Preparation and characterization of a PMMA/Ce(OH)3, Pr2O3/graphite nanosheet composite

An easy process for the synthesis of poly(methyl methacrylate)/Ce(OH)₃, Pr₂O₃/graphite nanosheet (PMMA/Ce(OH)₃, Pr₂O₃/NanoG) composite was developed. Graphite nanosheets (NanoG) were prepared by treating the expanded graphite with sonication in aqueous alcohol solution. The PMMA/Ce(OH)₃, Pr₂O₃/NanoG composites were prepared via in situ polymerization of MMA monomer in the presence of graphite nanosheets and Ce(OH)₃, Pr₂O₃ through reverse micelle template, in which the methyl methacrylate was designated as the oily phase. The composites were then dispersed with chloroform and coated on glass slides to form films. Scanning and transmission electron microscopy were used to characterize the structure and dispersion of the graphite nanosheets and the composites. The results showed that the high-aspect-ratio structure of the nanosheets played an important role in forming a conducting network in the PMMA matrix. From thermogravimetric analysis, the introduction of graphite nanosheets and inorganic nanopartices exhibited a beneficial effect on the thermal stability of PMMA.     

Thermal and mechanical properties of the polymers synthesized by the sequential polymerization of propylene and 1‐hexadecene

The block copolymer of poly(1‐hexadecene) (PHD) and polypropylene (PP) was effectively synthesized by the sequential polymerization of propylene and 1‐hexadecene by using highly isospecific TiCl₃/Cp₂Ti(CH₃)₂ (Cp = cyclopentadienyl). The block copolymers had two separate melting temperatures of constituent blocks. The modulus of PHD–PP block copolymer was enhanced as the content of sequentially polymerized PP block was increased. The elongation at break showed positive deviation at the intermediate compositions from the simple additive values of constituent homopolymers. Shape memory effect which utilizes the crystalline PHD block as a reversible phase and the crystalline PP block as a fixed structure was examined. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1709–1715, 2002; DOI 10.1002/app.10551     

宽带直流放大器的增益控制设计与研究

首先进行了方案论证与比较,分析各种方案的优点缺点,最后选择亚德诺半导体公司生产的低噪声增益可控集成运算放大器AD603和电流反馈型宽带运算放大器AD811等器件设计宽带直流放大器。输入级采用两级AD603级联,输出级设计通频带0~10MHz的带宽,通过单片机可以对放大器增益进行控制。该放大器具有频带宽、功率高、增益可调、带宽可选择等特点。此外,对提高直流放大器的各种性能指标提出了多种具体措施,在要求较高的系统中具有较强的实用性。     

Fe doping effect on EuTiO3: The magnetic properties and giant magnetocaloric effect

The magnetic properties and magnetocaloric effect for EuTi_1-xFe_xO₃ (x = 0.05, 0.1) compounds are investigated. When a part of Ti⁴⁺ions were substituted by Fe ions, the AFM ordering can be significantly changed to be FM. The EuTi_1-xFe_xO₃ (x = 0.05, 0.1) compounds exhibit a PM to FM transition with decreasing temperature and the Curie temperature is 6 K. Under the field changes of 1 T, and RC are valued to be 10.1 J/kg K and 50.2 J/kg for EuTi_0.95Fe_0.05O₃; 9.6 J/kg K and 47.7 J/kg for EuTi_0.9Fe_0.1O₃, without magnetic and thermal hysteresis. RC is almost twice as much as EuTiO₃ (27 J/kg) as substitution of Fe³⁺ ions for Ti⁴⁺ions, which may be attributed to the magnetic transition (AFM to FM). Therefore, the giant and large RC suggest the EuTi_1-xFe_xO₃ compounds are good materials for magnetic refrigerant.     

Preparation,characterization and salt-resistance of a coal based super absorbent composite

Potassium humate was extracted from brown coal.A novel super absorbent composite,poly (acrylic acid-co-acrylamide)/potassium humate (PAA-AM/KHA),was prepared by graft polymerization of acrylic acid,acrylamide and coal based potassium humate using N,N'-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator.The effects of reaction temperature,degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker,initiator and potassium humate were investigated.Salt resistance tests were also carried out.The composite prepared under optimal conditions had a potassium humate content of 10% and exhibited a water absorption of 770 g/g in distilled water,and 349,286 and 41 g/g in 0.5 mol/L KC1,MgCl2 and AlCl3 solutions respectively.The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly (acrylic acid-co-acrylamide) because of the collaborative effect of functional groups of the coal based potassium humate.The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy.Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments.The salt resisting property of the composite is improved,production costs are reduced and the growth stimulant effect is still present.     

A process study of electron beam nano-lithography and deep etching with an ICP system

A systemic process study on an electron beam nanolithography system operating at 100 kV was present. The exposure conditions were optimized for resist ZEP520A. Grating structures with line/space of 50 nm/50 nm were obtained in a reasonably thick resist which is beneficial to the subsequent pattern transfer technique. The ICP etching process conditions was optimized. The role of etching parameters such as source power, gas pressure, and gas flow rate on the etching result was also discussed. A grating structure with line widths as small as 100 nm, duty cycles of 0.5, depth of 900 nm, and the side-wall scalloping as small as 5 nm on a silicon substrate was obtained. The silicon deep etching technique for structure sizes smaller than 100 nm is very important for the fabrication of nano-optical devices working in the visible regime. Supported by the National Basic Research Program of China (“973” Program) (Grant No. 2007CB935301)     

基于3G传输网络的道路气象预警系统

利用传感技术为监测手段开发一套基于3G传输网络的道路气象预警系统,使道路管理部门精确掌握气象资料和天气预报,并根据各路段的地形及气候特点,结合路段交通状况,制定各自的应急预案,以保证道路的行车安全和顺畅。此系统对道路沿线气象状况进行监测、分析并采取有效的应急预案,对保障道路过往车辆和人身财产安全有着积极作用。     

Interfacial adhesion reaction of polyethylene and starch blends using maleated polyethylene reactive compatibilizer

The interfacial reaction of the polyethylene (PE)/starch blend system containing the reactive compatibilizer maleated polyethylene (m‐PE) was directly characterized by Fourier transform infrared (FTIR) spectroscopy. A significant amount of anhydride groups on m‐PE existed as hydrolyzed forms, resulting in a large amount of carboxyl groups. Using a vacuum‐heating‐cell designed in the laboratory, the carboxyl groups were successfully transformed into the dehydrolyzed state (i.e., anhydride group). This result enabled the direct spectroscopic observation of chemical reaction occurring at the interface. For the PE/starch blend system containing m‐PE, the chemical reaction at the interface was verified by the evolution of ester and carboxyl groups in the FTIR spectra. The effect of the reactive compatibilizer on the interfacial morphology was also examined by scanning electron micrography (SEM). Enhanced interfacial adhesion was clearly observed for the blend system containing reactive compatibilizer. Tensile strengths of blend systems containing m‐PE also increased noticeably compared with the corresponding system without compatibilizer. A similar observation was made for the breaking elongation data. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 767–776, 2002     

快充纯电动BRT运营效果评价方法

针对快充纯电动快速公交(bus rapid transit,BRT)系统的运营效果评价问题,提出基于快充纯电动公交车辆运行特性与BRT运营特点的评价方法.首先,分析快充纯电动公交车辆在BRT中的适用性,从运营车辆性能、设施水平、乘客服务水平、经济效益等角度出发,建立包含燃油车辆替换率、动力电池衰减率、充电设施供需平衡关系等9项细化指标的快充纯电动BRT运营效果评价指标体系;其次,采用灰色聚类方法,构建快充纯电动BRT运营效果评价模型;最后,以金华市国内首条纯电动BRT线路为例,进行运营效果评价.与实际运营情况调查结果对比后发现,相比传统BRT运营效果评价方法,该方法更能真实、有效地反映纯电动BRT的实际运营效果.     

一类修正的q-Baskakov算子的逼近性质

Baskakov型算子是研究函数逼近问题的一种很重要的工具。该文基于Gupta所提出的q-Baskakov算子,介绍了一类修正的q-Baskakov算子,给出了该类算子的一些基本性质,并且得到了该类算子的一致收敛定理,从而进一步推广了q-Baskakov算子的一些结论。