到不同的数值分布序列图和分岔图;其次,通过傅立叶变换得到Logistic映射的频谱特性,从频域弥补了时域分析中无法观测到的Logistic映射混沌特性;最后,通过对比分析表明Logistic映射的类随机性适合应用于保密通信领域.