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21.
Dr. Daisuke Fujiwara Kousuke Mihara Ryo Takayama Yusuke Nakamura Prof. Mitsuhiro Ueda Prof. Takeshi Tsumuraya Prof. Ikuo Fujii 《Chembiochem : a European journal of chemical biology》2021,22(24):3406-3409
Conformationally constrained peptides hold promise as molecular tools in chemical biology and as a new modality in drug discovery. The construction and screening of a target-focused library could be a promising approach for the generation of de novo ligands or inhibitors against target proteins. Here, we have prepared a protein kinase-focused library by chemically modifying helix-loop-helix (HLH) peptides displayed on phage and subsequently tethered to adenosine. The library was screened against aurora kinase A (AurA). The selected HLH peptide Bip - 3 retained the α-helical structure and bound to AurA with a KD value of 13.7 μM. Bip - 3 and the adenosine-tethered peptide Bip - 3 - Adc provided IC50 values of 103 μM and 7.7 μM, respectively, suggesting that Bip - 3 - Adc bivalently inhibited AurA. In addition, the selectivity of Bip - 3 - Adc to several protein kinases was tested, and was highest against AurA. These results demonstrate that chemical modification can enable the construction of a kinase-focused library of phage-displayed HLH peptides. 相似文献
22.
Crosslinked poly(N-benzyl-4-vinyipyridinium bromide) has been found to be digested by activated sludge obtained from sewage works. As an extension of this work, the authors attempted to make poly(methyl methacrylate) biodegradable by incorporation of a pyridinium group. Poly(methyl methacrylate) containing a small amount of N-benzyl-4-vinylpyridinium chloride in the main chain showed remarkable reduction in molecular weight and gravimetric weight when placed in an aeration tank of a sewage works. Molecular weight reduction by activated sludge was more conspicuous when content of the pyridinium group was larger and the original molecular weight before the biological treatment was lower. Since insoluble pyridinium-type polymer captures microbial cells alive, this biodegradation appears to be facilitated by enhancement of affinity of the synthetic hydrophobic polymer with cells of microogranisms. © 1994 John Wiley & Sons, Inc. 相似文献
23.
New bismaleimides containing ether bonds were prepared. The thermal properties of the bismaleimides were investigated by differential scanning calorimetry (DSC). The effects of structure of the bismaleimides and curing conditions on the thermal and mechanical properties of the cured resins such as initial decomposition temperature (Td), glass transition temperature (Tg), and flexural strength were studied. The introduction of ether bonds to bismaleimide resins decreased the brittleness of the resins without reductions in their heat-resistant properties. 相似文献
24.
Masaru Takahashi Tetsu Nakatani Shinji Iwamoto Tsunenori Watanabe Masashi Inoue 《Applied catalysis. B, Environmental》2007,70(1-4):73-79
The solvothermal reaction of mixtures of aluminum isopropoxide (AIP) and gallium acetylacetonate (Ga(acac)3) directly yielded the mixed oxides of γ-Ga2O3-Al2O3. In the solvothermal synthesis, the crystal structure of mixed oxides was controlled by the initial formation of γ-Ga2O3 nuclei. The mixed oxides prepared in diethylenetriamine have extremely high activities for selective catalytic reduction (SCR) of NO with methane as a reducing agent. With increasing crystallite size of the spinel structure, the catalytic activity increased. The ratio of the amount of methane consumed by combustion to total methane conversion was proportional to the density of acid sites on the surface of the mixed oxides. The mixed oxide catalysts prepared in diethylenetriamine had lower densities of acid sites and showed a higher methane-efficiency for CH4-SCR than those prepared in other solvents. These catalysts maintained their high activity even when the reaction was carried out under the severe conditions (i.e., high space velocity and low NO concentration). 相似文献
25.
Summary Giant hybrid liposomes of polymerizable lipid and cholesterol were prepared by the hydration method and were polymerized by UV irradiation. The obtained giant liposomes were freeze-dried and washed with chloroform to skeletonize the frame structure of the polymerized membrane. The skeletonized liposomes were directly confirmed by scanning electron microscopy. The single-layered and fully spherical liposome frame were easily confirmed by the stereo-pair of the obtained micrographs. 相似文献
26.
A metric of the 3D image quality of autostereoscopic displays based on optical measurements is proposed. This metric uses each view's luminance contrast, which is defined as the ratio of maximum luminance at each viewing position to total luminance at that position. Conventional metrics of the autostereoscopic display based on crosstalk, which uses “wanted” and “unwanted” lights. However, in case of the multiple‐views‐type autostereoscopic displays, it is difficult to distinguish exactly which lights are wanted lights and which are unwanted lights. This paper assumes that the wanted light has a maximum luminance at the good stereoscopic viewing position, and the unwanted light also has a maximum luminance at the worst pseudo‐stereoscopic viewing position. By using the maximum luminance that is indexed by view number of the autostereoscopic display, the proposed method enables characterizing stereoscopic viewing conditions without using wanted/unwanted light. A 3D image quality metric called “stereo luminance contrast,” the average of both eyes' contrast, is proposed. The effectiveness of the proposed metric is confirmed by the results of optical measurement analyses of different types of autostereoscopic displays, such as the two‐view, scan‐backlight, multi‐view, and integral. 相似文献
27.
Local structure and concentration in Al-Mn alloy electrodeposits 总被引:1,自引:0,他引:1
The structures of f.c.c. crystalline and amorphous phases coexisting in Al-Mn alloy electrodeposits containing 11–30 wt% were examined by using the grazing-incidence X-ray diffraction (GIXD) method, high-resolution transmission electron microscopy combined with energy dispersive X-ray spectrometry (HRTEM/EDS), and the manganese K-edge extended X-ray absorption fine-structure (EXAFS) technique. The amorphous and f.c.c. phases were homogeneously distributed in the through-thickness direction of the electrodeposits, although the amorphous phase increased and the f.c.c. phase decreased with increasing manganese total concentration. The decrease of Mn-content in the f.c.c. crystalline phases with increasing manganese total concentration was revealed by the lattice constant measurement of the f.c.c. crystalline phase. This result was also supported by the microarea elemental analysis by HRTEM/EDS. The EXAFS result has indicated that the manganese local structures in the amorphous phases are almost identical in different manganese total concentration electrodeposits. This suggests that the Mn-content in the amorphous phases hardly changes with increasing manganese total concentration. These results have revealed that a peculiar elemental partition occurs in the amorphous and crystalline phases of Al-Mn alloy electrodeposits. 相似文献
28.
Masaru Takahashi Noriyuki Inoue Tatsuya Takeguchi Shinji Iwamoto Masashi Inoue Tsunenori Watanabe 《Journal of the American Ceramic Society》2006,89(7):2158-2166
The reaction of mixtures of aluminum isopropoxide and gallium acetylacetonate in 1,4-butanediol or 1,5-pentanediol at high temperatures (glycothermal reaction) directly gave the γ-Ga2 O3 –Al2 O3 solid solutions, which had high catalytic activities for selective reduction of NO using methane as the reducing agent. However, the reaction with a higher Al/(Ga+Al) charged ratio yielded the glycol derivative of boehmite as a by-product and the catalytic activity of the solid solution decreased. Therefore, synthesis of the solid solution using various glycols was examined and it was found that solid solutions with high Al contents without contamination of the glycol derivative of boehmite were obtained by using 1,6-hexanediol as a reaction medium. The solid solution exhibited a higher NO conversion than that synthesized in other glycols. 相似文献
29.
Toshihiko Tanaka Norio Hasegawa Hiroshi Shiraishi Shinji Okazaki 《Polymer Engineering and Science》1992,32(20):1545-1549
The multiple interference effect is one of the major causes of the fluctuation in critical dimension control (CD) and in mark detection for alignment. Suppressing this effect is critical for future photolithography. We propose a new photolithography technique called anti reflective coating on resist (ARCOR), which improves linewidth accuracy and overlay accuracy by suppressing multiple interference. ARCOR consists of relatively simple processes: A clear antireflective film is spun onto the resist prior to the mark detecting for alignment and exposure. The film is subsequently removed and the resist developed in the conventional way. ARCOR differs from ARC, which suppresses the reflection at the resist/substrate interface. ARCOR suppresses the reflection at the air/resist interface. ARCOR allows mark detection and exposure without light intensity-loss and multiple interference. The experiments mainly examine polysiloxane and perfluoroalkylpolyether as ARCOR materials. It is shown that linewidth accuracy can be improved from 0.3 to 0.03 μm. The signal-to-noise ratio of the alignment signal is drastically improved, and the overlay error is about half that of the conventional method. ARCOR is also effective for directly measuring the reflectivity at the resist/substrate interface, which is a key parameter of the multiple interference effect and the halation. Using ARCOR and a thin resist film, the measured ratio of reflected light to incident light indicates the reflectivity at the resist/substrate interface. Because, the probe light does not reflect off the resist surface and the intensity-loss at the resist surface is suppressed. With perfluoroalkylpolyether film, the measurement error is ~ 1.5%. 相似文献
30.