In previous studies, we reported the linear and nonlinear rheological properties of three‐component composites consisting of acrylic polymer (AP), epoxy resin (EP), and various SiO
2 contents (AP/EP/SiO
2) in the molten state. In this study, the dynamic mechanical properties of AP/EP/SiO
2 composites with different particle sizes (0.5 and 8 μm) were investigated in the glass‐transition region. The EP consisted of three kinds of EP components. The α relaxation due to the glass transition shifted to a higher temperature with an increase in the volume fraction (?) for the AP/EP/SiO
2 composites having a particle size of 0.5 μm, but the α relaxation scarcely shifted for the composite having a particle size of 8 μm as a general result. This result suggested that the SiO
2 nanoparticles that were 0.5 μm in size adsorbed a lot of the low‐glass‐transition‐temperature (
Tg) component because of their large surface area. The AP/SiO
2 composites did not exhibit a shift in
Tg; this indicated that the composite did not adsorb any component. The modulus in the glassy state (
E′
g) exhibited a very weak &phis; dependence for the AP/EP/SiO
2 composites having particle sizes of 0.5 and 8 μm, although
E′
g of the AP/SiO
2 composites increased with &phis;. The AP/EP/SiO
2 composites exhibited a peculiar dynamic mechanical behavior, although the AP/SiO
2 composites showed the behavior of general two‐component composites. Scanning electron microscopic observations indicated that some components in the EP were adsorbed on the surface of the SiO
2 particles. We concluded that the peculiar behavior of the AP/EP/SiO
2 composites was due to the selective adsorption of the EP component. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 ,
131, 40409.
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