Noise figure of vertical-cavity semiconductor optical amplifiers

The noise figure of vertical-cavity semiconductor optical amplifiers (VCSOAs) is investigated theoretically and experimentally. Limitations on the noise figure set by the reflectivity of the mirrors are studied. Highly reflective mirrors lead to increased output noise as well as lasing at moderate carrier densities, which imposes a limit on the obtainable population inversion. Expressions for the excess noise coefficient, which governs signal-spontaneous beat noise enhancement due to finite mirror reflectivity, are presented for transmission and reflection-mode operation. Experimental results from a VCSOA operating in the reflection mode at 1.3 μm are presented. The results, from optical as well as electrical measurement techniques, are analyzed and compared to theoretical values     

The emergence and troubled growth of a ‘biopower’ innovation system in Sweden

Biopower, i.e. production of power using biomass, has a tremendous potential to deliver CO₂ neutral energy in the Nordic countries. This paper analyses the evolution of a biopower innovation system in Sweden where particular attention is given to current driving forces and obstacles to a large-scale diffusion of biopower. In the 1980s and 1990s, this innovation system went through a successful ‘formative phase’ in which all the constituent components of the ‘infant’ system emerged. With the introduction of green certificates and emission trading rights, incentives were created that were large enough to shift the system into a ‘growth phase’, where the extensive district heating system and voluminous production in the paper and pulp industry can be used to produce power on a large scale in CHP plants. An investment boom is now underway and output of biopower is rapidly growing. Yet, there are still substantial obstacles to a realisation of the full potential of biopower. Three of these are outlined and an associated set of policy challenges are specified.     

Predicting moisture state of timber members in a continuously varying climate

A prerequisite for a sensible estimate of moisture induced stresses in timber members is an accurate prediction of the members’ moisture states during their service life. There are, however, an infinite number of possible moisture states for an arbitrary timber member in a natural varying climate. The naturally varying humidity is possible to describe as harmonic cycles, with different periods, superimposed. This work presents realizations of envelop curves over the possible moisture states in a timber member for some carefully chosen harmonic humidity variations. The calculations, on which the realizations were made, are based on a fully coupled transport model including a model for the influential sorption hysteresis of wood. A format containing required information suitable for assessing the “moisture” action on timber members is proposed. In addition it is illustrated how a model of high complexity and nonlinearity renders results with large degree of consistency. Large moisture gradients in a timber member are detected when variations of the humidity are frequent (daily period) and with large amplitude at high humidity levels. Overall and complete moisture changes of structural timber members with normal dimensions are found for members subjected to varying humidity with long (annual) periods. A timber member’s initial moisture state in relation to the ambient humidity can have a significant influence on both moisture gradients and overall moisture change of the member.     

Strategies for revealing deformation and wear mechanisms of polymer composites by combining scanning electron microscopy,energy dispersive x-ray spectroscopy and cross-section techniques—Exemplified by glass fiber reinforced poly-phenylene-sulphide

Polymers and polymer composites are frequently used in tribological applications. However, their use is often limited by excessive wear or plastic deformation, therefore research and development aiming to improve the materials is ongoing. Tribological evaluations of polymer composites often study the friction coefficient and wear rate for different types, sizes and amounts of fillers. But rarely are any mechanisms presented. Although polymer materials differ from metals, the techniques typically used for metal components, for example, scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS), can be adapted to polymer materials, to achieve more informative SEM micrographs and EDS analyses. The aim of this article is to present useful analysis strategies, from sample preparation and selection of viewing angles, to selection of instrument settings and detector types. The strategies are exemplified by analysis of poly-phenylene-sulphide filled with glass fiber, evaluated against steel in a reciprocating ball-on-flat test set-up. This article takes its starting point with the worn surfaces, and subsequently analyze them using SEM and EDS. A selection of cross section preparation techniques, analysis parameters and microscopy settings are presented and discussed. By combining these techniques and settings, the observation of a strongly modified surface layer, as well as sub-surface plastic deformation and imbedded wear particles, is facilitated.     

Adsorption of glyphosate on goethite: molecular characterization of surface complexes

As a component of herbicides, the fate of glyphosate (PMG) in the environment is of significant interest. The nature of PMG adsorption on mineral surfaces plays a significant role in the degradation of PMG. The adsorption of PMG on goethite (alpha-FeOOH) has been studied as a function of pH and PMG concentration. Adsorption was investigated with batch experiments, attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), and X-ray photoelectron spectroscopy (XPS). The N 1s line in XPS spectra showed deprotonation of the amine group of PMG (NH2+) with increasing pH. IR analyses showed no evidence for the interaction of PMG's carboxylate group with the goethite surface, while the phosphonate group formed inner-sphere complexes. There is evidence for intramolecular hydrogen bonding between NH2+ and both the carboxylate and the phosphonate groups at low pH. Intramolecular hydrogen bonding is lost when the amine group is deprotonated, and the trend in intramolecular hydrogen bonding between NH2+ and phosphonate shows that PMG adsorbs via predominantly monodentate complexation. A minor quantity of bidentate complexes is thought to form both at near-neutral pH and when the surface concentration of PMG is low. While the phosphonate group of PMG binds directly, the carboxylate group remains relatively "free" from complexation with goethite, leaving it subject to degradation and/or complexation with metal ions present in the environment.     

Intermittent metal cutting at small cutting depths—1. Dead zone phenomena and surface finish

Chip formation in intermittent metal cutting at small cutting depths was investigated by single edge experiments. Single cutting strokes were performed in a modified Charpy pendulum tester which offers force measurement, accurate selection of cutting speed and feed in the ranges typical of many intermittent high speed steel (HSS) tool operations. The pendulum is also provided with an excellent quick-stop mechanism.

The cutting performance of HSS tools in three widely used steel grades (including one plain carbon, one quenched and tempered and one austenitic stainless steel) was studied. A number of double rake micro geometries, with primary rake angles ranging from +20° (parrot bill) to −60°, all with a prepared 0.1 mm wear land were tested. The performance of the different edge geometries was investigated with respect to class of dead zone developed on the cutting edge, and its relation to chip curl and finish of the cut surface. The results are visualized in a dead zone map. The influence of cutting length, cutting speed, cutting depth and TiN-coating was treated specifically.

Among the most important observations were:

• the micro geometry of the edge influences the dead zone formation mechanism and hence the class of dead zone,

• the surface finish is strongly dead zone class dependent,

• the chip curl is determined by edge micro geometry and dead zone class.

The relationships between the varied parameters, generated dead zones and resulting cutting forces are presented in part 2 of this paper.     

Modeling processes in the acquisition of fears: Vicarious electrodermal conditioning to fear-relevant stimuli.

Describes an experiment with 72 university students in which fear-relevant (snakes, spiders, and rats) and fear-irrelevant (flowers, mushrooms, and berries) pictures were compared as conditioned and instigating stimuli in a vicarious classical conditioning paradigm with skin conductance responses as the dependent variable. A female confederate model and an S watched the pictures side by side. After a few stimulus presentations, the experimenter (E) interrupted to investigate alleged overreactions of the model to one of the stimulus classes. The model then vividly described a phobia for this object, which was to serve as a vicarious instigating stimulus. The experiment continued for a few conditioning trials, and then the E announced that the disturbing stimulus would be omitted before the 2nd part of the experiment. There was no effect of stimulus content on vicariously instigated responses, although significant overall instigation was observed. However, the responses to the stimulus that was paired with the model's phobic stimulus, that is, the vicariously conditioned responses, failed to extinguish during the 2nd part of the experiment when it was fear-relevant but extinguished immediately when it was fear-irrelevant. (26 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Scatter correction of transmission near-infrared spectra by photon migration data: quantitative analysis of solids

The scope of this work is a new methodology to correct conventional near-infrared (NIR) data for scattering effects. The technique aims at measuring the absorption coefficient of the samples rather than the total attenuation measured in conventional NIR spectroscopy. The main advantage of this is that the absorption coefficient is independent of the path length of the light inside the sample and therefore independent of the scattering effects. The method is based on time-resolved spectroscopy and modeling of light transport by diffusion theory. This provides an independent measure of the scattering properties of the samples and therefore of the path length of light. This yields a clear advantage over other preprocessing techniques, where scattering effects are estimated and corrected for by using the shape of the measured spectrum only. Partial least squares (PLS) calibration models show that, by using the proposed evaluation scheme, the predictive ability is improved by 50% as compared to a model based on conventional NIR data alone. The method also makes it possible to predict the concentration of active substance in samples with other physical properties than the samples included in the calibration model.     

Comparative environmental assessment of wood transport models: A case study of a Swedish pulp mill

Wood transportation from forest landing to forest-based industries uses large amounts of energy. In the case of Sweden, where forest operations are highly and efficiently mechanized, this stage consumes more fossil fuels than other elements of the wood supply chain (such as silviculture and logging operations). This paper intends to compare the environmental burdens associated to different wood transport models considering a Swedish pulp mill as a case study by using Life Cycle Assessment (LCA) as an analytical tool.Five scenarios (the current one and four alternative reliable scenarios) were proposed and analysed taking into account two variables. On the one hand, the influence of imported pulpwood share from Baltic countries and on the other hand, the use of rail transportation for wood transport. In particular, the following impact categories were assessed: Eutrophication, Global Warming, Photochemical Oxidant Formation, Acidification and Fossil fuel extraction. The environmental results indicate that transport alternatives including electric and diesel trains, as well as the reduction in Baltic wood imports should present better environmental performance than the current scenario in terms of all the impact categories under study. Remarkable differences were identified with regard to energy requirements. This divergence is related to different long-distance transport strategies (lorry, boat and/or train) as well as the relative import of wood selected.The combination of lorry and train in wood transportation from Southern Sweden plus the reduction of wood imports from 25% to 15% seems to be more favourable from an environmental perspective. The results obtained allow forecasting the importance of the wood transport strategy in the wood supply chain in LCA of forest products and the influence of energy requirements in the results.