The interplay of electronic structure,molecular orientation and charge transport in organic semiconductors: Poly(thiophene) and poly(bithiophene)

Ultrathin films of poly(thiophene) (PT) and poly(bithiophene) (PBT) were prepared by electrochemical route using ionic liquid (BFEE) as medium and electrolyte. Distinct morphologies and electrical properties were observed in these materials. To evaluate its response in photovoltaics, these films were used as active layer in bilayer geometry solar cells with the electron acceptor molecule C₆₀. The best performance was observed for PT films. In order to probe the differences in molecular dynamics and structural order, ultrafast electron dynamics in the low-femtosecond regime was evaluated by resonant Auger spectroscopy using the core–hole clock method at the sulfur K absorption edge. Electron delocalization times for the different polymeric films were derived as a function of the excitation energy. Photoabsorption measurements were conducted and molecular orientation derived. These results corroborated with the morphology found for these films and thus the performance of PT and PBT in the devices, and with the proposed conduction mechanism.     

Energy Management Fuzzy Logic Supervisory for Electric Vehicle Power Supplies System

This paper introduces an energy management strategy based on fuzzy logic supervisory for road electric vehicle, combining a fuel cell power source and two energy storage devices, i.e., batteries and ultracapacitors. The control strategy is designed to achieve the high-efficiency operation region of the individual power source and to regulate current and voltage at peak and average power demand, without compromising the performance and efficiency of the overall system. A multiple-input power electronic converter makes the interface among generator, energy storage devices, and the voltage dc-link bus. Classical regulators implement the control loops of each input of the converter. The supervisory system coordinates the power flows among the power sources and the load. The paper is mainly focused on the fuzzy logic supervisory for energy management of a specific power electronic converter control algorithm. Nevertheless, the proposed system can be easily adapted to other converters arrangements or to distributed generation applications. Simulation and experimental results on a 3-kW prototype prove that the fuzzy logic is a suitable energy management control strategy.     

Control of the single-phase three-leg AC/AC converter

This paper investigates the control of a single-phase three-leg ac/ac reversible converter in which a leg is shared by both the grid and the load side. Pulsewidth-modulation (PWM) techniques based on scalar and vector approaches are developed, introducing the concept of local and general apportioning factor and, also, a complete equivalence between scalar and space vector PWM. A hysteresis current controller capable of taking into account the shared leg is developed and a zero current error linear controller is presented. Furthermore, a control strategy to obtain maximum utilization of the dc-bus voltage is proposed. In addition, several relevant characteristics of the converter are addressed, such as voltage rating, harmonic distortion, shared leg and capacitor currents, and power rating. The converter is compared to four-leg and two-leg converters. Experimental results are presented.     

Constant-frequency sliding-mode and PI linear controllers for powerrectifiers: a comparison

Constant-frequency sliding-mode and linear proportional integral (PI) cascaded controllers (internal current loop and external output voltage control loop) for 12-pulse thyristor rectifiers are designed, using new models and convenient assumptions, and their performances compared. The use of sliding-mode control on line-commutated power converters implies the use of fixed-frequency sliding-mode design, originating steady-state errors. These are eliminated using a higher order switching function, with fourth-order Bessel polynomial coefficients, to minimize the response time and to eliminate the overshoot in the reaching mode. Comparisons are made using simulations (MATLAB/SIMULINK blocks) and experimental results. The sliding-mode controllers, as well as the PI controllers, need almost the same hardware and present no steady-state errors and no output voltage overshoots. Besides allowing a faster dynamics than the PI controllers, the proposed sliding-mode approach provides a new, nonlinear theoretical frame for solving the control problem of power rectifiers with output filters     

A buck quadratic PWM soft-switching converter using a single activeswitch

High-switching frequency associated with soft commutation techniques is a trend in switching converters. Following this trend, a buck pulsewidth modulation (PWM) converter is presented. The DC voltage conversion ratio of this converter has a quadratic dependence on duty cycle, providing a large stepdown. This new buck quadratic PWM soft-single-switched converter, having only a single active switch, provides a high efficient operating condition for a wide load range at high-switching frequency. In order to illustrate the operating principle of this new converter, a detailed study including theoretical analysis, relevant equations and simulation, and experimental results is carried out     

Gate delay variability estimation method for parametric yield improvement in nanometer CMOS technology

In digital CMOS circuits, parametric yield improvement may be achieved by reducing the variability of performance and power consumption of individual cell instances. Such improvement of variation robustness can be attained by evaluating parameter variation impact at gate level. Statistical characterization of logic gates are usually obtained by computationally expensive electrical simulations. An efficient gate delay variability estimation method is proposed for variability-aware design. The proposed method has been applied to different topologies (transistor network arrangements) and CMOS gates, and it has been compared to Monte Carlo simulations for data validation, resulting in computation time savings.     

Virtual RF system platform dedicated to heterogeneous complex SoC design

In this paper, we propose to develop a hierarchical library associated with various simulators that can be used in a single platform, called TrustMe-ViP, which enables a unique simulation framework and full model interoperability. Such platform is dedicated to complex SoC design, such as trusted personal devices where cost and time-to-market are very important constraints. To validate this methodology, we present the estimation of BER and power consumption for a Bluetooth transceiver.     

Discriminators for Instantaneous Frequency Measurement Subsystem Based on Open-Loop Resonators

The authors have studied a new way to design an instantaneous frequency measurement subsystem (IFMS). The method is based on bandstop filters. The device uses rectangular open-loop resonators instead of delay lines. The resonance frequency is adjusted by a resonator perimeter that must be approximately a half-wavelength long, and also by coupling distance between the resonators and the main transmission line. Simulated and experimental results are presented for a 5-bit IFMS.     

Deriving Efficient Porous Heteroatom‐Doped Carbon Electrocatalysts for Hydrazine Oxidation from Transition Metal Ions‐Coordinated Casein

In this work, the synthesis of high‐performance, metal ion‐imprinted, mesoporous carbon electrocatalysts for hydrazine oxidation reaction (HzOR) using casein or a family of phosphoproteins derived from cow's milk as a precursor is shown. The synthesis is made possible by mixing trace amounts of non‐noble metal ions (Fe³⁺ or Co²⁺) with casein and then producing different metal ions‐functionalized casein intermediates, which upon carbonization, followed by acid treatment, lead to metal ion‐imprinted catalytically active sites on the materials. The materials effectively electrocatalyze HzOR with low overpotentials at neutral pH and exhibit among the highest electrocatalytic performances ever reported for carbon catalysts. Their catalytic activities are also better than the corresponding control material, synthesized by carbonization of pure casein and other materials previously reported for HzOR. This work demonstrates a novel synthetic route that transforms an inexpensive protein to highly active carbon‐based electrocatalysts by modifying its surfaces with trace amounts of non‐noble metals. The types of metal ions employed in the synthesis are found to dictate the electrocatalytic activities of the materials. Notably, Fe³⁺ is found to be more effective than Co²⁺ in helping the conversion of casein into more electrocatalytically active carbon materials for HzOR.     

Video coding using greedy decompositions on generalised bit-planes

A novel method for performing greedy decompositions using generalised bit-planes is proposed. It provides an elegant solution to the tradeoff between quantisation of coefficients and number of passes in the matching pursuits algorithm. In addition, when replacing the matching pursuits algorithm in video coding, it provides a significant performance improvement