Integration of diamond in fully-depleted silicon-on-insulator technology as buried insulator: A theoretical analysis

We examine here by electro-thermal simulation tools (SILVACO's Atlas) a configuration of Silicon-On-Insulator substrate for Fully-Depleted MOSFET architectures, incorporating diamond as buried insulator, and compare it with traditional silicon dioxide BOX for the future technological nodes of the ITRS (90 nm and below). Our aim is to give major trends to be followed in order to optimize diamond integration from electrical and thermal points of view, constraints that must be kept in mind in parallel with the technological work on thin diamond films. In this theoretical study, we perform a benchmarking between SiO₂ and diamond BOX. We first point out that the BOX thickness should not be more than few hundred nanometers to maintain electrical performances. From thermal point of view, we demonstrate that the replacement of 100 nm thick buried oxide by a 100 nm thick diamond layer can lead to about 50% reduction of the temperature when only 33% decrease can be obtained with Ultra Thin SiO₂ BOX (20 nm). Furthermore, thick diamond BOX avoids the parasitic capacitances issue that reduces Ultra Thin BOX devices working frequency.     

An arithmetical hierarchy in propositional dynamic logic

We prove that any alternation of modalities in PDL adds to its expressive power. The proof uses Turing machine models where PDL formulas define the arithmetical hierarchy of sets. As a by-product, we obtain a theorem of Berman and Paterson.     

Chemomechanical Systems: Study of Contraction and Mechanical Work of Poly(Acrylonitrile) Gel Fibers

Poly(acrylonim1e) fibers were preoxidated under stress, in the presence of air, then saponified by boiling in alkaline solutions. The chemomechani-cal behavior of these fibers, expressed as contraction and mechanical work, under different loads and in different solvent-nonsolvent and/or base-acid systems were investigated. Total nitrogen content, carboxyl groups content, tensile strength, and cross-link density were determined. Both contraction and mechanical work were expressed as functions of applied load in every studied system. The results of chemomechanical measurements were connected to those of chemical and physical investigations. Significant differences in chemomechanical behavior were found to be the result of different stress conditions during the preoxidation stage.     

Synthesis and characterization of polyurethane cationomer/MMT hybrid composite

BACKGROUND: The development of polymeric nanocomposites incorporating intercalated or exfoliated layered silicate clays into the organic matrix has been substantially motivated by the significant improvements induced by the presence of the inorganic component. Moreover, understanding and controlling the dispersion of inorganic layers into segmented polyurethane matrices by means of ionic interactions, and exploiting these interactions to enhance physicomechanical behaviour, could be of great interest in the field of polymer nanocomposites. RESULTS: New cationic polyurethane elastomers were prepared starting from poly(butylene adipate)diol (M_n = 1000 g mol^?1), 4,4′‐diphenylmethane diisocyanate, 1,4‐butanediol and N‐methyldiethanolamine or N,N′‐β‐hydroxyethylpiperazine, used as potential quaternizable moieties. The characterization of the polymers was achieved using specific analyses employed for the macromolecular samples (Fourier transform infrared and ¹H NMR spectroscopy, thermogravimetric analysis (TGA), gel permeation chromatography). An extension of our research on polymers reinforced with organically modified montmorillonite (OM‐MMT) in order to prepare hybrid composites with improved properties was performed and the resulting materials were characterized using TGA, X‐ray diffraction, atomic force microscopy and scanning electron microscopy. Also, the mechanical properties of the cationic polyurethane/OM‐MMT composites were investigated in comparison with the pristine ionic/non‐ionic polymers and their composites containing non‐ionic polymer blended with OM‐MMT or ionic polymer and unmodified MMT. CONCLUSION: The insertion of the organically modified clay into the polymeric matrix gave an improvement of the mechanical properties of the polyurethane composites, especially the tensile strength and stiffness of the hybrid materials. Copyright © 2009 Society of Chemical Industry     

Globalization and heterogenization: Cultural and civilizational clustering in telecommunicative space (1989–1999)

The globalization of telecommunicative ties between nations is studied from a heterogenization perspective. A theoretical model inspired by Appadurai’s “disjuncture hypothesis,” which stipulates that global flows of communication are multidimensional and reinforce regional/local identities, is tested empirically on an international voice traffic dataset. Spatial-statistical measures (global and local versions of Moran’s I) indicate that countries that share the same linguistic (English, Spanish, or French) or civilizational (Catholic, Protestant, and Buddhist–Hindu) background are more likely to be each other’s “telecommunicative neighbors” and that this tendency has increased over time (1989–1999).     

Asymptotic Properties of Monotonic Nonexpansive Mappings

Let T be a nonexpansive monotonic mapping from C to itself where C is a closed subset of a space of bounded real functions, with the supremum norm. We study asymptotic properties of several average iterates of T, related to the cycle time.     

Load-Balanced Sparse Matrix–Vector Multiplication on Parallel Computers

We considered the load-balanced multiplication of a large sparse matrix with a large sequence of vectors on parallel computers. We propose a method that combines fast load-balancing with efficient message-passing techniques to alleviate computational and inter-node communications challenges. The performance of the proposed method was evaluated on benchmark as well as on synthetically generated matrices and compared with the current work. It is shown that, by using our approach, a tangible improvement over prior work can be obtained, particularly for very sparse and skewed matrices. Moreover, it is also shown that I/O overhead for this problem can be efficiently amortized through I/O latency hiding and overall load-balancing.     

Synthesis of few-layered graphene by ion implantation of carbon in nickel thin films

The synthesis of few-layered graphene is performed by ion implantation of carbon species in thin nickel films, followed by high temperature annealing and quenching. Although ion implantation enables a precise control of the carbon content and of the uniformity of the in-plane carbon concentration in the Ni films before annealing, we observe thickness non-uniformities in the synthesized graphene layers after high temperature annealing. These non-uniformities are probably induced by the heterogeneous distribution/topography of the graphene nucleation sites on the Ni surface. Taken altogether, our results indicate that the number of graphene layers on top of Ni films is controlled by the nucleation process on the Ni surface rather than by the carbon content in the Ni film.