Poly(3‐chlorothiophene) films prepared by the direct electrochemical oxidation of 3‐chlorothiophene in mixed electrolytes of boron trifluoride diethyl etherate and sulfuric acid

3‐Chlorothiophene (CT) was electrochemically polymerized in mixed electrolytes of a boron trifluoride diethyl etherate solution containing 0–20% (by volume) sulfuric acid. The oxidation potentials of the monomer in these media were measured to be only 1.06–1.31 V (vs Ag/AgCl). These values were much lower than that of CT in acetonitrile and 0.1 mol/L (Bu)₄NBF₄ (1.92 V vs Ag/AgCl). Poly(3‐chlorothiophene) (PCT) films with conductivities of 0.1–2 S cm^?1 were obtained. The structure, morphology, and electrochemical behavior of the PCT films also were investigated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 502–509, 2003     

聚氨酯丙烯酸酯紫外光固化PVC涂料的研制

通过对涂料不同组分的种类及配比进行调节,制备不同配方的PVC清漆。在测试附着力、硬度、耐温、耐水性能的基础上,优化涂料配方,并配制出性能优异的PVC清漆涂料。     

Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006     

Soap‐free emulsion copolymerization of perfluoroalkyl acrylates in the presence of a reactive surfactant

Soap‐free emulsion copolymerization of perfluoroalkyl acrylate (FA)/methyl methacrylate (MMA)/n‐butyl acrylate (n‐BA) was carried out in the presence of sodium 2‐acrylamide‐2‐methyl propanesulfonate (AMPSNa) as a reactive surfactant and potassium persulfate (KPS) as an initiator. An analysis of the effects of concentration of AMPSNa, KPS, FA as well as polymerization temperature on the kinetic features (rate of polymerization) and colloidal characteristics (mean particle diameter, particle disperse index, particle numbers, and surface charge density) was followed. NMR, FTIR, AFM, and fluorine‐selective electrode analysis were used to characterize the composition and morphology of the FA copolymers. Both AFM analysis and contact angle measurements strongly implied that the fluorinated segments migrated to the outmost surface and created films with lower surface energy. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2438–2444, 2007     

扬巴工程中承包商合同控制

阐述扬巴项目中合同控制的基本做法,比较国内工程与涉外工程项目中合同控制的差异,提出承包商在涉外工程项目中做好合同控制工作的建议。     

新型聚丙烯接枝物的制备及应用

为制备强韧的共混材料,利用熔融接枝法研制了含有两种接技单体的新型聚丙烯接枝物,讨论了第二单体在接枝过程中的作用,并将其应用于尼龙6/聚丙烯(PA6/PP)共混体系,获得了使分散相粒径更细小、界面更模糊的增容效果。     

庙宇平坝防洪治理方案研究

庙宇平坝地处大溪河右岸支流庙宇沟上游山间盆地内,仅靠一条人工开凿的排洪洞和天然消坑排泄洪水,过流能力不足致使每年都遭受洪涝灾害。根据庙宇平坝地形条件及防洪现状,复核现有排洪设施泄流能力,分析存在的问题,结合庙宇平坝地形条件及区内实际情况,采取整个消水洞的扩建及进口前100 m的河道支护,从而提高泄洪能力,降低庙宇平坝水位,有效减少洪水淹没历时及淹没深度。     

A survey of traffic-based routing metrics in family of expected transmission count for self-organizing networks

Self-Organizing Networks (SONs) are attractive for applications where flexibility, resilience, and a large network service area are required. In order to meet the requirements of those applications, the principal issue is to guarantee efficient routing in SONs. Hence, the design and selection of appropriate routing metrics is important. A mass of metrics have been proposed in the past several decades. Among all the metrics, Expected Transmission Count (ETX) has drawn the most attention. Since the proposal of ETX, many ETX-based or extended metrics have been proposed. ETX and its descendants compose the ETX family. This paper is an attempt to analyze, compare and summarize traffic-based routing metrics in the ETX family. Details of each routing metric are presented and analyzed. Some of our viewpoints on the principal for designing metrics in SONs are presented.     

国产核电厂蒸汽发生器下封头接管区模拟装置承受循环载荷能力的试验

国产核电厂蒸汽发生器下封头群孔接管区具有应力分布复杂、焊接施工条件差的特点。为考核其承受循环载荷的能力，设计制造了与实物相似的模拟试验装置，根据核电厂运行寿命期内的载荷特点，确定了模拟试验装置的试验载荷与试验循环数。循环加载试验的结果表明，蒸汽发生器下封头群孔接管区承受循环载荷的能力在寿命期内是符合要求的。     

广西田阳县生态扶贫产业核心示范区一期工程补水泵站设计

结合广西田阳县生态扶贫产业核心示范区一期工程补水泵站实际情况,通过方案比选,采用河流入江口东岸布置方案,并对泵站进行了设计介绍,总结技术特点,为类似工程提供参考。