π‐Conjugated Molecules Crosslinked Graphene‐Based Ultrathin Films and Their Tunable Performances in Organic Nanoelectronics

Graphene‐based ultrathin films with tunable performances, controlled thickness, and high stability are crucial for their uses. The currently existing protocols, however, could hardly simultaneously meet these requirements. Using amino‐substituted π‐conjugated compounds, including 1,4‐diaminobenzene (DABNH2), benzidine (BZDNH2), and 5,10,15,20‐tetrakis (4‐aminophenyl)‐21H,23H‐porphine (TPPNH2), as cross‐linkages, a new protocol through which graphene oxide (GO) nanosheets can be anchored on solid supports with a high stability and controlled thickness via a layer‐by‐layer method is presented. A thermal annealing leads to the reduction of the films, and the qualities of the samples can be inherited by the as‐produced reduced GO films (RGO). When RGO films are integrated as source/drain electrodes in OFETs, tunable performances can be realized. The devices based on the BZDNH2‐crosslinked RGO electrodes exhibit similar electrical behaviors as those based on the non‐π‐conjugated compound crosslinked electrodes, while improved performances can be gained when those crosslinked by DABNH2 are used. The performances can be further improved when RGO films crosslinked by TPPNH2 are employed. This work likely paves a new avenue for graphene‐based films of tunable performances, controlled thickness, and high stability.     

Effects of environmental uncertainty on organizational intention to adopt distributed work arrangements

Uncertainty in the external environmental context has been shown to affect organizational change and innovation. Distributed work arrangement is an organizational innovation that has the potential to enable a firm to meet the challenges of an uncertain environment more effectively. With the emergence of virtual organizations, such work arrangements are likely to gain increasing popularity. This exploratory empirical study employs a structural model to examine how environmental uncertainty affects organizational predisposition (adoption intention) toward distributed work arrangements. Environmental uncertainty has two different dimensions: environmental complexity (heterogeneity) and environmental variability (dynamism). In this paper, environmental dimensions are modeled to influence adoption of distributed work arrangements through shaping the organizational perceptions of three innovation characteristics: perceived relative advantage, compatibility and complexity. Data analyses using partial least squares statistical technique revealed that environmental complexity is negatively associated with perceived relative advantage, and perceived compatibility. Perceived relative advantage and perceived compatibility are in turn positively related to adoption intention for distributed work arrangements. However, environmental variability has no significant effect on the three innovation characteristics. Contrary to past findings that suggest organizations are more predisposed toward innovations in a complex environment, our study found that organizations in an environment of lower, rather than higher complexity are more likely to adopt distributed work arrangements. Implications for organizations are discussed.     

Efficient visualization of large routing topologies

As the Internet grows in size and complexity, network managers face a significant challenge in trying to understand the behaviour of routing protocols in large networks. In this paper, we present a tool called VLNT (visualizing large network topologies), which helps network managers to analyse complex routing topologies. A key contribution of our system is a novel hybrid layout algorithm, which significantly reduces the computation time required to layout large network topologies in comparison to conventional layout approaches. In addition our algorithm includes a novel termination criterion that avoids unnecessary iterations when optimizing the network layout. We demonstrate how the visualization features of VLNT can be used to analyse and improve BGP routing topologies, and provide examples using real‐life routing data. Copyright © 2004 John Wiley & Sons, Ltd.     

61单元分立式压电变形反射镜的研制

用于校正波前误差的61单元分立式压电变形反射镜是61单元自适应光学系统（AO）的关键器件之一。由于系统对单元数（61单元）和变形量（±3μm）的要求超过以往曾研制的变形镜，对研制工作带来许多困难。我们从理论分析到工艺研究采取措施，使研制的变形镜成功用于AO系统实验。     

Entwurf nichtrekursiver Digitalfilter mit beliebigen Betrags- und Phasengängen

This paper presents an efficient multiple exchange algorithm for the frequency domain design of digital FIR filters with arbitrary magnitude and phase responses. The designed filters minimize theL ₂ norm of the weighted complex frequency domain error function subject to constraints on the resulting magnitude and phase errors. This general design criterion allows for an arbitrary trade-off between complexL ₂ approximation and Chebyshev approximation of given magnitude and phase responses. The optimization can be carried out by iteratively solving small quadratic programs. These linearly constrained subproblems can be solved using robust standard software.     

从上海市民的居住生活习惯看能源消耗特征

通过对上海市314户居民进行问卷调查,根据当地居民的居住条件、生活习惯和家用电器使用情况,分析能源消费特征。在此基础上分析了居民能源使用结构和能源消费观念,为相关部门进行能源规划和政策调整提供参考依据。     

PLC课程体系的多层次实验结构的研究

因为可编程控制器PLC课程具有自动控制、计算机和网络技术相结合的特色,本文以PLC为核心,从控制系统的知识结构出发,构建了一个PLC、组态技术和工业控制网络交互的多模式、多层次的实验系统,使学生达到知识与能力的有机统一。该研究与实践为推动自动化专业创新教育,培养具有综合素质和全面发展的应用型高级工程技术人才起到一个重要的作用。     

Protocol-aided channel equalization in wireless ATM

We study the equalization problem in time division multiple access wireless asynchronous transfer mode (ATM) systems. Aiming at minimizing the overhead associated with equalization, we propose a protocol-aided channel equalization (PACE) approach for wireless ATM. Specifically, the medium access control (MAC) and data link control (DLC) protocols are exploited to provide known ATM cell headers to the receiver at the base station. A blind channel estimation-decision feedback equalizer (BCE-DFE) algorithm is developed for uplink data transmissions. There are two advantages of the BCE-DFE algorithm: the elimination of training symbols for uplink data bursts and the removal of channel estimation error propagation suffered by conventional block equalization schemes. Simulation results show the BCE-DFE has a robust performance for wireless ATM uplink data transmissions over fast time-varying channels     

Nanoporous Surface High-Entropy Alloys as Highly Efficient Multisite Electrocatalysts for Nonacidic Hydrogen Evolution Reaction

Electrocatalytic hydrogen evolution in alkaline and neutral media offers the possibility of adopting platinum-free electrocatalysts for large-scale electrochemical production of pure hydrogen fuel, but most state-of-the-art electrocatalytic materials based on nonprecious transition metals operate at high overpotentials. Here, a monolithic nanoporous multielemental CuAlNiMoFe electrode with electroactive high-entropy CuNiMoFe surface is reported to hold great promise as cost-effective electrocatalyst for hydrogen evolution reaction (HER) in alkaline and neutral media. By virtue of a surface high-entropy alloy composed of dissimilar Cu, Ni, Mo, and Fe metals offering bifunctional electrocatalytic sites with enhanced kinetics for water dissociation and adsorption/desorption of reactive hydrogen intermediates, and hierarchical nanoporous Cu scaffold facilitating electron transfer/mass transport, the nanoporous CuAlNiMoFe electrode exhibits superior nonacidic HER electrocatalysis. It only takes overpotentials as low as ≈240 and ≈183 mV to reach current densities of ≈1840 and ≈100 mA cm⁻² in 1 m  KOH and pH 7 buffer electrolytes, respectively; ≈46- and ≈14-fold higher than those of ternary CuAlNi electrode with bimetallic Cu–Ni surface alloy. The outstanding electrocatalytic properties make nonprecious multielemental alloys attractive candidates as high-performance nonacidic HER electrocatalytic electrodes in water electrolysis.     

High-Gain Chemically Gated Organic Electrochemical Transistor

Organic electrochemical transistors (OECTs) have exhibited promising performance as transducers and amplifiers of low potentials due to their exceptional transconductance, enabled by the volumetric charging of organic mixed ionic/electronic conductors (OMIECs) employed as the channel material. OECT performance in aqueous electrolytes as well as the OMIECs’ redox activity has spurred a myriad of studies employing OECTs as chemical transducers. However, the OECT's large (potentiometrically derived) transconductance is not fully leveraged in common approaches that directly conduct chemical reactions amperometrically within the OECT electrolyte with direct charge transfer between the analyte and the OMIEC, which results in sub-unity transduction of gate to drain current. Hence, amperometric OECTs do not truly display current gains in the traditional sense, falling short of the expected transistor performance. This study demonstrates an alternative device architecture that separates chemical transduction and amplification processes on two different electrochemical cells. This approach fully utilizes the OECT's large transconductance to achieve current gains of 10³ and current modulations of four orders of magnitude. This transduction mechanism represents a general approach enabling high-gain chemical OECT transducers.