电沉积NiHCF薄膜在碱土金属溶液中的电控离子分离性能

采用电沉积方法在铂基体上制备出电活性NiHCF(Nickel Hexacyanoferrate)薄膜,在碱土金属溶液中考察了薄膜电极对碱土金属离子的电控离子分离性能.通过循环伏安法在0.1mol·L-1Mg(NO3)2、Ca(NO3)2、Sr(NO3)2和Ba(NO3)2溶液中可逆置入和释放碱土金属离子,比较了不同溶液中NiHCF膜电极的电活性、电化学行为和离子的置入机制;在0.1mol·L-1[Mg(NO3)z Ba(NO3)2]混合溶液中结合电化学石英晶体微天平(EQCM)原位检测了不同浓度下膜电极氧化还原过程中的伏安特性曲线和频率响应,分析了薄膜对Mg/Ba离子的选择性;并通过XPS测定了氧化还原状态下NiHCF膜的化学组成及元素价态.结果表明,NiHCF膜在二价碱土金属溶液中具有可逆的离子交换行为,对Ba2 离子的选择性大于Mg2 离子,通过电控离子分离方法可以实现碱土金属离子的有效分离.     

薄壳层核壳型Ni/Pt纳米粒子的制备及电催化性能

通过胶体-化学镀法制备不同厚度薄壳层核壳型Ni/Pt纳米粒子, 采用HRTEM、EDS、XPS和XRD手段对粒子的形貌、晶型和组成进行物理表征. 采用动电位、循环伏安法对其氧电还原和甲醇电氧化活性进行测试. 实验结果表明, 核壳结构Ni/Pt纳米颗粒基本为球形, 其中Ni₁-Pt_0.067平均直径为7 nm左右, 壳层厚度约1 nm. 与Pt/C相比, 核壳型Ni/Pt纳米粒子对氧电还原和甲醇电氧化的催化活性显著提高. 在所制备的不同壳层厚度催化剂中, Ni₁-Pt_0.067/C在0.5 mol/L H₂SO₄中氧电还原的最大峰电流密度可达到143.06 mA/mg, 是相同反应条件Pt/C峰电流密度的1.4倍; 而Ni₁-Pt_0.067/C在0.5 mol/L H₂SO₄+1.0 mol/L CH₃OH溶液中甲醇电氧化峰电流密度可达538.3 mA/mg, 是Pt/C峰电流密度的5.2倍. 若以1 mg贵金属Pt为基准, Ni₁-Pt_0.067/C的比质量活性相对Pt/C的提高了30倍.     

超重力熔铸Y2O3-Al2O3-SiO2玻璃的晶化行为研究

研究了以超重力熔铸方法制备的Y₂O₃-Al₂O₃-SiO₂玻璃的晶化行为, 并结合相图分析了热处理条件对晶化过程的影响规律。实验结果表明, Y₂O₃-Al₂O₃-SiO₂玻璃的晶化行为与热处理温度和SiO₂含量密切相关。当热处理温度为1050℃时, 晶化后样品的相组成沿超重力场方向呈现出梯度分布, 自上而下分别为Al₆Si₂O₁₃玻璃陶瓷、纯玻璃相、χ-Al₂O₃玻璃陶瓷。当退火温度为1100℃时, 析出晶相主要为Y₃Al₅O₁₂及Y₂Si₂O₇; 退火温度为1200℃时主要析出Y₃Al₅O₁₂。因此, 以超重力熔铸法制备YAS玻璃结合后续热处理的工艺, 提供了一种快速制备YAS基微晶玻璃的新方法。     

Pyrene-based hypercrosslinked microporous resins for effective CO2 capture

Two hydrophobic pyrene-based hypercrosslinked microporous resins (ZLYs) with intrinsic hydroxyl groups on the pore-walls have been prepared by condensation of 1,3,6,8-tetrakis(p-formylphenyl)pyrene (TFPPy) with phloroglucinol (L₁) or 1,5-dihydroxynaphthalene (L₂). The resulting porous networks exhibited high thermal stabilities and moderate Brunauer–Emmett–Teller surface area with 647 and 243 m² g⁻¹ respectively. The experiments showed that the weak interactions between CO₂ and the intrinsic hydroxyl groups on the pore-wall of the resins could enhance CO₂ uptake and CO₂/CH₄ selectivity. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47448.     

A sensitive immunochromatographic assay using colloidal gold–antibody probe for rapid detection of fumonisin B1 in corn

A sensitive immunochromatographic assay (ICA) using a colloidal gold–antibody probe for the rapid detection of fumonisin B₁ (FB₁) in corn samples was developed. The colour density of the test line correlated with the concentration of FB₁ in the range 2–40 ng ml^–1 by the assay, and the detection limit for FB₁ was 2 ng ml^–1. The linear range for FB₁ was 50–1000 µg kg^–1, and the visual limit detection of the test was 1000 µg kg^–1 in corn samples. The ICA to detect FB₁ is sensitive, specific and rapid. Specific anti-FB₁ monoclonal antibody (mAb) and FB₁-ovalbumin (FB₁-OVA) conjugate antigen were prepared. FB₁ mAb, labelled with colloidal gold, was used as the probe on the immunochromatographic strip. FB₁-OVA and goat-anti-mouse IgG were coated onto a nitrocellulose (NC) membrane as test lines and control lines, respectively. FB₁ in samples will competitively combines the FB₁ mAb with the FB₁-OVA in an NC membrane and the results are directly observed by the colour of the detection and quality control lines. The concentrations of FB₁ mAb labelled with colloidal gold, detecting antigen and goat anti-mouse IgG, were optimised. The results indicate that the test strip is specific for FB₁, with no cross-reactivity to other toxins. The strip assay for FB₁ was simple, only needing one step without complicated assay performance and expensive equipment, and the total time for visual evaluation was less than 10 min. A survey of 24 corn samples from Hefei, China, was performed with the test strip and HPLC, and the detection results showed that the developed ICA and the HPLC were in excellent agreement. Hence, the developed ICA can be used as a method for rapid detection of FB₁ in corn samples.     

Optimization of measurement distance of (109)~Cd K XRF system for obese subjects

The precision of results obtained from the 109Cd K XRF in vivo measurement system of bone lead for obese subjects with high BMI (body mass index) was poor. The main factor affecting the precision was the distance between tibia and detector. Compared with the standard phantom, a large phantom was used to simulate the obese subject in the measurements at different distances to the detector. The counts of Compton scattering increased highly because of the tissue overlying and surrounding tibia of the obese subject. When the distance between leg and detector was too small, the instrument would produce the distorted X-ray spectra, so that the obtained data were inaccurate. In order to ensure good measurement precision and accuracy, the distance between leg and detector should be maintained at 25 mm during the counting period. Meanwhile, the dead time displayed instantly on the instrument should be controlled to around 30%.     

基于JBPM的遥感产品在线定制系统

本文将工业生产组织和办公自动化领域的工作流理念引入到遥感在线产品的定制中,提出了一种融合JBPM工作流框架的遥感产品在线定制系统设计方案．本设计方案,具有以下几点创新：为适应遥感产品在线定制系统需求,将传统JBPM的三层框架转化为五层架构;将富客户端Flex技术应用到Web可视化流程定制中,增强了客户端浏览器的兼容性;采用JBPMAPI的二次开发技术,解决了个性化流程定制工具与JBPM引擎之间的流程驱动问题;采用面向SOA体系的整体设计框架,降低了系统中各模块问的耦合性．试验系统表明,本设计方案能有效的满足用户对个性化遥感产品的在线定制需求,并高效的完成用户所需遥感产品的生产．     

Comment on “flexible protocol for quantum private query based on B92 protocol”

In a recent paper (Quantum Inf Process 13:805–813, 2014), a flexible quantum private query (QPQ) protocol based on B92 protocol is presented. Here we point out that the B92-based QPQ protocol is insecure in database security when the channel has loss, that is, the user (Alice) will know more records in Bob’s database compared with she has bought.     

国产数据库选型测评指标体系

建立国产数据库选型测评指标体系与测试内容具备重要意义. 一是针对政府、金融银行业、央企的业务IT系统提供数据库性能对比依据; 二是将不同数据库进行横评对比, 对国产数据库厂商进一步改进性能起到指导与促进作用. 本文分析了软件质量特性测试及网络安全评估标准, 提出了一种数据库选型测评指标体系模型, 该模型从性能效率、信息安全性、其它类指标3个方面建模, 并对各指标给出了通用的测试内容, 可在具体测评实践中裁减应用, 该指标体系及测试内容在5类常用国产数据库的选型测评中具备合理性和可操作性.     

C_9石油树脂加氢工艺的研究

随着石油树脂需求的不断增长，对其产品质量要求也越来越高。为了得到色相好、软化点高的石油树脂，采用适宜的催化剂在实验室进行了C9石油树脂加氢工艺的研究，得到软化点为136℃，色相（赛）＞30#的水白色氢化C9石油树脂。