Pure red emission hybrid light-emitting devices based on the blend of CdSe/ZnS quantum dots and an n-type polymer

We report on hybrid light-emitting devices (HLEDs) based on CdSe/ZnS quantum dots in polymer matrices. Color purity of the HLED with a mixed matrix consisting of polyvinylcarbazole (PVK) and 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (PBD) improves with the increasing concentration of PBD. We attribute this improvement to the increased electron mobility of the matrix. By using an n-type cyano-containing polymer derived from 6-(3,6-dibromo-9H-carbazol-9-yl)hexanenitrile and tetraphenylsilane to replace PVK:PBD as the matrix, further pure red emission with Commission Internationale De L'Eclairage coordinates of (0.67, 0.33) and maximum external quantum efficiency of 2.51% has been achieved.     

三维石墨烯及其复合材料的制备及在超级电容器中的研究进展

三维(3D)石墨烯及其复合材料具有柔韧性好、比表面积大、功率密度高、力学性能稳定以及离子传输迅速等优良性能,成为材料科学领域备受关注的材料。概述了三维石墨烯材料的基本性质和性能,并对其多元复合材料的制备方法以及在超级电容器储能材料方面的应用研究进展进行了评述。三维(3D)石墨烯常用的制备方法有自组装法、模板导向法和3D打印法等,通过对制备方法进行改进,可以有效调控三维材料的多孔结构、孔径、柔韧性和电子传递速度等性能。三维(3D)石墨烯与过渡金属化合物及导电聚合物复合而成的多元复合物在超级电容器电极材料方面表现出广阔的应用前景。     

Design of an effective heat treatment involving intercritical hardening for high-strength–high elongation of 0.2C–1.5Al–(6–8.5)Mn-Fe TRIP steels: microstructural evolution and deformation behaviour

ABSTRACT

We propose an effective heat treatment involving a combination of intercritical hardening and tempering to obtain high strength–high ductility in hot-rolled 0.2C–1.5Al–(6–8.5)Mn–Fe transformation-induced plasticity (TRIP) steels. An excellent combination of high ultimate tensile strength of 1045–1380?MPa and total elongation of 34–39% was obtained when the steels were subjected to intercritical hardening at 630–650?°C and tempered at 200?°C. Intercritical hardening impacted the co-existence of austenite, ferrite and martensite, such that the deformation behaviour varied with the Mn content. The excellent properties of the steels were attributed to cumulative contribution of enhanced TRIP effect of austenite and ferrite and martensite constituents. The discontinuous TRIP e?ect during tensile deformation involves stress relaxation and led to consequent enhancement of ductility.     

阳离子丙烯酸酯共聚物表面活性剂的结构及溶液性能

通过自由基溶液共聚合法合成了无规型阳离子丙烯酸酯共聚物表面活性剂,利用红外光谱(FT-IR)和核磁共振谱(1H-NMR和13C-NMR)对聚合产物的结构和组成进行了表征,考察了浓度、温度等对聚合物丙酮溶液的增比黏度和聚合物水溶液表面张力的影响。结果表明,聚合物丙酮溶液的增比黏度随溶液浓度增加总体呈现上升趋势,在相同溶液浓度下,其增比黏度随温度升高呈先降低后升高再降低的趋势;聚合产物可将水溶液的表面张力降低到43mN/m,其临界胶束浓度为0.8 g/L;聚合物水溶液的表面张力随温升高而降低,且随溶液pH值增大而增大。     

Mesoporous silica nanoparticles as a delivery system of gadolinium for effective human stem cell tracking

The progress of using gadolinium (Gd)-based nanoparticles in cellular tracking lags behind that of superparamagnetic iron oxide (SPIO) nanoparticles in magnetic resonance imaging (MRI). Here, dual functional Gd-fluorescein isothiocyanate mesoporous silica nanoparticles (Gd-Dye@MSN) that possess green fluorescence and paramagnetism are developed in order to evaluate their potential as effective T1-enhancing trackers for human mesenchymal stem cells (hMSCs). hMSCs are labeled efficiently with Gd-Dye@MSN via endocytosis. Labeled hMSCs are unaffected in their viability, proliferation, and differentiation capacities into adipocytes, osteocytes, and chondrocytes, which can still be readily MRI detected. Imaging, with a clinical 1.5-T MRI system and a low incubation dosage of Gd, low detection cell numbers, and short incubation times is demonstrated on both loaded cells and hMSC-injected mouse brains. This study shows that the advantages of biocompatibility, durability, high internalizing efficiency, and pore architecture make MSNs an ideal vector of T1-agent for stem-cell tracking with MRI.     

芳纶纤维增韧碳纤维泡沫金属夹芯梁压缩性能及界面性能

为研究芳纶短纤维对复合材料夹芯材料/结构的界面及性能的影响,对具有芳纶短纤维增韧界面的碳纤维-泡沫铝夹芯梁进行了试验和细观增韧机制研究.在夹芯梁制备过程中,在碳纤维-泡沫铝界面加入低密度芳纶短纤维薄膜,通过短纤维的桥联作用,提高夹芯梁的界面黏接性能.研究了芳纶纤维增韧对夹芯梁面内压缩性能和破坏模态的影响,采用非对称双悬臂梁(ADCB)试验测量了不同增韧参数条件下,碳纤维表板与泡沫铝芯体之间的临界能量释放率.试验结果显示:在相同增韧参数条件下,Kevlar纤维增韧夹芯梁的面内压缩性能和界面临界能量释放率均较好,而混杂长度Kevlar纤维的界面增韧效果最优.通过对试件断面的SEM观测,分析了芳纶纤维增韧的细观增韧机制.     

低热膨胀聚(苯并噁唑-酰亚胺)薄膜与铜黏结性能EI北大核心CSCD

采用氧等离子体活化聚(苯并噁唑-酰亚胺)(PI)薄膜,以此为基底,通过离子注入和化学电镀铜工艺制备高黏结性、耐锡焊性的无胶柔性单面覆铜板(FCCL)。控制气流压强,研究处理功率、处理时间对薄膜表面结构、化学成分及其与Cu层黏结性能的影响。结果表明:氧等离子体改性对改善PI薄膜黏结性能有重要影响,控制压强30 Pa,处理功率100 W,时间10 min,表面引入含氧极性基团,蚀刻明显,使薄膜的浸润性增强;PI薄膜与铜离子形成络合物,进一步赋予FCCL优良的黏结性能,其剥离强度比现有FCCL提高60%以上。     

Structure design of reinforced honeycomb paperboard core and characterization of its out‐of‐plane bearing strength

Honeycomb paperboard's out‐of‐plane bearing performance is one of the important properties in packaging field application. Further improvement of its bearing performance has important value in engineering practice. In this paper, a honeycomb core structure was designed, and the bonding dimension and manufacturing process were designed. The mechanism of out‐of‐plane quasi‐static compression deformation of reinforced honeycomb paperboard was analyzed by experiments. The theoretical model of out‐of‐plane platform stress was constructed by applying the plastic deformation, plastic energy dissipation and energy conservation theory. The results show that the improved structure can be mechanically bonded in a flat state with less technological changes. Under the same honeycomb core material and core size parameters, the bearing strength of the improved structure increases by an average of 3.9 times to conventional structure. In order to meet the same compressive strength requirement, the improved structure can reduce the performance requirements of honeycomb core material or increase the core size compared with the conventional structure. When the honeycomb core cell is larger, the tension on the core layer required for the production process is reduced. The theoretical and experimental data are in good agreement with each other, and the relative errors are all less than 13%.     

分布式测试系统时间同步技术的研究

分布式测试系统是集计算机控制技术、网络通信技术与多传感器信息融合技术于一体的复杂测控系统;与独立测试系统不同,在网络化分布式测试系统中,各测试装置需按通信协议与网关节点通信以完成相应的测试;不同测试装置在接收网关节点发出的信号时,由于传输距离不同会引起时延差;如果系统中的各个测试装置不具备统一的时间基准,那么得到的测试数据因为时钟差异将无法反映出信息的真实情况;因此,整个网络中所有测试装置需要保持时间同步;针对分布式测试系统时间同步的需求,对信号传输过程中的时延问题进行了研究,提出了一种基于FPGA的时延测量方法,对这种软硬件结合时延测量方法的实现原理进行了详细阐述,并进行了功能仿真及试验验证。     

Single‐Component TiO2 Tubular Microengines with Motion Controlled by Light‐Induced Bubbles

In this work, light‐controlled bubble‐propelled single‐component metal oxide tubular microengines have for the first time been demonstrated. For such a simple single‐component TiO₂ tubular microengine in H₂O₂ aqueous solution under UV irradiation, when the inner diameter and length of the tube are regulated, the O₂ molecules will nucleate and grow into bubbles preferentially on the inner concave surface rather than on the outer surface, resulting in a vital propulsion of the microengine. More importantly, the motion state and speed can be modulated reversibly, fast (the response time is less than 0.2 s) and wirelessly by adjusting UV irradiation. Consequently, the as‐developed TiO₂ tubular microengine promises potential challenged applications related to photocatalysis, such as “on‐the‐fly” photocatalytic degradation of organic pollutes and photocatalytic inactivation of bacteria due to the low cost, single component, and simple structure, as well as the facile fabrication in a large‐scale.