Influence of the degree of crosslinking on the stringiness of crosslinked polyacrylic pressure‐sensitive adhesives

The stringiness of crosslinked polyacrylic pressure‐sensitive adhesive (PSA) was observed during 90° peeling under the constant peel load. The random copolymer of butyl acrylate with 5 wt % acrylic acid crosslinked by N,N,N′,N′‐tetraglycidyl‐m‐xylenediamine was used as PSA. All observed stringiness upon peeling was sawtooth‐shaped, but it could be classified into three types dependent on the degree of crosslinking. The typical sawtooth‐shaped stringiness with interfacial failure was observed at the relatively higher crosslinker content ranging from 0.008 to 0.016 chemical equivalents (Eq.), where the PSA has high cohesive strength and low interfacial adhesion. The frame formed at the front end of stringiness at the content ranging from 0.002 to 0.004 Eq. Sufficient interfacial adhesion and deformability generate large internal deformation of the PSA layer. Internal deformation occurred preferentially over peeling as a result of front frame formation. The mode of peeling was changed from cohesive failure to interfacial failure in this range of crosslinker content. The sawtooth‐shaped with cohesive failure was observed at the lower content ranging from 0 to 0.001 Eq. The PSA has high interfacial adhesion and low cohesive strength, and thus exhibited cohesive failure. The PSA after peeling remained in the shape of belts. It was found that the shape of stringiness is strongly dependent on the balance between the interfacial adhesion and the cohesive strength of PSA. When the sawtooth‐shaped stringiness with frame formed, the peeling rate was lowest. This means the peel strength should be the maximum in this shape of stringiness. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40336.     

From topological gels to slide‐ring materials

A novel type of gel, called a topological gel, has been recently developed with a supramolecular architecture with topological characteristics. In the topological gel, polymer chains with bulky end groups are neither covalently crosslinked as in chemical gels nor attractively interacting as in physical gels but are topologically interlocked by figure‐eight shaped crosslinks. Hence, these crosslinks can pass along the polymer chains freely to equalize the tension of the threading polymer chains similarly to pulleys; this is called the pulley effect. This concept can be applied not only to gels but also to a wide variety of polymeric materials without solvents. Then, polymeric materials with movable crosslinks are referred to as slide‐ring materials (SRMs) in a wider sense. Here, we review the synthesis, structure, physical properties, and applications of topological gels and SRMs. In particular, slide‐ring elastomers show remarkable scratch‐proof properties for application to coating materials for automobiles, cell phones, mobile computers, golf clubs, and so on. © 2014 The Authors Journal of Applied Polymer Science Published by Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40509.     

Formal Nucleophilic Boryl Substitution of Organic Halides with Silylborane/Alkoxy Base System

Boryl substitution of organohalides with a silylborane and alkoxy bases is described. This reaction can be applied to various functionalized aryl halides. Alkyl and alkenyl halides, and even sterically congested aryl bromides also provided the corresponding borylated products in high yields. Mechanistic studies indicated that neither trace transition-metal impurities nor aryl radical species involved in this reaction.     

巴塞罗那费拉Porta Fira双子塔

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Zeolite synthesis from paper sludge ash at low temperature (90 degrees C) with addition of diatomite

Paper sludge ash was partially converted into zeolites by reaction with 3M NaOH solution at 90 degrees C for 24 h. The paper sludge ash had a low abundance of Si and significant Ca content, due to the presence of calcite that was used as a paper filler. Diatomite was added to the NaOH solution to increase its Si content in order to synthesize zeolites with high cation exchange capacity. Diatomite residue was filtered from solution before addition of ash. The original ash without addition of diatomite yielded hydroxysodalite with a cation exchange capacity ca. 50 cmol/kg. Addition of Si to the solution yielded Na-P1 (zeolite-P) with a higher cation exchange capacity (ca. 130 cmol/kg). The observed concentrations of Si and Al in the solution during the reaction explain the crystallization of these two phases. The reaction products were tested for their capacity for PO(4)(3-) removal from solution as a function of Ca(2+) content, suggesting the formation of an insoluble Ca-phosphate salt. The product with Na-P1 exhibits the ability to remove NH(4)(+) as well as PO(4)(3-) from solution in concentrations sufficient for application in water purification. Both NH(4)(+) and PO(4)(3-) removal showed little variation with pH between 5 and 9. Alternative processing methods of zeolite synthesis, including the addition of ash to an unfiltered Si-NaOH solution and addition of a dry ash/diatomite mixture to NaOH solution, were tested. The third process yielded materials with lower cation exchange capacity due to formation of hydroxysodalite. The second process results in a product with relatively high cation exchange capacity, and reduces the number of processing steps necessary for zeolite synthesis.     

Performance of expression vector, pTD1, in insect cell-free translation system

We constructed a pTD1 vector for an insect cell-free translation system containing a 5' untranslated region (UTR) of a polyhedrin gene as a translational enhancer sequence. Its translational efficiency was about 50-fold higher than those of mRNAs without an enhancer sequence. Moreover, the pTD1 vector functioned as an effective expression vector not only in the insect cell-free translation system but also in wheat germ extract and rabbit reticulocyte lysate systems.     

Membership problems for data dependencies in relational expressions

In relational databases, a query can be formulated in terms of a relational algebra expression using projection, selection, restriction, cross product and union. In this paper, we consider a problem, called the membership problem, of determining whether a given dependency d is valid in a given relational expression E over a given database scheme R that is, whether every instance of the view scheme defined by E satisfies d (assuming that the underlying constraints in R are always satisfied).Consider the case where each relation scheme in R is associated with functional dependencies (FDs) as constraints, and d is an FD. Then the complement of the membership problem is NP-complete. However, if E contains no union, then the membership problem can be solved in polynomial time. Furthermore, if E contains neither a union nor a projection, then we can construct in polynomial time a cover for valid FDs in E, that is, a set of FDs which implies every valid FD in E.Consider the case where each relation scheme in R is associated with multivalued dependencies (MVDs) as well as FDs, and d is an FD or an MVD. Even if E consists of selections and cross products only, the membership problem is NP-hard. However, if E contains no union, and each relation scheme name in R occurs in E at most once, then the membership problem can be solved in polynomial time. As a corollary of this result, it can be determined in polynomial time whether a given FD or MVD is valid in $\text{R}{}_1\text{???R}{}_{\mathrm{s}}$, where R₁,…,R_s are relation schemes with FDs and MVDs, and $\text{R}{}_{\mathrm{i}}\text{?R}{}_{\mathrm{j}}$ is the natural join of R_i and R_j.     

Point cloud data map creation from factory design drawing for LiDAR localization of an autonomous mobile robot

Artificial Life and Robotics - When using an autonomous mobile robot, an environmental map should be created in advance. In this study, we propose a method for creating a point cloud data (PCD) map...     

CMAS degradation of ytterbium aluminum garnets

The degradation of ytterbium aluminum garnet (YbAG) exposed to molten Ca–Mg–Fe–Al–Si–O (CMAS) at 1673 K was investigated for two kinds of dense polycrystalline YbAG with compositions deviating slightly from stoichiometry, referred to as Al- and Yb-rich. The mitigation of the CMAS attack for Yb-rich YbAG was markedly superior to that for the Al-rich one. For both types of YbAG, corrosion progressed due to the preferential penetration of the CMAS melt along grain boundaries in the thickness direction and the simultaneous dissolution of crystal grains into the melt. The lower of the corroded region consisted of YbAG crystals with a core/shell-I/shell-II structure. Shell-I contained alkaline earth, silicon, and iron cations, whereas these cations were hardly detected in shell-II. Growth of the shell-I region was considered to progress by dissolution and reprecipitation through the melt existing around it, and finally, the melt disappeared, resulting in the formation of a thin shell-II region containing little of these ions. The formation and growth of the shell-I region were found to be promoted by making the YbAG Yb-rich, resulting in enhancement of the resistance to CMAS.