[4]Helicene–Squalene Fluorescent Nanoassemblies for Specific Targeting of Mitochondria in Live‐Cell Imaging

Ester, amide, and directly linked composites of squalene and cationic diaza [4]helicenes 1 are readily prepared. These lipid‐dye constructs 2 , 3 , and 4 give in aqueous media monodispersed spherical nanoassemblies around 100–130 nm in diameter with excellent stability for several months. Racemic and enantiopure nanoassemblies of compound 2 are fully characterized, including by transmission electron microscope and cryogenic transmission electron microscope imaging that did not reveal higher order supramolecular structures. Investigations of their (chir)optical properties show red absorption maxima ≈600 nm and red fluorescence spanning up to the near‐infrared region, with average Stokes shifts of 1350–1550 cm^?1. Live‐cell imaging by confocal microscopy reveals rapid internalization on the minute time scale and organelle‐specific accumulation. Colocalization with MitoTracker in several cancer cell lines demonstrates a specific staining of mitochondria by the [4]helicene–squalene nanoassemblies. To our knowledge, it is the first report of a subcellular targeting by squalene‐based nanoassemblies.     

3D Macroscopic Architectures from Self‐Assembled MXene Hydrogels

Assembly of 2D MXene sheets into a 3D macroscopic architecture is highly desirable to overcome the severe restacking problem of 2D MXene sheets and develop MXene‐based functional materials. However, unlike graphene, 3D MXene macroassembly directly from the individual 2D sheets is hard to achieve for the intrinsic property of MXene. Here a new gelation method is reported to prepare a 3D structured hydrogel from 2D MXene sheets that is assisted by graphene oxide and a suitable reductant. As a supercapacitor electrode, the hydrogel delivers a superb capacitance up to 370 F g^?1 at 5 A g^?1, and more promisingly, demonstrates an exceptionally high rate performance with the capacitance of 165 F g^?1 even at 1000 A g^?1. Moreover, using controllable drying processes, MXene hydrogels are transformed into different monoliths with structures ranging from a loosely organized porous aerogel to a dense solid. As a result, a 3D porous MXene aerogel shows excellent adsorption capacity to simultaneously remove various classes of organic liquids and heavy metal ions while the dense solid has excellent mechanical performance with a high Young's modulus and hardness.     

X-ray based tools for the investigation of buried interfaces in organic electronic devices

X-ray reflectivity combined with grazing incidence diffraction is a valuable tool for investigating organic multilayer structures that can be used in devices. We focus on a bilayer stack consisting of two materials (poly-(3-hexylthiophene)) (P3HT) and poly-(4-styrenesulfonic acid) (PSSA) spin cast from orthogonal solvents (water in the case of PSSA and chloroform or toluene for P3HT). X-ray reflectivity is used to determine the thickness of all layers as well as the roughness of the organic–organic hetero-interface and the P3HT surface. The surface roughness is found to be consistent with the results of atomic force microscopy measurements. For the roughness of P3HT/PSSA interface, we observe a strong dependence on the solvent used for P3HT deposition. The solvent also strongly impacts the texturing of the P3HT crystallites as revealed by grazing incidence diffraction. When applying the various PSSA/P3HT multilayers in organic thin-film transistors, we find an excellent correlation between the determined interface morphology, structure and the device performance.     

Engineering the Interlayer Spacing by Pre-Intercalation for High Performance Supercapacitor MXene Electrodes in Room Temperature Ionic Liquid

MXenes exhibit excellent capacitance at high scan rates in sulfuric acid aqueous electrolytes, but the narrow potential window of aqueous electrolytes limits the energy density. Organic electrolytes and room-temperature ionic liquids (RTILs) can provide higher potential windows, leading to higher energy density. The large cation size of RTIL hinders its intercalation in-between the layers of MXene limiting the specific capacitance in comparison to aqueous electrolytes. In this work, different chain lengths alkylammonium (AA) cations are intercalated into Ti₃C₂T_x, producing variation of MXene interlayer spacings (d-spacing). AA-cation-intercalated Ti₃C₂T_x (AA-Ti₃C₂), exhibits higher specific capacitances, and cycling stabilities than pristine Ti₃C₂T_x in 1 m 1-ethly-3-methylimidazolium bis-(trifluoromethylsulfonyl)-imide (EMIMTFSI) in acetonitrile and neat EMIMTFSI RTIL electrolytes. Pre-intercalated MXene with an interlayer spacing of ≈2.2 nm, can deliver a large specific capacitance of 257 F g⁻¹ (1428 mF cm⁻² and 492 F cm⁻³) in neat EMIMTFSI electrolyte leading to high energy density. Quasi elastic neutron scattering and electrochemical impedance spectroscopy are used to study the dynamics of confined RTIL in pre-intercalated MXene. Molecular dynamics simulations suggest significant differences in the structures of RTIL ions and AA cations inside the Ti₃C₂T_x interlayer, providing insights into the differences in the observed electrochemical behavior.     

Microwave active resonator band-pass filters in various mmic technologies

In this article, two topologies of L-C parallel active resonators are presented. These circuits are realized in MMIC technology, using three transistors which could be MESFET, hemt or HBT. The survey of these resonators shows the possibility, by controling the values of a resistor and/or a capacitor, on the one hand, to tune the resonance frequency of these circuits, and on the other hand, to cancel out their losses so as to obtain negative conductance. Compact, lossless and narrow-band filters are then implemented using previous active resonators. To date, the use of mesfet technology has reduced the synthesis of such active filters in S-band and at X-band low frequencies. Now, however, hemt and HBT technologies allow the extension of their implementation to the whole X-band. This survey is illustrated by the simulated response of a 10 GHz filter with a 500 MHz 3 dB bandwidth. The mmic technology is a 0.2 μm hemt one. The simulated performances of this filter achieve a mean transmission gain of 0. 5 dB, with a reflection loss higher than 10 dB at 10 GHz,     

Enhancement of turbulent jet diffusion flame blowout limits by annular counterflow

The effects of a proposed combustion technique, named as annular counterflow, on the enhancement of jet diffusion flame blowout limits were investigated by a series of experiments conducted for the present study. Annular counterflow was formed in a concentric annulus, in which fuel jet was ejected from a nozzle and air was sucked into an outer cylinder encompassing the nozzle. Three fuel nozzles and outer cylinders of different sizes were utilized to perform the experiments. Schlieren technique and normal video filming were employed for the visualization of diverse flame morphologies triggered by the said flow. Gas samplings were taken and scrutinized by the use of a gas chromatograph. Results showed that the blowout limits can be enhanced dramatically by an increase in volume flow rates of air‐suction. Mixing enhancement is achieved with frequent and strong outward ejection of fluids from the cold jet when this technique is applied. The blowout limits are further extended when the diameter of outer cylinders becomes smaller and/or that of the fuel nozzle becomes larger. The base widths of lifted flames were found to be narrower in the interim of annular counterflow application. The rates of increase in flame lift‐off heights and base widths along with an increase in fuel flow velocities become sluggish when the volume flow rates of air are increased. The amount of fuel that was sucked into the outer cylinder was found to be negligible and trivial. A model based on annular and coaxial jet was developed to predict the lifted flame base width and blowout limits. The coincidence between the prediction and experimental results unambiguously validates that the momentum of air‐suction dominates the beneficial effect. Copyright © 2001 John Wiley & Sons, Ltd.     

Mechanical properties of a reinforced composite polymer electrolyte membrane and its simulated performance in PEM fuel cells

The hygro-thermo-mechanical properties and response of a class of reinforced perfluorosulfonic acid membranes (PFSA), that has potential application as an electrolyte in polymer fuel cells, are investigated through both experimental and numerical modeling means. A critical set of material properties, including Young's modulus, proportional limit stress, break stress and break strain, is determined for a range of temperature and humidity levels in a custom-built environmental test apparatus. The swelling strains are also determined as functions of temperature and humidity level. To elucidate the mechanical response and the potential effect these properties have on the mechanical durability, mechanics-based simulations are performed using the finite element method (ABAQUS). The results indicate that the relatively high strength of the experimental membrane, in combination with its relatively low in-plane swelling due to water absorption, should have a positive influence on membrane durability, potentially leading to longer life times for polymer electrolyte membrane fuel cells (PEMFC).     

MIMO Channel Capacity and Configuration Selection for Switched Parasitic Antennas

Multiple-input multiple-output (MIMO) systems offer significant enhancements in terms of their data rate and channel capacity compared to traditional systems. However, correlation degrades the system performance and imposes practical limits on the number of antennas that can be incorporated into portable wireless devices. The use of switched parasitic antennas (SPAs) is a possible solution, especially where it is difficult to obtain sufficient signal decorrelation by conventional means. The covariance matrix represents the correlation present in the propagation channel, and has significant impact on the MIMO channel capacity. The results of this work demonstrate a significant improvement in the MIMO channel capacity by using SPA with the knowledge of the covariance matrix for all pattern configurations. By employing the “water-pouring algorithm” to modify the covariance matrix, the channel capacity is significantly improved compared to traditional systems, which spread transmit power uniformly across all the antennas. A condition number is also proposed as a selection metric to select the optimal pattern configuration for MIMO-SPAs.     

Dynamic directional gradient vector flow for snakes.

Snakes, or active contour models, have been widely used in image segmentation. However, most present snake models do not discern between positive and negative step edges. In this paper, a new type of dynamic external force for snakes named dynamic directional gradient vector flow (DDGVF) is proposed that uses this information for better performance. It makes use of the gradients in both x and y directions and deals with the external force field for the two directions separately. In snake deformation, the DDGVF field is utilized dynamically according to the orientation of snake in each iteration. Experimental results demonstrate that the DDGVF snake provides a much better segmentation than GVF snake in situations when edges of different directions are present which pose confusion for segmentation.     

On the optimum design of unitary cyclic group space-time codes

In this letter, based on the exact pairwise-error probability, we derive the union bound on the symbol-error probability (SEP) of the differential unitary space-time (DUST) modulation employing group codes. Instead of using the rank-and-determinant or Euclidean distance criteria, we optimize the cyclic group codes such that the union bound on the SEP is minimized for a predetermined scenario, taking into account the number of transmit and receive antennas and the operating signal-to-noise ratio (SNR). Our simulation results show that for a wide range of SNRs, the codes with the minimum union bound for a particular SNR outperform the codes designed based on rank-and-determinant or Euclidean distance criteria.