Top-down process based on electrospinning, twisting, and heating for producing one-dimensional carbon nanotube assembly

Multiwalled carbon nanotube (MWNT)/poly(vinyl butyral) (PVB) composite nanofibers were prepared by electrospinning, successive twisting and heat treatment. The MWNTs were highly oriented in an electrified thin jet during electrospinning. The heat treatment of the twisted electrospun nanofiber yarns produced the characteristics of the CNT in the composite nanofiber yarns and enhanced their electrical properties, mechanical properties, and thermal properties. The electrical conductivity of the heated yarn was significantly enhanced and showed the maximum value of 154 S cm(-1) for the yarn heated at 400 °C. It is an order of magnitude higher than other electrospun CNT composite materials. These results demonstrated that the novel top-down process based on electrospinning, twisting, and heat treatment provide a promising option for simple and large-scale manufacture of CNT assemblies.     

Rapid Sintering of Silica Xerogel Ceramic Derived from Sago Waste Ash Using Sub-millimeter Wave Heating with a 300 GHz CW Gyrotron

In this paper, we present and discuss experimental results from a microwave sintering of a silica-glass ceramic, produced from a silica xerogel extracted from a sago waste ash. As a radiation source for the microwave heating a sub-millimeter wave gyrotron (Gyrotron FU CW I) with an output frequency of 300 GHz has been used. The powders of silica xerogel have been dry pressed and then sintered at temperatures ranging from 300°C to 1500°C. The influence of the sintering temperature on the technological properties such as porosity and bulk density was studied in detail. Furthermore, X-ray diffraction (XRD) and Fourier Transform Infrared (FTIR) spectroscopy have been used in order to study the structure of the produced silica glass-ceramics. It has been found that the silica xerogel crystallizes at a temperature of 800°C, which is about 200°C lower than the one observed in the conventional process. The silica xerogel samples sintered by their irradiation with a sub-millimeter wave at 900°C for 18 minutes are fully crystallized into a silica glass-ceramic with a density of about 2.2 g/cm³ and cristobalite as a major crystalline phase. The results obtained in this study allow one to conclude that the microwave sintering with sub-millimeter waves is an appropriate technological process for production of silica glass-ceramics from a silica xerogel and is characterized with such advantages as shorter times of the thermal cycle, lower sintering temperatures and higher quality of the final product.     

Investigations of the interactions between synthetic antimicrobial polymers and substrate-supported lipid bilayers using sum frequency generation vibrational spectroscopy

Sum frequency generation (SFG) vibrational spectroscopy was used to analyze interactions between solid-supported lipid bilayers acting as models for cellular membranes and several membrane-active random copolymers with different lipophilic side chains, named 0R (no group), 33Me (methyl group), 11Bz (benzyl group), and 33Bu (butyl group), according to both the identity and percentage of the side chains within the polymer. Biological tests of the minimum inhibitory concentration (MIC) and hemolytic concentration were performed. The inherent surface sensitivity of SFG allowed for independent monitoring of isotopically labeled lipid bilayer leaflets as a function of concentration to study polymer-bilayer interaction mechanisms. Concentrations at which each bilayer leaflet was disrupted were quantitatively determined for each copolymer. Spectroscopic evidence of interaction with the bilayer below the critical concentrations was observed for the 11Bz polymer. The lipophilic butyl side chain of the 33Bu polymer was found to be oriented parallel to the surface normal. This research shows that SFG is a useful analytical technique which provides unique details regarding the interaction mechanisms of these membrane-active copolymers and lipid bilayers.     

Residual stresses in girth butt welded pipes and treatments to modify these

A number of Type 304 stainless steel pipes are used in the primary cooling systems of nuclear plants. Intergranular stress corrosion cracks (IGSCC) were found at some welded joints in these piping systems due to very high tensile residual stress, sensitization of the material due to welding, and corrosive environment, all occurring simultaneously. Investigations have shown that at least one of the above factors must be eliminated to prevent IGSCC.

This report describes experimental results on the temperature variations during pipe welding by conventional techniques and by the heat sink welding (HSW) technique. The mechanism of residual stress generation due to welding is also discussed. The pipe used in these experiments was 4B Sch80 Type 304 stainless steel. It was found that the temperature distribution through the thickness of the pipes was almost uniform for the conventional welding technique, but had a very sharp gradient for HSW. In the pipe axial direction, the temperatures varied sharply for both welding techniques. This implies that the sensitization of metal due to HSW is lighter than that of conventional welding and that the residual stress on the inside surface of the heat sink welded pipe is compressive.

The induction heating stress improvement (IHSI) method has been investigated analytically and experimentally. In the IHSI method, a pipe is heated with an induction coil while cold water is pumped through it. This causes a temperature gradient throughout the pipe wall which generates high thermal stresses. This, in turn, generates compressive stresses on the inner surface of the pipe. This method is designed to eliminate tensile residual stresses near the weld heat affected zone on the inner surface.

Temperature analysis and subsequent thermoelastic-plastic analysis show that tensile weld residual stresses at a joint were changed into compressive stresses on the inner surface of a pipe. It was confirmed experimentally that these stresses suppressed fatigue crack propagation in the heat affected zone (HAZ) of a welded pipe. Therefore, the IHSI method is effective not only in preventing crack initiation but also in suppressing crack propagation.

As for the relaxation of residual stresses, no significant relaxation was measured when external loads were applied at as much as 80% of the yield strength in the experiments.     

Comparison of Performances of Turbines for Wave Energy Conversion

The Wells turbine for a wave power generator is a self-rectifying air turbine that is available for an energy conversion in an oscillating water-air column without any rectifying valve. The objective of this paper is to compare the performances of the Wells turbines in which the profile of blade are NACA0020, NACA0015, CA9 and HSIM15-262123-1576 in the small-scale model testing. The running characteristics in the steady flow, the start and running characteristics in the sinusoidal flow and the hysteretic characteristics in the sinusoidal flow were investigated for four kinds of turbine. As a conclusion, the turbine in which the profile of blade is NACA0020 has the best performances among 4 turbines for the running and starting characteristics in the small-scale model testing.     

Oral administration of multispecies microbial supplements to sows influences the composition of gut microbiota and fecal organic acids in their post-weaned piglets

The timings of the administration of microbial supplements to control the populations of gut microbiota of piglets have been poorly understood. Here the effects of temporal administering multispecies microbial supplements to sows on the composition of gut microbiota and on the bacteria-mediated fecal metabolites in their offsprings were investigated. During gestation and lactation, pregnant sows were fed either a normal diet (group A) or a diet with multispecies supplements comprised of nine microbial species such as Lactobacillus delbrueckii subsp. bulgaricus, Bifidobacterium bifidum, Enterococcus faecium, Candida pintolopesii, and Aspergillus oryzae etc. (group B). All of the sows' piglets were temporarily fed with the same supplements around weaning in accordance with the guideline of the farm. This regimen was followed by a normal diet in both groups over one month thereafter. Under such conditions, the concentration of short-chain fatty acids (SCFAs) in fecal samples remarkably increased in group B compared to group A. When 16S rDNA sequences of the fecal bacteria were analyzed, the microbial structure of bacteria was different between both goups. Especially the Clostridium cluster IV and subcluster XIVa were particularly increased in group B, although the administered microbes were undetectable. Thus, temporal administration of multispecies-microbial supplements to pregnant sows changes the composition of SCFAs and gut microbiota in their offsprings.     

Suitability of TBA method for the evaluation of the oxidative effect of non-water-soluble and water-soluble rosemary extracts

The antioxidative effects of rosemary and grape-seed extracts spiked in human plasma were examined using the thiobarbituric acid (TBA) method. The TBA values of plasma spiked with reagents to generate reactive oxygen species, such as singlet oxygen ((1)O(2)), hydroxyl radicals ((·)OH), peroxynitrite (ONOO(-)), and superoxide anions (O(2)(·-)), were measured by a flow injection analysis method with fluorescence (FL) detection. TBA values obtained by the addition of 50 mg/mL of rosemary extracts for (1)O(2), (·)OH, ONOO(-), and O(2)(·-) increased to 964 ± 65%, 1063 ± 61%, 758 ± 78%, and 698 ± 41%, respectively (n = 3, P < 0.01), whereas the values with 1 mg/mL of grape-seed extracts or tocopherol decreased (40.2 - 66.3%). Furthermore, the antioxidative effects of rosemary extract in rat plasma, spiked with reagents to generate (·)OH, were examined by high-performance liquid chromatography with FL detection. No peak, other than TBA-malondialdehyde, could be detected using wavelengths of 532 (λ(ex)) and 553 nm (λ(em)).     

Novel voltage limiter for fast torque response of IPMSM in voltage saturation region

A new voltage limiter for fast torque response of IPMSM in the voltage saturation region is proposed, which we name the “maximum torque response voltage limiter.” In transient condition, the fastest response is vital while voltage saturation occurs. Thus, the problem is to divide the limited voltage into d‐ and q‐axis voltages so as to generate the fastest torque response. The nonlinear relation between the torque and the d‐q axis currents of the IPMSM makes the problem complicated. In our proposed method, both voltage equations and a torque equation of the IPMSM are considered and, based on the Lagrange optimization technique, explicit expressions for the d‐ and q‐axis voltages are derived. Compared with conventional voltage limiters such as the constant phase angle method, the constant back emf method, and the constant d‐axis voltage method, the proposed limiter yields faster torque response in the voltage saturation region, which is confirmed by computer simulation and experimental results. Furthermore, the proposed method uses simple software calculations, and it can be readily implemented without any modification of the hardware system. © 2011 Wiley Periodicals, Inc. Electr Eng Jpn, 175(4): 57–69, 2011; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.21078     

Optimal operation of a continuous DTB crystallizer

The optimal operation of a continuous crystallizer is studied by taking a real industrial scale crystallizer as an example. The objective function to be maximized is the production rate of the crystals which are larger than a certain size. Since continuous crystallizers exhibit sustained oscillation, it is important to find the optimal operation under oscillatory condition. In this study, the optimal operating condition is derived for two types of operation: one is the case where the manipulated variables are kept constant (constant input operation), and the other is the case where the values of manipulated variables are changed periodically (time varying input operation). The optimization result of time varying input operation indicates that the production rate of large crystals can be increased if the number of fine crystals in the vessel is reduced by withdrawing along with the product. Furthermore, this study examines the optimal operation of the crystallizer in the case where the sustained oscillation is eliminated by a stabilizing controller. The optimization result clearly indicates that the production rate of large crystals can be significantly increased if the operation is optimized under the condition where crystal size distribution (CSD) is stabilized.     

Ultracompact Asymmetric Mach–Zehnder Interferometers with High Visibility Constructed from Exciton Polariton Waveguides of Organic Dye Nanofibers

Manipulation of light using subwavelength waveguides is a key technology in the development of miniaturized photonic circuits, which possess various advantages over their electronic counterparts. The novel approach presented for such waveguiding involves the propagation of exciton polaritons (EPs), which are quasi‐particles formed by strong exciton–photon coupling, along organic dye nanofibers. A self‐assembled nanofiber of thiacyanine (TC) with a width of ≈200 nm propagates the EPs created by an optical excitation over a submillimeter‐scale distance and passes through a bend with a micrometer‐scale radius with low bending loss. To demonstrate the remarkable potential of EP‐based miniaturized photonic circuits, asymmetric Mach–Zehnder interferometers (AMZIs) are fabricated with TC nanofibers by micromanipulation. The AMZIs with a footprint of ≈20 μm × 20 μm exhibit a visibility of nearly unity and function as channel drop filters with the considerably high extinction ratio of up to ≈15 dB. Such high‐performance and ultracompact channel drop filters operating in the visible wavelength region have rarely been developed with other waveguide technologies. The coherent properties of the EPs in the nanofibers are investigated using time‐resolved experiments. The coherent properties provide useful information for designing EP‐based photonic circuits and for understanding EP dynamics in a nanofiber.