Edge passivation and related electrical stability in silicon powerdevices

Factors governing long-term stability of silicon power devices are discussed with particular reference to a major failure mechanism observed in a thyristor device. The device failure was due to electrical instability during an electrical and thermal stability storage test, wherein it was observed that the reverse blocking voltage deteriorated under applied bias at the rated maximum junction temperature. The major cause of this failure was identified as lack of exhaust during the edge passivation and curing process due to which excessive chemical deposits are retained in the bevel region of the silicon element. This contributes to surface leakage current and, hence, a rapid degradation of the off-state characteristics. An orthogonal array experiment was employed to optimize the process factors and levels. The manufacturing process was then modified by incorporating an effective exhaust system in the passivant curing oven. This resulted in marked improvements in the electrical stability and manufacturing yield of this device     

Magnetic and transport properties of Laves phase Dy1−xMmxCo2 (x = 0–0.5) alloys

The influence of Mm substitution (Mm = mischmetal) on structural, transport and magnetic properties of (Dy_1?xMm_x)Co₂ (x = 0, 0.1, 0.2, 0.3, 0.4 and 0.5) alloys has been investigated by means of X-ray diffraction (XRD), temperature dependent electrical resistivity (ρ(T)), ac susceptibility (χ(T)) and thermopower (S(T)). XRD patterns show the formation of solid solutions crystallizing with cubic Laves (C15) type structure at room temperature. The pronounced discontinuities in the resistivity and thermopower at Curie temperature (T_C) are explained based on the suppression of the spin-fluctuation contribution. The gradual decrease in T_C and sharpness of discontinuities in ρ(T) and S(T) with increasing Mm substitution has been discussed.     

Peristaltic transport in an asymmetric channel with heat transfer — A note

The problem of heat transfer for the motion of a viscous incompressible fluid induced by travelling sinusoidal waves has been analytically investigated for a two-dimensional asymmetrical channel. The channel asymmetry is produced by choosing the peristaltic wave train on the walls to have different amplitudes and phase. The flow is investigated in a wave frame of reference moving with the velocity of the wave. The momentum and energy equations have been linearized under long-wavelength and low-Reynolds number assumptions and closed form expressions for temperature and coefficient of heat transfer have been derived. The effect of Hartmann number, Eckert number, width of the channel and phase angle on temperature and coefficient of heat transfer are discussed numerically and explained graphically.     

An Efficient,Stable and Reusable Palladium Nanocatalyst: Chemoselective Reduction of Aldehydes with Molecular Hydrogen in Water

Palladium nanoparticles (Pd‐BNP) stabilized by a binaphthyl‐backbone can be efficiently used for the chemoselective reduction of aldehydes in the presence of hydrogen at room temperature in water. The Pd‐BNP catalyst is easily recovered and reused for five catalytic cycles.

     

The aggregation behavior and structure of blends of κ-carrageenan and ε-polylysine hydrochloride

Polypeptides play a key role in improving food quality, and understanding their interactions with polysaccharides would be beneficial to developing new foods. Herein, κ-carrageenan (KC) and ε-polylysine hydrochloride (PLH) were chosen as the model polysaccharide and polypeptide, respectively, to study polysaccharide/polypeptide complexes. The KC/PLH solutions were characterized for turbidity as a function of mass ratio, pH, salts and stirred conditions at 0.5 and 1 mg mL^–1 concentrations. The solutions at a KC/PLH mass ratio of 7:3 have the highest turbidity, and the turbidity is stable in acidic conditions, decreases with increase in pH in alkaline conditions and salt concentration, and increases with increase of stirred time and temperature. The Fourier transform infrared spectra suggest that the amide I band of PLH disappears along with a change in the amide II band upon complexing with KC. These changes further influence the microstructure and reveal a rough, non-uniform and large irregular cavity network structure. Indeed, these observations are intimately associated with the dynamic interactions persistent at the molecular level between the KC and PLH. © 2021 Society of Industrial Chemistry.     

Laser-Induced Carbonization for Anticounterfeiting Tags

The counterfeiting of products is a serious concern for any nation with the increasing activity of counterfeit markets. Anticounterfeiting tags demand low-cost, unclonable, facile, and ultrafast manufacturing processes. In this study, a laser-induced carbonization (LIC) technique is employed to produce discrete sizes of LIC spots distributed randomly in an array fashion, as a tag, preferably on a laser wavelength-sensitive polyimide (PI) film. This technique enables the intrinsic creation of LIC spots in PI without any foreign functional materials, thus avoiding the need for external material. Owing to laser technology, based on the input design and laser processing parameters, the reconfigurable desired output tags can be accomplished in a very short time. Different forms of LIC spots in an optical image are grouped and sorted into three-level bits based on their sizes and brightness for digitalization. The unique LIC-based tags can be applied to the flexible printed circuit board industry to address counterfeiting.     

Cooperative control of a platoon of connected autonomous vehicles and unconnected human-driven vehicles

By using kinematic state information obtained through vehicle-to-vehicle communications, connected autonomous vehicles (CAVs) can drive cooperatively to alleviate shockwave propagation associated with traffic disturbances. However, during the transition to full autonomy, CAVs and human-driven vehicles (HDVs) will coexist on the road, creating mixed-flow traffic. The inherent heterogeneity and randomness in human driving behavior can generate additional disturbances in the traffic flow. Further, HDVs without communication functionality (unconnected HDVs) can cause the control performance of CAVs to degrade by negatively impacting platoon formation. To proactively mitigate the negative impacts of HDVs in mixed-flow traffic, this study proposes a cooperative control strategy with three components for platoons consisting of CAVs and unconnected HDVs: (i) a number estimator for estimating the number of HDVs between two CAVs, (ii) a kinematic state predictor for predicting the kinematic states of HDVs, and (iii) a multi-anticipative car-following controller (i.e., control strategy using kinematic state information of multiple preceding vehicles) for CAVs to maintain string stability and desired time headway. To initialize the proposed strategy, the number estimator is developed using a deep neural network (DNN). Then, a DNN-based kinematic state predictor predicts the kinematic states of HDVs for CAVs to enable multi-anticipative car-following control. The multi-anticipative car-following controller is implemented using an extended intelligent driver model-guided deep deterministic policy gradient algorithm, which ensures safety, string stability, and traffic efficiency. The effectiveness of the proposed control strategy is validated through numerical experiments using NGSIM data. Results indicate that the proposed strategy can produce accurate estimations of the number and the kinematic states of HDVs between CAVs. Further, it can achieve string stability while maintaining smaller time headways, compared to car-following models used for training guidance under different market penetration rates of CAVs, which significantly improves traffic smoothness and mobility.     

Defect-Engineered Mesoporous Undoped Carbon Nanoribbons for Benchmark Oxygen Reduction Reaction

For large-scale fuel cell applications, it is significant to replace expensive Pt-based oxygen reduction reaction (ORR) electrocatalysts with nonprecious metal- or metal-free carbon-based catalysts with high activity. However, it is still challenging to deeply understand the role of intrinsic defects and the origin of ORR activity in pure nanocarbon. Therefore, a novel self-assembly and a pyrolysis strategy to fabricate defect-rich mesoporous carbon nanoribbons are presented. Due to the effective regulation of nanoarchitecture, a vast number of defective catalytic sites (edge defects and holes) are exposed, which thereby enhances the electron transfer kinetics and catalytic activity. Such undoped nanoribbons display a large half-wave potential of 0.837 V, excellent long-term stability, and exceptional methanol tolerance, surpassing the most undoped ORR catalysts and the commercial Pt/C (20 wt.%) catalyst. Structural characterizations and density functional theory (DFT) calculations confirm that the zigzag edge defects and the armchair pentagon at the hole defect are responsible for outstanding ORR performance.     

Lubricating and physico-chemical properties of CI- 4 plus engine oil dispersed with surface modified multi-walled carbon nanotubes

This paper studies the effect of surface modification of multiwall carbon nanotubes (MWCNTs) prior to dispersion in engine oil to improve the tribological properties. The MWCNTs are stabilised in the lubricant with two different surfactants cetrimonium bromide (CTAB) and sorbitan monooleate (SPAN 80) and the effect of surfactants on the tribological properties has been studied. Pristine and surface modified MWCNTs in weight per cent range of 0·5% are dispersed in CI4 plus diesel engine oil. The foaming tendency and other physico-chemical properties of test lubricant have been studied to investigate the effect of nano materials and surfactants. The anti-wear and anti-friction properties are tested on a four ball wear tester and the comparison is made to assess the relative performance of pristine MWCNTs over surface modified MWCNTs. A strong influence of the surface modification technique is found on lubricating and physico-chemical properties. Both CTAB and SPAN 80 could keep the MWCNTs stable in the lubricant without compromising the foaming tendency of lubricant and other physico-chemical properties. The friction and wear characteristics of lubricants have improved with the dispersion of surface modified MWCNTs while there is no improvement in the properties of lubricant dispersed with pristine MWCNTs.     

Physical layer impairment-aware shared path protection in wavelength-routed optical networks

The Journal of Supercomputing - In this paper, physical layer impairment (PLI)-aware shared path protection (SPP) scheme for single-link failures in transparent optical WDM mesh networks is...