基于红外光纤多液层检测系统的研究与设计

低成本、高精度、结构简单,安全可靠的油水分离器对于提高化工生产的安全水平和效率具有重要意义;介绍了一种以微处理器AT89S52为核心、利用红外光吸收理论实时检测化工生产中多层液体的嵌入式系统;运用化工生产中各层液体浓度不同对红外光吸收程度不同的理论,设计了红外光纤传感器的信号调理电路,开发了以AT89S52为核心,包括A/D转换模块、数据存储模块、串口通讯模块在内的中央硬件处理平台;基于红外光纤液层检测系统与同类系统相比,具有成本低廉,传感检测探头本质安全,系统安全级别高,实时性好,便于大规模推广应用的特点,具有广阔的应用前景。     

小灵通基站电源监控系统的电磁干扰设计

为了保证小灵通基站电源的可靠性,业界提出了通过ISDN通信线路进行信号和电源同时传输的方案,即直流电源远供;由于监控单元是小灵通远供电源系统的控制核心,因此,监控模块能够稳定和可靠地工作是保证远供电源系统可靠运行的关键;而通信局站中通信设备众多,电磁环境相对比较恶劣,因此对设备的电磁兼容性要求也较高;分析了小灵通基站电源监控模块的功能与结构,并从原理图设计、PCB设计及外壳设计方面给出了解决电磁干扰的方案;实践证明,该监控系统运行稳定可靠,取得了预期效果,具有较高的实用价值。     

并行测试技术及在导弹测试中的应用研究

并行测试技术是将并行处理技术引进自动测试领域形成的一种先进的测试技术和方法,拥有减少测试时间、降低测试成本的强大优势,正成为研究热点之一;首先介绍了并行测试的基本概念,分析对比了几种实现并行测试的软硬件方法及基本结构体系;然后结合导弹传统串行测试方法的不足及未来战场快速测试的要求,设计了一种导弹的网络化并行测试的基本结构;最后,针对并行测试技术在导弹测试中的应用,提出了需要注意的任务调度、死锁预防及并行测试接口设计等几点关键技术和导弹并行测试系统组建原则。     

一种新的基于Zernike正交矩亚像素边缘定位的直径测量方法

提出了一种新的基于亚像素边缘定位技术的棒状物体直径测量方法;该方法利用两个CCD摄像头,分别获得两张棒状物体横截面的椭圆特征图像,利用仿射变换将灰度椭圆特征图像变换成圆形特征图像,然后利用亚像素中的Zernike正交矩对边缘进行精确定位,进而分别计算出棒状物体的直径,再将两个测量数据加以平均融合,完成对直径的测量;实验结果表明,与像素级方法相比较,该方法定位精度高,测量误差小,能够达到提高测量精度的目的。     

嵌入式模糊智能控制系统设计

文章概括了嵌入式模糊控制的基本数学理论基础和重要应用价值,从实践和理论角度全面综述了嵌入式模糊智能控制系统的基本构造和设计特点,说明了嵌入式模糊控制体系设计、仿真、实现的一般规律和方法措施。文章重点阐述了二维SVFC和MISO--MVFC体系的嵌入式过程实现,理论结合实践,列举了一系列典型的具体项目设计实例。文章探讨了嵌入式模糊控制的优势和不足,进一步阐述了如何进行嵌入式模糊控制体系的白适应寻优设计问题。     

白蚁提取液急性毒性及致突变性研究

本文采用大,小鼠急性经口毒性试验、Ａｍｅｓ试验、小鼠骨髓细胞微核试验及小鼠精子畸变试验对白蚁提取液的毒理学安全性进行了研究,结果表明,白蚁提取液大,小鼠急性经口ＬＤ５０均大于１０ｇ／ｋｇ体重,属“实际无毒”：体内（包括体细胞和生殖细胞）、体外致突变性试验系统均未检出其致突性。     

Modelling the removal of organic vehicle from ceramic or metal mouldings: The effect of gas permeation on the incidence of defects

A shrinking undegraded core and a porous outer layer result, if the organic vehicle used for shaping ceramic or metal powder mouldings recedes in the interparticle space of the moulded body during pyrolysis. In the present work, a numerical model has been used which simulates the undegraded shrinking core situation and quantifies degradation of the organic vehicle and the diffusion of the resulting products in solution in the organic phase during pyrolysis of a ceramic moulding. This model is extended to include gaseous mass transport in the porous outer layer for a moulding in the shape of an infinite cylinder. The effect of resistance to gaseous mass transport in the porous outer region on defects originating in inner regions was estimated. It is shown that the greatest obstruction to mass transport is diffusion of degradation products in solution in the organic phase. However, the permeability coefficient for gas transport in the outer region begins to affect the critical heating rate required for avoidance of defects only when it is less than 10^–15m².Nomenclature C Concentration,C=C (r, t), based on the total volume of ceramic suspension - d Effective molecular diameter of alphamethylstyrene - D Diffusion coefficient,D=D (C, T) - e Porosity of powder - E Activation energy for thermal degradation - h Remaining weight fraction of polymer - H_vap Enthalphy of vaporization - i Node number - I Pre-exponential constant in Equation 13 - j Time step - K _p Permeability coefficient - K ₀ Specific rate constant - m Mass of monomer displaced - M Mass of one alphamethylstyrene molecule - P Monomer vapour pressure - P _s Monomer vapour pressure at outer surface of the cylinder - P ₁ ⁰ Vapour pressure of monomer over its pure liquid - Q Rate of production of monomer, based on the total volume of ceramic suspension - r Radius of the cylinder - r _j Distance from central axis to the inner surface of the porous layer at time stepj - r ₀ Initial radius of the cylinder - R Universal gas constant - S ₀ Specific surface area of powder per unit solid volume - t Time - T Absolute temperature - T _c Temperature at maximum vapour pressure of monomer and atZ _c - V Volume of monomer - V _c Ceramic volume fraction - V _p Polymer volume fraction - w Mass of monomer stored in the porous annulus - Z Heating rate - Z _c Critical heating rate - ₁ Volume fraction of monomer in the polymer-monomer solution - Viscosity of the monomer vapour - _p Density of the polymer - Polymer-monomer interaction constant     

Single-Atom Metal Sites Anchored Hydrogen-Bonded Organic Frameworks for Superior “Two-In-One” Photocatalytic Reaction

Photoredox catalysis is a green solution for organics transformation and CO₂ conversion into valuable fuels, meeting the challenges of sustainable energy and environmental concerns. However, the regulation of single-atomic active sites in organic framework not only influences the photoredox performance, but also limits the understanding of the relationship for photocatalytic selective organic conversion with CO₂ valorization into one reaction system. As a prototype, different single-atomic metal (M) sites (M²⁺ = Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺) in hydrogen-bonded organic frameworks (M-HOF) backbone with bridging structure of metal-nitrogen are constructed by a typical “two-in-one” strategy for superior photocatalytic C N coupling reactions integrated with CO₂ valorization. Remarkably, Zn-HOF achieves 100% conversion of benzylamine oxidative coupling reactions, 91% selectivity of N-benzylidenebenzylamine and CO₂ conversion in one photoredox cycle. From X-ray absorption fine structure analysis and density functional theory calculations, the superior photocatalytic performance is attributed to synergic effect of atomically dispersed metal sites and HOF host, decreasing the reaction energy barriers, enhancing CO₂ adsorption and forming benzylcarbamic acid intermediate to promote the redox recycle. This work not only affords the rational design strategy of single-atom active sites in functional HOF, but also facilitates the fundamental insights upon the mechanism of versatile photoredox coupling reaction systems.     

Ligand Design in Atomically Precise Copper Nanoclusters and Their Application in Electrocatalytic Reactions

Metal nanoclusters (MNCs) are compositionally well-defined and also structurally precise materials with unique molecule-like properties and discrete electronic energy levels. Atomically precise ligand-protected Cu nanoclusters (LP-CuNCs) are one category of typical MNCs that usually demonstrate unique geometric and electronic structures to serve as electrocatalysts. However, the synthesis, application, as well as structure-performance relationship of LP-CuNCs are not adequately studied. Significantly, the ligands are essential to the geometric structure, crystal structure, size, and electronic structure of LP-CuNCs, which determine their physiochemical properties and applications. In this review, significant progress in the ligand design of LP-CuNCs, and their application in electrocatalytic reactions is introduced. The general basics of ligand-protected MNCs (LP-MNCs) are first introduced and the functions of ligands are emphasized. Subsequently, a series of different ligands for LP-CuNCs including thiolates, phosphines, alkynyl, polymers, and biomolecules are highlighted. Thereafter, their applications in different electrocatalytic reactions are discussed. It is believed that this review will not only inspire the design and synthesis of novel LP-CuNCs, but also contribute to the extension of their applications in electrocatalytic reactions and the establishment of accurate structure-performance relationships.     

Evaluation Model of Click Rate of Electronic Commerce Advertising Based on Fuzzy Genetic Algorithm

Mobile Networks and Applications - In order to improve the ability of quantitative evaluation of e-commerce advertising click rate, a model of e-commerce advertising click rate evaluation based on...