全文获取类型
收费全文 | 182877篇 |
免费 | 16927篇 |
国内免费 | 8726篇 |
专业分类
电工技术 | 11726篇 |
技术理论 | 13篇 |
综合类 | 12031篇 |
化学工业 | 29836篇 |
金属工艺 | 10141篇 |
机械仪表 | 11521篇 |
建筑科学 | 14001篇 |
矿业工程 | 5546篇 |
能源动力 | 5388篇 |
轻工业 | 13013篇 |
水利工程 | 3372篇 |
石油天然气 | 10844篇 |
武器工业 | 1485篇 |
无线电 | 22088篇 |
一般工业技术 | 21968篇 |
冶金工业 | 8899篇 |
原子能技术 | 1977篇 |
自动化技术 | 24681篇 |
出版年
2024年 | 965篇 |
2023年 | 3605篇 |
2022年 | 6674篇 |
2021年 | 8889篇 |
2020年 | 6716篇 |
2019年 | 5272篇 |
2018年 | 5953篇 |
2017年 | 6659篇 |
2016年 | 5875篇 |
2015年 | 7844篇 |
2014年 | 9672篇 |
2013年 | 11560篇 |
2012年 | 12566篇 |
2011年 | 13154篇 |
2010年 | 11263篇 |
2009年 | 10620篇 |
2008年 | 10132篇 |
2007年 | 9323篇 |
2006年 | 9451篇 |
2005年 | 8065篇 |
2004年 | 5386篇 |
2003年 | 4518篇 |
2002年 | 4067篇 |
2001年 | 3652篇 |
2000年 | 3572篇 |
1999年 | 4168篇 |
1998年 | 3463篇 |
1997年 | 2940篇 |
1996年 | 2753篇 |
1995年 | 2219篇 |
1994年 | 1810篇 |
1993年 | 1302篇 |
1992年 | 1045篇 |
1991年 | 791篇 |
1990年 | 573篇 |
1989年 | 466篇 |
1988年 | 367篇 |
1987年 | 254篇 |
1986年 | 209篇 |
1985年 | 130篇 |
1984年 | 117篇 |
1983年 | 86篇 |
1982年 | 88篇 |
1981年 | 69篇 |
1980年 | 63篇 |
1979年 | 31篇 |
1978年 | 25篇 |
1977年 | 24篇 |
1976年 | 26篇 |
1975年 | 16篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
Catalysis Letters - Inspired by the discovery of the special structures of Ti-doped boron nitride fullerenes [(2019) Nat Commun 10: 4908], we herein present a computational investigation of... 相似文献
92.
Xi Chen Zhengkun Yu Chen Yang Yao Chen Chao Jin Yuejiao Ding Wenbin Li Zhongmin Wan 《International Journal of Hydrogen Energy》2021,46(19):11127-11139
Flow field structure can largely determine the output performance of Polymer electrolyte membrane fuel cell. Excellent channel configuration accelerates electrochemical reactions in the catalytic layer, effectively avoiding flooding on the cathode side. In present study, a three-dimensional, multi-phase model of PEMFC with a 3D wave flow channel is established. CFD method is applied to optimize the geometry constructions of three-dimensional wave flow channels. The results reveal that 3D wave flow channel is overall better than straight channel in promoting reactant gases transport, removing liquid water accumulated in microporous layer and avoiding thermal stress concentration in the membrane. Moreover, results show the optimal flow channel minimum depth and wave length of the 3D wave flow channel are 0.45 mm and 2 mm, respectively. Due to the periodic geometric characteristics of the wave channel, the convective mass transfer is introduced, improving gas flow rate in through-plane direction. Furthermore, when the cell output voltage is 0.4 V, the current density in the novel channel is 23.8% higher than that of conventional channel. 相似文献
93.
Yilin Yang Siddarth K. Achar John R. Kitchin 《American Institute of Chemical Engineers》2022,68(6):e17653
The degree of rate control (DRC) quantitatively identifies the kinetically relevant (sometimes known as rate-limiting) steps of a complex reaction network. This concept relies on derivatives which are commonly implemented numerically, for example, with finite differences (FDs). Numerical derivatives are tedious to implement, and can be problematic, and unstable or unreliable. In this study, we demonstrate the use of automatic differentiation (AD) in the evaluation of the DRC. AD libraries are increasingly available through modern machine learning frameworks. Compared with the FDs, AD provides solutions with higher accuracy with lower computational cost. We demonstrate applications in steady-state and transient kinetics. Furthermore, we illustrate a hybrid local-global sensitivity analysis method, the distributed evaluation of local sensitivity analysis, to assess the importance of kinetic parameters over an uncertain space. This method also benefits from AD to obtain high-quality results efficiently. 相似文献
94.
Weiguo Cao Wenjuan Li Liang Zhang Jianfa Chen Shuo Yu Zhuanghong Zhou Yun Zhang Xiaobo Shen Yingxin Tan 《International Journal of Hydrogen Energy》2021,46(52):26693-26707
The explosion venting duct can effectively reduce the hazard degree of a gas explosion and conduct the venting energy to the safe area. To investigate the flame quantitative propagation law of explosion venting with a duct, the effects of hydrogen fraction and explosion venting duct length on jet flame propagation characteristics of premixed H2-air mixtures were analyzed through experiment and simulation. The experiment results under initial conditions of room temperature and 1 atm show that when hydrogen fraction was high enough, part of the unburned hydrogen was mixed with air again to reach an ignitable concentration, resulting in the secondary combustion was easier produced and the duration of the secondary flame increased. With the increase of venting duct length, the flame front distance and propagation velocity increased. Meanwhile, the spatial distribution of pressure field and temperature field, and the propagation process and mechanism of the flame venting with a duct were analyzed using FLUENT software. The variation of the pressure wave and the pressure reflection oscillation law in the explosion venting duct was captured. Therefore, in the industrial explosion venting design with a duct, the hazard caused by the coupling of venting pressure and venting flame under different fractions should be considered comprehensively. 相似文献
95.
Mengting Ma Zijun Li Feng Yang Huaixiang Wu Wuyang Huang Zhongquan Sui Harold Corke 《International Journal of Food Science & Technology》2021,56(7):3607-3617
Waxy, normal and high-amylose maize starches were subjected to heat-moisture treatment (HMT) and then added to wheat flour (WF) in different ratios (1%, 5% and 10%). The properties of blends and their cooked noodles were studied to investigate the effects of HMT starches. The incorporation of HMT starch in WF led to an increase in swelling power, peak viscosity and breakdown and to a decrease in setback, thus inhibiting retrogradation, hence enhancing resultant noodle softness. Compared to the same addition ratio of native starch to WF, HMT starch led to higher tensile strength and extensibility in resultant noodles. WF with added HMT starch had higher resistant starch than with native starch. This study showed that addition of HMT maize starch has potential to bring nutritional benefits. However, it is necessary to select the proper blending ratio and amylose content of starch to add, in consideration of its effect on noodle quality. 相似文献
96.
Wei-Fei Hu Shuo Chen Hong-Chao Hao Hong Jiang 《American Institute of Chemical Engineers》2022,68(11):e17879
Herein, we propose a novel method to enhance the photoreactivity of an MOF catalyst by grafting isocyanate bonds ( NCO) and sulfhydryl-complexed copper ( SCu) onto ZIF-8 (NIF-SCu). The grafting process intercalated interlayer bands between the conduction and valence bands of ZIF-8, thereby providing a “ladder” for facile electron transition. The extreme improvement in the photoreactivity of NIF-SCu could be attributed to the enhancement in light responses in the range of 350–450 nm by NCO groups and the widening of the visible light range of the MOF by SCu groups. The formation of staggered energy levels in NIF-SCu could also narrow the band gap, lower the resistance, and facilitate the transfer of photogenerated carriers, thereby generating electrons with strong reduction potential in the SCu conduction band. This study provides a new strategy for improving or even endowing the photoactivity of environmental functional materials with wide bandgaps. 相似文献
97.
Wenjia Jing Baoqiang Hou Jinxiao Wang Qiang Zhi Jianfeng Yang Bo Wang 《Journal of the American Ceramic Society》2022,105(5):3141-3146
Photocatalysts often show excellent performances on the basis of their surface state of exposed faces with high reactivity, but unfortunately surfaces of this type are usually concealed into the interior of crystals for their high surface energy. We report here a possibility that for fluorine-terminated surfaces of monoclinic ZrO2, these higher-energy surfaces could be retained and exposed. Urchin-like ZrO2 hollow microspheres (UZHS) composed of nanoribbons with exposed (010) facets are obtained through a fluoride mediately solvothermal method. We prove the stabilization effect of fluorine adsorption on (010) facets by density functional theory calculations. More interestingly, UZHS exhibit tunable photocatalytic selectivity in dye degradation. The fluorinated UZHS exhibit good performances both on decomposing Congo red (CR) and methylene blue, while the surface-modified UZHS by calcination only favor decomposition of CR. 相似文献
98.
Donghai Xu Peng Feng Yang Wang Wanpeng Yang Yu Wang Shaoyan Sun 《American Institute of Chemical Engineers》2022,68(2):e17472
Corrosion and salt deposition problems severely restrict the industrialization of supercritical water oxidation. Transpiring wall reactor can effectively weaken these two problems by a protective water film. In this work, methanol was selected as organic matter, and the influences of vital structural parameters on water film properties and organic matter removal were studied via numerical simulation. The results indicate that higher than 99% of methanol conversion could be obtained and hardly affected by transpiration water layer, transpiring wall porosity and inner diameter. Increasing layer and porosity reduced reactor center temperature, but inner diameter's influence was lower relatively. Water film temperature reduced but coverage rate raised as layer, porosity, and inner diameter increased. Notably, the whole reactor was in supercritical state and coverage rate was only approximately 85% in the case of one layer. Increasing reactor length affected slightly the volume of the upper supercritical zone but enlarged the subcritical zone. 相似文献
99.
性能效率是APP软件的重要质量属性,但目前缺乏APP软件性能效率的通用模型。分析了APP软件的性能特征,基于ISO/IEC 25010标准提出了APP软件的性能效率模型,定义了APP软件性能效率的子特性和度量指标。基于提出的APP软件性能效率模型,通过实验对APP软件的性能效率进行了度量及相关分析。 相似文献
100.