Comparative Study of 9×19 mm Ammunition Combustion Products and Residues

During the last decades, authorities’ awareness on environmental and human health impact at national and international level has increased in the field of small arms ammunition containing lead and antimony. Thus, the evolution of environmental policies regarding production and use of heavy metals and their compounds, especially in EU countries, implied extensive studies on the environmental implications of 9×19 mm caliber ammunition use, especially in indoor shooting ranges. In this context, the paper describes the experimental studies performed on Pb‐containing conventional FMJ (full metal jacketed) ammunition and comparative measurements on new ammunition designed for training. The combustion products and residues from conventional Pb‐containing ammunition and Cu‐based “greener” ammunition were compared in terms of gaseous products, metal concentration in aerosols and metal concentrations in solid residues. Gas emissions and solid residues were measured for four different types of ammunitions. The results showed that the copper content of the residue is significantly higher in case of Cu‐containing composite bullets. For the ammunition equipped with Pb bullet, an important percentage of the Pb residue is generated by erosion of the exposed part of the bullet core. On the other hand, the ammunition containing Cu‐composite bullet generates large quantities of Cu residues, which have similar environmental impact and less impact on human health. Gas analysis indicated the presence of CO and NO_x and, surprisingly, high concentrations of HCN, CH₄, and NH₃. Lower gas concentrations are obtained for the composite bullets due to an incomplete combustion of gun propellant.     

Synthesis of hybrid nanocomposites based on new triazeno copolymers and montmorillonite used for detecting metal ions

The modern synthesis of novel functional materials with improved properties includes that of hybrid nanocomposites composed of inorganic nanoparticles and organic derivatives, where controlling the molecular structure at atomic and macroscopic dimensions is a key factor, with a major effect on performance. An extension of this approach to the field of nanocomposites containing photopolymers with triazene groups attached on a methacrylic backbone could be of great interest in the future development of chemosensors and photoresists, among others. Photopolymer/clay nanocomposites were prepared by in situ free radical copolymerization of 1‐(phenyl)‐3‐(2‐methacryloyloxyethylcarbamoyloxyethyl)‐3‐methyltriazene‐1 or 1‐(p‐methoxyphenyl)‐3‐(2‐methacryloyloxyethylcarbamoyloxyethyl)‐3‐methyltriazene‐1 and vinyl acetate or styrene in solution and in the presence of 3 and 5 wt% of organically modified montmorillonite. The characterization of the nanocomposites and pure copolymers was achieved through ¹H NMR and Fourier transform infrared spectroscopy, gel permeation chromatography, thermogravimetric analysis, X‐ray diffraction, atomic force microscopy and fluorescence analysis. The morphologies and properties of the nanocomposites are dependent on the nature of the triazene, on the co‐monomer structure and on the organoclay content. Also, the fluorescence response of these nanocomposites towards certain metal ions (Fe³⁺, Cu²⁺, Hg²⁺, Ni²⁺) in dimethylformamide solution was investigated. The effect of uranyl ions on the fluorescence intensity of the nanocomposites in solution or as films could be exploited in the development of ‘turn‐off’ or ‘turn‐on’ chemosensors for this type of analyte. Triazeno copolymer/organophilic montmorillonite nanocomposites with exfoliated (not completely exfoliated) or exfoliated and intercalated structures exhibit distinct characteristics concerning their fluorescence behaviour, a higher sensing ability towards certain target compounds (Fe³⁺, UO₂²⁺) being evidenced for those incorporating 3 wt% organoclay in solution and as films. Copyright © 2010 Society of Chemical Industry     

Multistage access network for bidirectional DWDM transmission using ASE-injected FP-LD

We propose a novel optical distribution network for multistage optical access network with multiple remote nodes (RNs) using 4skip0 filters. The system can be implemented by use of 1/spl times/N arrayed waveguide grating in the central office, cascaded RNs, and a plurality of optical network units (ONUs). It also employs colorless ONUs based on incoherent light injected Fabry-Pe/spl acute/rot laser diodes for low operation and maintenance cost. Experiment shows error-free transmission with simultaneous bidirectional 1.25 Gb/s per channel up to 20 km.     

The meta-stable dip (MSD) effect in SOI FinFETs

The meta-stable dip (MSD) effect is demonstrated and characterized in SOI FinFETs. With ascending scan of front-gate voltage (V_G1), the magnitude of drain current (I_D) tends to be fixed within a specific region of the front-gate voltage and this leads to a dip of transconductance (g_m). The dip width can be modulated through a control of bias condition or measurement speed such as back-gate voltage (V_G2), drain voltage (V_D) and step size of the front-gate voltage. From the dual-gate transient measurement, it is found that the MSD effect is highly dependent on the floating-body effect. In SOI FinFETs, the MSD effect is significantly affected by the fin width due to the fringing electric field of the lateral gates.     

Generic fitted shapes (GFS): Volumetric object segmentation in service robotics

In this paper, a simultaneous 3D volumetric segmentation and reconstruction method, based on the so-called Generic Fitted Shapes (GFS) is proposed. The aim of this work is to cope with the lack of volumetric information encountered in visually controlled mobile manipulation systems equipped with stereo or RGB-D cameras. Instead of using primitive volumes, such as cuboids or cylinders, for approximating objects in point clouds, their volumetric structure has been estimated based on fitted generic shapes. The proposed GFSs can capture the shapes of a broad range of object classes without the need of large a-priori shape databases. The fitting algorithm, which aims at determining the particular geometry of each object of interest, is based on a modified version of the active contours approach extended to the 3D Cartesian space. The proposed volumetric segmentation system produces comprehensive closed object surfaces which can be further used in mobile manipulation scenarios. Within the experimental setup, the proposed technique has been evaluated against two state-of-the-art methods, namely superquadrics and 3D Object Retrieval (3DOR) engines.     

Relaxing PWQ Lyapunov stability criteria for PWA systems

The note addresses the calculation of piecewise quadratic (PWQ) Lyapunov functions for PWA (piecewise affine) systems. New LMI relaxations are proposed. These relaxations have been found to be effective in cases where the traditional relaxations fail.     

A patchy approximation of explicit model predictive control

The explicit solution of multi-parametric optimisation problems (MPOP) has been used to construct an off-line solution to relatively small- and medium-sized constrained control problems. The control design principles are based on receding horizon optimisation and generally use linear prediction models for the system dynamics. In this context, it can be shown that the optimal control law is a piecewise linear (PWL) state feedback defined over polytopic cells of the state space. However, as the complexity of the related optimisation problems increases, the memory footprint and implementation of such explicit optimal solution may be burdensome for the available hardware, principally due to the high number of polytopic cells in the state-space partition. In this article we provide a solution to this problem by proposing a patchy PWL feedback control law, which intend to approximate the optimal control law. The construction is based on the linear interpolation of the exact solution at the vertices of a feasible set and the solution of an unconstrained linear quadratic regulator (LQR) problem. With a hybrid patchy control implementation, we show that closed-loop stability is preserved in the presence of additive measurement noise despite the existence of discontinuities at the switch between the overlapping regions in the state-space partition.     

Vertically oriented nickel nanorod/carbon nanofiber core/shell structures synthesized by plasma-enhanced chemical vapor deposition

Plasma-enhanced chemical vapor deposition, without a nickel-containing gaseous precursor, was used to synthesize continuous nickel (Ni) nanorods inside the hollow cavity of carbon nanofibers (CNFs), thus forming vertically aligned Ni/CNF core/shell structures. Scanning and transmission electron microscopic images indicate that the elongated Ni nanorods originate from the catalyst particles at the tips of the CNFs and that their formation is due to the effect of extrusion induced by the compressive force of the graphene layers during growth. Different from previous work, each vertically-aligned core/shell structure reported is totally isolated from its neighbors. Continuous Ni nanorods are found to separate into smaller ones with increasing growth time, which was ascribed to (i) the limited amount of Ni available in the tip of the CNF, (ii) the polycrystalline nature of the Ni nanorods and (iii) the combined effects of the compressive stresses on the side of the Ni nanorods and of the tensile stress along their axis.     

Tunable single-mode fiber reflective grating filter

A single-mode fiber tunable reflective filter is demonstrated by translating a fan-shaped grating structure through the evanescent field of a side-polished fiber. Filter linewidths of about 1 nm were measured over tuning ranges in excess of 65 nm. Reflectivities as high as 88 percent were observed. Using the fiber filter as a feedback element, a multimode semiconductor laser was observed to oscillate in a single mode which could be discretely turned over a wavelength range of 26 nm.     

Argus: Low-Cost, Comprehensive Error Detection in Simple Cores

Argus, a novel approach for detecting errors in simple processor cores, dynamically verifies the correctness of the four tasks performed by a von Neumann core: control flow, data flow, computation, and memory access. Argus detects transient and permanent errors, with far lower impact on performance and chip area than previous techniques.